IPC분류정보
국가/구분 |
United States(US) Patent
등록
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국제특허분류(IPC7판) |
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출원번호 |
US-0236272
(2011-09-19)
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등록번호 |
US-8545633
(2013-10-01)
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발명자
/ 주소 |
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출원인 / 주소 |
- Abengoa Bioenergy New Technologies, Inc.
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대리인 / 주소 |
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인용정보 |
피인용 횟수 :
5 인용 특허 :
120 |
초록
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The present invention generally relates to processes for production of ethanol from cellulosic biomass. The present invention also relates to production of various co-products of preparation of ethanol from cellulosic biomass. The present invention further relates to improvements in one or more aspe
The present invention generally relates to processes for production of ethanol from cellulosic biomass. The present invention also relates to production of various co-products of preparation of ethanol from cellulosic biomass. The present invention further relates to improvements in one or more aspects of preparation of ethanol from cellulosic biomass including, for example, improved methods for cleaning biomass feedstocks, improved acid impregnation, and improved steam treatment, or “steam explosion.”
대표청구항
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1. A method for pretreatment of cellulosic biomass feedstock comprising cellulose, hemicellulose, and lignin, the method comprising: contacting the cellulosic biomass feedstock with an acidic liquid medium to form an acid-impregnated biomass feedstock;contacting the acid-impregnated cellulosic bioma
1. A method for pretreatment of cellulosic biomass feedstock comprising cellulose, hemicellulose, and lignin, the method comprising: contacting the cellulosic biomass feedstock with an acidic liquid medium to form an acid-impregnated biomass feedstock;contacting the acid-impregnated cellulosic biomass feedstock with H2O at elevated temperature and pressure within a contact zone under conditions effective for solubilizing hemicellulose and producing a steam treated feedstock, wherein the pressure in the contact zone is at least about 55 psig;subjecting the steam treated feedstock within a depressurization zone to conditions and for at time effective for solubilizing hemicellulose and producing a volatilized fraction of the steam treated feedstock; andreleasing at least a portion of the volatilized fraction from the depressurization zone for control of temperature and pressure within the depressurization zone, wherein the pressure within the depressurization zone is controlled to from about 5 to about 50 psig. 2. The method of claim 1 wherein the acid-impregnated cellulosic biomass feedstock is contacted with H2O in the contact zone as saturated steam at a pressure of from about 75 psig to about 250 psig. 3. The method of claim 1 wherein the acid-impregnated cellulosic biomass feedstock is contacted with H2O in the contact zone as saturated steam at a temperature of from about 160° C. to about 230° C. 4. The method of claim 1 wherein the acid-impregnated cellulosic biomass feedstock is contacted with H2O in the contact zone as saturated steam for from about 1 to about 15 minutes. 5. The method of claim 1 wherein the depressurization zone temperature is from about 110° C. to about 150° C. 6. The method of claim 1 wherein the pressure within the depressurization zone is from about 5 psig to about 40 psig and the temperature is from about 110° C. to about 140° C. 7. The method of claim 1 wherein the pressure within the depressurization zone is from about 10 psig to about 15 psig and the temperature is from about 110° C. to about 120° C. 8. The method of claim 1 wherein the steam treated feedstock is subjected to conditions effective for solubilizing hemicellulose and producing a volatilized fraction of the steam treated feedstock in the depressurization zone for from about 2 to about 30 minutes. 9. The method of claim 1 wherein the steam treated feedstock within the contact zone comprises a liquid fraction comprising xylose and the steam treated feedstock within the depressurization zone comprises a liquid fraction comprising xylose, and wherein the xylose content of the liquid fraction of the steam treated feedstock within the depressurization zone represents a xylose yield of at least about 60%. 10. The method of claim 9 wherein the xylose content of the liquid fraction of the steam treated feedstock within the depressurization zone represents a xylose yield of at least about 70%. 11. The method of claim 9 wherein the xylose content of the liquid fraction in the depressurization zone is at least about 5% higher than the xylose content of the liquid fraction in the contact zone. 12. The method of claim 1 wherein the volatilized fraction of the steam treated feedstock released from the depressurization zone comprises furfural, acetic acid, steam, or a combination thereof. 