IPC분류정보
국가/구분 |
United States(US) Patent
등록
|
국제특허분류(IPC7판) |
|
출원번호 |
US-0002112
(2009-06-30)
|
등록번호 |
US-8536095
(2013-09-17)
|
국제출원번호 |
PCT/US2009/049170
(2009-06-30)
|
§371/§102 date |
20110613
(20110613)
|
국제공개번호 |
WO2010/002836
(2010-01-07)
|
발명자
/ 주소 |
- Seifert-Higgins, Simone
- Abraham, William
- Bates, Christopher I.
|
출원인 / 주소 |
|
대리인 / 주소 |
|
인용정보 |
피인용 횟수 :
1 인용 특허 :
84 |
초록
Efficacious herbicidal compositions comprising a derivatized saccharide surfactant and an amine oxide surfactant are described. The compositions are characterized as having low toxicity and are readily biodegradable.
대표청구항
▼
1. A composition comprising glyphosate or a salt or ester thereof, a derivatized saccharide surfactant and an amine oxide surfactant having an oxyalkylene or polyoxyalkylene group bonded to the amine oxide group via a nitrogen-carbon bond, wherein the oxyalkylene or polyoxyalkylene group is capped a
1. A composition comprising glyphosate or a salt or ester thereof, a derivatized saccharide surfactant and an amine oxide surfactant having an oxyalkylene or polyoxyalkylene group bonded to the amine oxide group via a nitrogen-carbon bond, wherein the oxyalkylene or polyoxyalkylene group is capped at a terminus remote from said nitrogen-carbon bond with a hydrocarbyl group via an ether linkage;said derivatized saccharide comprises a surfactant of the formula: R11—O-(sug)u wherein: R11 is a straight or branched chain C4-22 hydrocarbyl;sug is an open or cyclic saccharide residue selected from the group consisting of ribose, xylose, arabinose, glucose, galactose, mannose, telose, gulose, allose, altrose, idose, lyxose, ribulose, sorbose (sorbitan) and fructose,sug is a disaccharide selected from maltose, lactose and sucrose, orsug is a disaccharide, oligosaccharide or polysaccharide selected from two or more identical saccharides or two or more different saccharides selected from the group consisting of ribose, xylose, arabinose, glucose, galactose, mannose, telose, gulose, allose, altrose, idose, lyxose, ribulose, sorbose (sorbitan) and fructose; andu is an average number of from 1 to about 10; andthe weight ratio of the derivatized saccharide surfactant to the amine oxide surfactant is greater than 1:1. 2. The composition of claim 1 wherein said amine oxide comprises a surfactant of the formula: wherein R1 is C1-22 straight or branched chain hydrocarbyl, each X is independently an ether, thioether, sulfoxide, ester, thioester or amide linkage, each R2 is independently C2-6 alkylene, each R3 is independently C2-4 alkylene, each R4 is independently C2-4 alkylene, and R5 and R6 are independently hydrogen, C1-4 alkyl or C2-4 acyl; x and y are average numbers such that the sum of x and y is from 2 to about 60, m is from 0 to about 9, and n is from 0 to about 5. 3. The composition of claim 2 wherein R1 is straight or branched chain C8-18 alkyl, aryl or alkaryl, and m is 0. 4. The composition of claim 3 wherein R1 is straight or branched chain C8-18 alkyl, R3 is ethylene, n-propyl or iso-propylene, n is from 1 to about 3, R4 is ethylene, the sum of x and y is from 2 to about 20, and R5 and R6 are hydrogen. 5. The composition of claim 1 wherein R11 is straight or branched chain C8-18 alkyl, sug is an open or cyclic saccharide residue of glucose, and u is an average number from 1 to about 5. 6. The composition of claim 1 wherein the weight ratio of the derivatized saccharide surfactant to the amine oxide surfactant is from about 2:1 to about 10:1. 7. The composition of claim 1 wherein the weight ratio of the derivatized saccharide surfactant to the amine oxide surfactant is from about 2:1 to about 8:1. 8. The composition of claim 1 wherein the weight ratio of the derivatized saccharide surfactant to the amine oxide surfactant is from about 2:1 to about 6:1. 9. The composition of claim 1 wherein the herbicide comprises a salt of glyphosate selected from the mono(isopropylamine), trimethylsulfonium, monoethanolammonium, monoammonium, diammonium, sodium and potassium salts. 10. The composition of claim 9 wherein the salt is the potassium salt. 11. The composition of claim 9 wherein the composition is an aqueous concentrate wherein the glyphosate is in a concentration ranging from about 300 to about 600 grams acid equivalent per liter. 12. The composition of claim 9 wherein the composition is an aqueous application mixture wherein the glyphosate is in a concentration ranging from about 1 to about 20 grams acid equivalent per liter. 13. The composition of claim 9 wherein the glyphosate is in the form of the ammonium, diammonium or sodium salt thereof, and the composition is a solid concentrate wherein the glyphosate is in a concentration ranging from about 20 to about 90 percent by weight acid equivalent. 14. The composition of claim 9 wherein the weight ratio of glyphosate acid equivalent to total surfactant is from about 2:1 to about 10:1. 15. The composition of claim 14 wherein the weight ratio of glyphosate acid equivalent to total surfactant is from about 2:1 to about 5:1. 