A dioxaborinane compound, or salt thereof, where boron has two oxy substituents, each independently substituted with H, alkyl, alkenyl, aryl, —C(O)R3, —C(O)OR3, —C(O)NHR3, or the two oxy substituents, together with the oxygen atoms to which they are bonded, join to form a 5- or 6-membered ring; and
A dioxaborinane compound, or salt thereof, where boron has two oxy substituents, each independently substituted with H, alkyl, alkenyl, aryl, —C(O)R3, —C(O)OR3, —C(O)NHR3, or the two oxy substituents, together with the oxygen atoms to which they are bonded, join to form a 5- or 6-membered ring; and R3 is H, alkyl, alkenyl, or aryl, where the alkyl and alkenyl are optionally interrupted with one or more oxygen or sulfur atoms; and where boron also has the substituent -L-X1-PG1; where L may be absent, or alkylenyl, alkenylenyl, or arylene, where the alkylenyl and alkenylenyl are optionally interrupted with one or more oxygen or sulfur atoms; X1 is absent, or is amino, oxo, thio, or phosphino; and PG1 is a polymerizable group. The dioxaborinane compound can be used as a wood preservative.
대표청구항▼
1. A compound of Formula IA: wherein: L is absent, or is alkylenyl, alkenylenyl, or arylene, wherein the alkylenyl and alkenylenyl are optionally interrupted with one or more oxygen or sulfur atoms;X1 is absent, or is amino, oxo, thio, or phosphino;PG1 is a polymerizable group;R5 and R6 are independ
1. A compound of Formula IA: wherein: L is absent, or is alkylenyl, alkenylenyl, or arylene, wherein the alkylenyl and alkenylenyl are optionally interrupted with one or more oxygen or sulfur atoms;X1 is absent, or is amino, oxo, thio, or phosphino;PG1 is a polymerizable group;R5 and R6 are independently H, alkyl, alkenyl, aryl, or —C(O)R7; andR7 is alkyl, alkenyl, or aryl. 2. The compound of claim 1, wherein PG1 is acrylyl, methacrylyl, epoxyl, isocycanyl, styrenyl, vinyl, oxyvinyl, thiovinyl, ketovinyl, ketoalkyl, ketoalkoxy, ketoaryl, or cycloalkenyl. 3. The compound of claim 1, wherein PG1 is —C(O)C(R4)═CH2, —C(O)CH═CH2, —O—CH═CH2, —S—CH═CH2, —N═C═O, or and R4 is a C1-C8 alkyl. 4. The compound of claim 1, wherein PG1 is —C(O)C(R4)═CH2 and R4 is a C1-C8 alkyl. 5. The compound of claim 1, wherein PG1 is —C(O)CH═CH2. 6. The compound of claim 1, wherein X1 is —NH—, —O—, —S—, or —PH—. 7. The compound of claim 1, wherein L is C1-C10 alkylene. 8. The compound of claim 1, wherein R5 is —C(O)alkyl and R6 is —C(O)alkyl. 9. The compound of claim 1, wherein X1 is —O—. 10. A polymer comprising a polymerization product of the compound of claim 1. 11. A composition comprising the compound of claim 1 and a cellulosic material. 12. The composition of claim 11, wherein the cellulosic material is wood, and the composition is a wood-polymer borinane composite material. 13. A process of preparing a wood-polymer borinane composite material comprising: contacting a cellulosic material with a compound of Formula IA; andpolymerizing the compound of Formula IA to form the wood-polymer borinane composite material;wherein: Formula IA is: L is absent, or is alkylenyl, alkenylenyl, or arylene, wherein the alkylenyl and alkenylenyl are optionally interrupted with one or more oxygen or sulfur atoms;X1 is absent, or is amino oxo, thio, or phosphino;PG1 is a polymerizable group;R5 and R6 are independently H, alkyl, alkenyl, aryl, or —C(O)R7; andR7 is alkyl, alkenyl, or aryl. 14. The process of claim 13, wherein the contacting comprises employing a pressure process, a full cell process, or a fluctuation pressure process. 15. The process of claim 13, wherein the polymerizing comprises-activating the polymerizable group with UV, visible, or near-IR radiation, adding a thermal initiator to the polymerizable group, or adding a photochemical initiator to the polymerizable group. 16. The process of claim 13, wherein the polymerizing comprises adding a thermal initiator that is 4,4-azobis(4-cyanovaleric acid), 1,1′-azobis(cyclohexanecarbonitrile), 2,2′-azobisisobutyronitrile, benzoyl peroxide, tert-butyl peracetate, lauroyl peroxide, or dicumyl peroxide, or adding a photochemical initiator to the polymerizable group that is 3-butyl-2-[5-(1-butyl-3,3-dimethyl-1,3-dihydro-indol-2-ylidene)-penta-1,3-dienyl]-1,1-dimethyl-1H-benzo[e]indolium triphenylbutylborate, 3-butyl-2-[5-(3-butyl-1,1-dimethyl-1,3-dihydro-benzo[e]indol-2-ylidene)-penta-1,3-dienyl]-1,1-dimethyl-1H-benzo[e]indolium triphenylbutylborate, or 6-hydroxy-2,4,5,7-tetraiodo-3-oxo-9,9a-dihydro-3H-xanthene-9-carbonitrile. 17. An article comprising the composition of claim 12. 18. The article of claim 17 which is a railroad tie, a pole for supporting cable, or a building member. 19. A method of preparing a compound of Formula IA, the method comprising: contacting a precursor compound with a compound of Formula III to form the compound of Formula IA;wherein: Formula IA is: the precursor compound is: Formula III is PG1-Y;L is absent, or is alkylenyl, alkenylenyl, or arylene, wherein the alkylenyl and alkenylenyl are optionally interrupted with one or more oxygen or sulfur atoms;X1 is absent, or is —O—, —NH—, —S—, or —P(R3)—;R5 and R6 are independently H, alkyl, alkenyl, aryl, or —C(O)R7;R7 is alkyl, alkenyl, or arylPG1 is acrylyl, methacrylyl, epoxyl, isocycanyl, styrenyl, vinyl, oxyvinyl, thiovinyl, ketovinyl, ketoalkyl, ketoalkoxy, ketoaryl, or cycloalkenyl; andY is a leaving group.
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이 특허에 인용된 특허 (4)
Saischek Gerald (Wels ATX) Bodingbauer Hans (Hellmonsdt ATX), 1,3,2-dioxaborinanes.
Warren Craig B. (Rumson NJ) Butler Jerry F. (Gainesville FL) Wilson Richard A. (Westfield NJ) Mookherjee Braja D. (Holmdel NJ) Smith Leslie C. (Jamesburg NJ) Marin Anna B. (Long Branch NJ) Narula Anu, Insect repellent compositions and methods for using same.
Warren Craig B. (Rumson NJ) Butler Jerry F. (Gainesville FL) Wilson Richard A. (Westfield NJ) Mookherjee Braja D. (Holmdel NJ) Smith Leslie C. (Jamesburg NJ) Marin Anna B. (Long Branch NJ) Narula Anu, Insect repellent compositions and methods for using same.
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