13. The method of claim 1 wherein the method comprises: continuously contacting the acid-impregnated cellulosic biomass feedstock with H2O in the contact zone;continuously subjecting the steam treated feedstock to the conditions within the depressurization zone; andcontinuously releasing at least a portion of the volatilized fraction from the depressurization zone. 14. The method of claim 1 wherein the contact zone and depressurization zone are contained within a single vessel. 15. The method of claim 1 wherein the contact zone and depressurization zone are contained within separate vessels. 16. The method of claim 1 wherein the contact zone comprises a first pretreatment stage and a second pretreatment stage wherein, in the second pretreatment stage, at least a portion of the volatilized fraction is released from the contact zone at a rate effective to control the pressure in the contact zone, wherein the pressure in the second pretreatment stage is reduced by at least 30 psig as compared to the pressure in the first pretreatment stage. 17. A method for pretreatment of cellulosic biomass feedstock comprising cellulose, hemicellulose, and lignin, the method comprising: contacting the cellulosic biomass feedstock with an acidic liquid medium to form an acid-impregnated cellulosic biomass feedstock;in a first pretreatment stage, contacting the acid-impregnated cellulosic biomass feedstock with H2O at elevated temperature within a contact zone containing a vapor phase wherein the partial pressure of water vapor is at least about 55 psig to solubilize hemicellulose and produce a volatilized fraction of the acid-impregnated feedstock; andin a second pretreatment stage, releasing at least a portion of the volatilized fraction from the contact zone at a rate effective to control the pressure of in the contact zone, wherein the pressure in the second pretreatment stage is reduced by at least about 30 psig as compared to the first pretreatment stage pressure, the pressure in the second pretreatment stage is controlled above atmospheric pressure, and the acid-impregnated feedstock is held in the second pretreatment stage for a time effective for solubilizing hemicellulose and producing a volatilized fraction of the steam treated feedstock. 18. The method of claim 17 wherein the volatilized fraction comprises acetic acid, furfural, hydroxymethyl furfural, condensable gases, or a combination thereof. 19. The method of claim 17 wherein the acid impregnated cellulosic biomass in the first pretreatment stage and the second pretreatment stage comprises a liquid fraction comprising xylose, wherein the xylose content of the liquid fraction in the second pretreatment stage is at least about 5% higher than the xylose content of the liquid fraction in the first pretreatment stage. 20. The method of claim 17 wherein the first pretreatment stage pressure is at least about 150 psig. 21. The method of claim 17 wherein the second pretreatment stage pressure is from about 25 psig to about 150 psig. 22. The method of claim 17 wherein the first pretreatment stage temperature is from about 160° C. to about 220° C. 23. The method of claim 17 wherein the second pretreatment stage temperature is from about 130° C. to about 185° C. 24. The method of claim 17 wherein the second pretreatment stage hold time is from about 0.1 to about 5 minutes. 25. The method of claim 17 further comprising treating the acid-impregnated feedstock from the second pretreatment stage steam treated feedstock within a depressurization zone to conditions and for at time effective for solubilizing hemicellulose and producing a volatilized fraction of the steam treated feedstock; and releasing at least a portion of the volatilized fraction from the depressurization zone for control of temperature and pressure within the depressurization zone, wherein control of the temperature and pressure within the depressurization zone comprises releasing at least a portion of the volatilized fraction therefrom, wherein the pressure within the depressurization zone is controlled to from about 5 to about 50 psig. 26. A method for pretreatment of cellulosic biomass feedstock comprising cellulose, hemicellulose, and lignin, the method comprising: introducing said feedstock into a steam contact zone, said contact zone having an inlet for steam and an outlet for pretreated feedstock;introducing steam into said contact zone at said inlet to contact steam and said feedstock and form a steam treated feedstock, wherein the pressure in the contact zone is at least about 51) psig; andremoving pretreated feedstock from said contact zone through said outlet and into a receiving zone, wherein the pressure in the receiving zone does not differ from the pressure in the contact zone by more than about 200 psig, the pressure in the receiving zone is controlled above atmospheric pressure, and the pretreated feedstock is held in the receiving zone for a time effective for solubilizing hemicellulose and producing a volatilized fraction of the steam treated feedstock. 