16. The composition of claim 11 wherein the cloud point is at least 50° C. 17. The composition of claim 11 wherein the composition does not exhibit phase separation upon exposure to temperatures up to about 50° C. for 14 days. 18. The composition of claim 11 wherein the composition does not form crystals of glyphosate or salt thereof upon exposure to a temperature of about 0° C. for a period of up to about 7 days. 19. A composition comprising glyphosate or a salt or ester thereof, a derivatized saccharide surfactant and an amine oxide surfactant having a group corresponding to the formula R1—(XR2)m—(OR3)n—Z— attached to the amine oxide group via a carbon-nitrogen bond, wherein R1 is a hydrocarbyl group comprising from about 6 to about 22 carbon atoms, R2 and R3 are independently selected from alkylene groups comprising from 2 to 4 carbon atoms, Z is a carbon-nitrogen bond or an oxyhydrocarbylene group comprising from 2 to 6 carbon atoms, each X is independently an ether, thioether, sulfoxide, ester, thioester or amide linkage, m is an average number from 0 to about 9, n is an average number from 0 to about 5 and m+n≧1;said derivatized saccharide comprises a surfactant of the formula: R11—O-(sug)u wherein: R11 is a straight or branched chain C4-22 hydrocarbyl;sug is an open or cyclic saccharide residue selected from the group consisting of ribose, xylose, arabinose, glucose, galactose, mannose, telose, gulose, allose, altrose, idose, lyxose, ribulose, sorbose (sorbitan) and fructose,sug is a disaccharide selected from maltose, lactose and sucrose, orsug is a disaccharide, oligosaccharide or polysaccharide selected from two or more identical saccharides or two or more different saccharides selected from the group consisting of ribose, xylose, arabinose, glucose, galactose, mannose, telose, gulose, allose, altrose, idose, lyxose, ribulose, sorbose (sorbitan) and fructose; andu is an average number of from 1 to about 10; andthe weight ratio of the derivatized saccharide surfactant to the amine oxide surfactant is greater than 1:1. 20. The composition of claim 19 wherein the concentrations of said derivatized saccharide and said amine oxide surfactants is such that the composition exhibits lesser aquatic toxicity on an EC50 basis than a reference composition as measured by at least one of EPA method 2002.0, EPA method 1002, EPA method 2000.0, EPA method 1000, EPA method 2019.0, OECD Guideline 202 or the method of Annex V of European Union Directive 67/548/EEC, but provides plant growth control of at least 85 percent of the growth control provided by the reference composition when the composition and reference composition are applied to the plants at same glyphosate acid equivalent application rate, said reference composition being devoid of said derivatized saccharide but otherwise identical to said composition in the nature and concentration of its herbicide, amine oxide surfactant and any other herbicidally active components. 21. The composition of claim 19 wherein the concentrations of said derivatized saccharide and said amine oxide surfactants is such that the composition exhibits greater biodegradability than a reference composition as measured by at least one of ASTM method D-5864, CEC method L-33-A-934, OECD method 301, OECD method 302B, or EPA method 560/6-82-003, but provides growth control of at least 85 percent of the growth control provided by the reference composition when the composition and reference composition are applied to the plants at same glyphosate acid equivalent application rate, said reference composition being devoid of said derivatized saccharide but otherwise identical to said composition in the nature and concentration of its herbicide, amine oxide surfactant and any other herbicidally active components. 22. A composition as set forth in claim 20 wherein the EC50 concentration is at least 360 milligrams per liter when measured at 48 hours according to the method of OECD Guideline 202. 23. A composition as set forth in claim 21 wherein the composition is defined as inherently biodegradable when measured according to the method of OECD Guideline 301 or the method of OECD Guideline 302B. 24. A low toxicity herbicidal composition comprising glyphosate or a salt or ester thereof, a derivatized saccharide surfactant and an amine oxide surfactant having a group corresponding to the formula R1—(XR2)m—(OR3)n—Z— attached to the amine oxide group via a carbon-nitrogen bond, wherein R1 is a hydrocarbyl group comprising from about 6 to about 22 carbon atoms and R2 and R3 are independently selected from alkylene groups comprising from 2 to 4 carbon atoms, Z is a carbon-nitrogen bond or an oxyhydrocarbylene group comprising from about 2 to about 6 carbon atoms, each X is independently an ether, thioether, sulfoxide, ester, thioester or amide linkage, m is an average number from 0 to about 9, n is an average number from 0 to about 5 and m+n≧1;said derivatized saccharide comprises a surfactant of the formula: R11—O-(sug)u wherein: R11 is a straight or branched chain C4-22 hydrocarbyl;sug is an open or cyclic saccharide residue selected from the group consisting of ribose, xylose, arabinose, glucose, galactose, mannose, telose, gulose, allose, altrose, idose, lyxose, ribulose, sorbose (sorbitan) and fructose,sug is a disaccharide selected from maltose, lactose and sucrose, orsug is a disaccharide, oligosaccharide or polysaccharide selected from two or more identical saccharides or two or more different saccharides selected from the group consisting of ribose, xylose, arabinose, glucose, galactose, mannose, telose, gulose, allose, altrose, idose, lyxose, ribulose, sorbose (sorbitan) and fructose; andu is an average number of from 1 to about 10;the concentrations of said derivatized saccharide and said amine oxide surfactants are such that the low toxicity composition exhibits lesser aquatic toxicity on an EC50 basis than a reference composition as measured by at least one of EPA method 2002.0, EPA method 1002, EPA method 2000.0, EPA method 1000, EPA method 2019.0, OECD Guideline 202 or the method of Annex V of European Union Directive 67/548/EEC, but provides growth control equivalent to that provided by a reference composition when the composition and reference composition are applied to the plants at same glyphosate acid equivalent application rate, said reference composition having the same herbicide content as said low toxicity composition and comprising said amine oxide surfactant but being devoid of said alkyl polysaccharide; andwherein the weight ratio of the derivatized saccharide surfactant to the amine oxide surfactant is greater than 1:1.
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