27. A method as set forth in claim 26 wherein the pressure within said contact zone is at least about 100 psig. 28. The method of claim 26 wherein the acid impregnated cellulosic biomass in the contact zone and receiving zone comprises a liquid fraction comprising xylose, wherein the xylose content of the liquid fraction in the receiving zone is at least about 5% higher than the xylose content of the liquid fraction in the contact zone. 29. The method of claim 26 wherein the contact zone pressure is at least about 150 psig. 30. The method of claim 26 wherein the receiving zone pressure is from about 25 psig to about 150 psig. 31. The method of claim 26 wherein the contact zone temperature is from about 160° C. to about 220° C. 32. The method of claim 26 wherein the receiving zone temperature is from about 130° C. to about 185° C. 33. The method of claim 26 wherein the receiving zone hold time is from about 0.1 to about 5 minutes. 34. A method for pretreatment of cellulosic biomass feedstock comprising cellulose, hemicellulose, and lignin, the method comprising: introducing said feedstock into a steam contact zone;introducing steam into said contact zone to contact said feedstock and form a steam-treated feedstock, wherein the pressure in the contact zone is at least about 51) psig; andpassing said steam-treated feedstock from said steam contact zone through a flow restriction and into a receiving zone, the pressure drop across said flow restriction being less than about 150 psi, the pressure in the receiving zone is controlled above atmospheric pressure, and the steam-treated feedstock is held in the receiving zone for a time effective for solubilizing hemicellulose and producing a volatilized fraction of the steam treated feedstock. 35. The method of claim 34 wherein the acid impregnated cellulosic biomass in the contact zone and receiving zone comprises a liquid fraction comprising xylose, wherein the xylose content of the liquid fraction in the receiving zone is at least about 5% higher than the xylose content of the liquid fraction in the contact zone. 36. The method of claim 34 wherein the contact zone pressure is at least about 150 psig. 37. The method of claim 34 wherein the receiving zone pressure is from about 25 psig to about 150 psig. 38. The method of claim 34 wherein the contact zone temperature is from about 160° C. to about 220° C. 39. The method of claim 34 wherein the receiving zone temperature is from about 130° C. to about 185° C. 40. The method of claim 34 wherein the receiving zone hold time is from about 0.1 to about 5 minutes. 41. A method for pretreatment of cellulosic biomass feedstock comprising cellulose, hemicellulose, and lignin, the method comprising: in a first pretreatment stage, contacting the cellulosic biomass feedstock with H20 within a contact zone containing a vapor phase wherein the partial pressure of water vapor is at least about 55 psig, said H20 being distributed within said zone so that the biomass is brought to a target temperature, and the average temperature of any region of the biomass that contains more than 15% by weight of the biomass does not differ by more than 5° C. from said target temperature, andin a second pretreatment stage, reducing the pressure by at least 31) psig as compared to the first pretreatment stage pressure, the pressure in the second pretreatment stage is controlled above atmospheric pressure, and the feedstock-is held in the second pretreatment stage for a time effective for solubilizing hemicellulose and producing a volatilized fraction of the steam treated feedstock. 42. The method of claim 41 wherein the average temperature of any region of biomass that contains more than about 10% by weight of the biomass does not differ by more than 5° C. from said target temperature. 43. The method of claim 41 wherein the acid impregnated cellulosic biomass in the first pretreatment stage and the second pretreatment stage comprises a liquid fraction comprising xylose, wherein the xylose content of the liquid fraction in the second pretreatment stage is at least about 5% higher than the xylose content of the liquid fraction in the first pretreatment stage. 44. The method of claim 41 wherein the first pretreatment stage pressure is at least about 150 psig. 45. The method of claim 41 wherein the second pretreatment stage pressure is from about 25 psig to about 150 psig. 46. The method of claim 41 wherein the first pretreatment stage temperature is from about 160° C. to about 220° C. 47. The method of claim 41 wherein the second pretreatment stage temperature is from about 130° C. to about 185° C. 48. The method of claim 41 wherein the second pretreatment stage hold time is from about 0.1 to about 5 minutes.
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