Lubricant formulation with high oxidation performance
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IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
C10M-137/10
C10M-133/12
출원번호
US-0161906
(2011-06-16)
등록번호
US-8569216
(2013-10-29)
발명자
/ 주소
Blain, David A.
Farng, Liehpao Oscar
Sanchez, Eugenio
Douglass, Michael R.
Galiano-Roth, Angela S.
Carey, James T.
출원인 / 주소
ExxonMobil Research and Engineering Company
대리인 / 주소
Migliorini, Robert A.
인용정보
피인용 횟수 :
4인용 특허 :
28
초록▼
A Group IV/Group V lubricating composition providing improved antioxidation performance comprises from 5 wt. % to 40 wt. % of a Group V base oil component, such as alkylated naphthalene, at least 30 wt. % of a Group IV base oil component, such as one or more polyalphaolefin base stocks, and from 0.2
A Group IV/Group V lubricating composition providing improved antioxidation performance comprises from 5 wt. % to 40 wt. % of a Group V base oil component, such as alkylated naphthalene, at least 30 wt. % of a Group IV base oil component, such as one or more polyalphaolefin base stocks, and from 0.25 wt. % to 1.5 wt. % of a trithiophosphate-containing compound. The trithiophosphate-containing compound is preferably C30H57O7PS3. The lubricating composition includes not greater than 5 wt. % of a Group I, Group II, or Group III base oil component, and, preferably not greater than 10 ppm heavy metal component. The lubricating composition preferably has a kinematic viscosity of from 20 cSt to 1,000 cSt at 40° C. and a viscosity index (VI) of from 130 to 200.
대표청구항▼
1. A lubricating composition comprising in admixture: from 15 wt. % to 25 wt. % of a Group V base oil component, based on the total weight of the blend components that are used to produce the lubricating composition, wherein the Group V base oil component is alkylated naphthalene,from 65 wt. % to 85
1. A lubricating composition comprising in admixture: from 15 wt. % to 25 wt. % of a Group V base oil component, based on the total weight of the blend components that are used to produce the lubricating composition, wherein the Group V base oil component is alkylated naphthalene,from 65 wt. % to 85 wt. % of a Group IV base oil component, based on the total weight of the blend components that are used to produce the lubricating composition, wherein the Group IV base oil component is one or more polyalphaolefin base stocks,from 0.25 wt. % to 1.5 wt. % of a trithiophosphate-containing compound, based on the total weight of the blend components that are used to produce the lubricating composition, wherein the trithiophosphate-containing compound is S,S,S-Tris-carbo-2-isooctyloxy-methyl trithiophosphate,from 0.25 wt. % to 1.5 wt. % of alkylated diphenyl amine, based on the total weight of the blend components that are used to produce the lubricating composition, andnot greater than 5 wt. % of a Group I, Group II, or Group III base oil component, based on the total weight of the blend components that are used to produce the lubricating composition, andwherein the 210 hour oxidation stability test of the lubricating composition yields a value greater than 210 hours. 2. The lubricating composition of claim 1, wherein the trithiophosphate-containing compound has a Mw of 600 g/mol to 700 g/mol. 3. The lubricating composition of claim 1 including not greater than 1 wt. % of the trithiophosphate-containing compound, based on the total weight of the blend components that are used to produce the lubricating composition. 4. The lubricating composition of claim 1 including not greater than 1 wt. % of the trithiophosphate-containing compound and not greater than 1 wt. % of the alkylated diphenyl amine, based on the total weight of the blend components that are used to produce the lubricating composition. 5. The lubricating composition of claim 1, wherein the lubricating composition comprises not greater than 10 parts per million (ppm) of a heavy metal component, based on the total weight of the blend components that are used to produce the lubricating composition. 6. The lubricating composition of claim 1, wherein the lubricating composition comprises a total of at least 80 wt. % of the combined Group V base oil component and the Group IV base oil component, based on the total weight of the blend components that are used to produce the lubricating composition. 7. The lubricating composition of claim 1 wherein the Group IV base oil component has a kinematic viscosity of from 2 cSt to 2000 cSt at 40° C. 8. The lubricating composition of claim 1 wherein the blended lubricating composition has a kinematic viscosity of from 20 cSt to 1,000 cSt at 40° C. 9. The lubricating composition of claim 1 wherein the blended lubricating composition has a viscosity index (VI) of from 130 to 200. 10. The lubricating composition of claim 1 wherein the blended lubricating composition has an ISO VG grade of from 22 to 1000. 11. A method of producing a lubricating composition, comprising blending together at least the following components: from 15 wt. % to 25 wt. % of a Group V base oil component, based on the total weight of the blend components that are used to produce the lubricating composition, wherein the Group V base oil component is alkylated naphthalene,from 65 wt. % to 85 wt. % of a Group IV base oil component, based on the total weight of the blend components that are used to produce the lubricating composition, wherein the Group IV base oil component is one or more polyalphaolefin base stocks,from 0.25 wt. % to 1.5 wt. % of a trithiophosphate-containing compound, based on the total weight of the blend components that are used to produce the lubricating composition, wherein the trithiophosphate-containing compound is S,S,S-Tris-carbo-2-isooctyloxy-methyl trithiophosphate,from 0.25 wt. % to 1.5 wt. % of alkylated diphenyl amine, based on the total weight of the blend components that are used to produce the lubricating composition, andnot greater than 5 wt. % of a Group I, Group II, or Group III base oil component, based on the total weight of the blend components that are used to produce the lubricating composition, andwherein the 210 hour oxidation stability test of the lubricating composition yields a value greater than 210 hours. 12. A method of improving the antioxidation performance of a lubricating composition comprising in admixture from 15 wt. % to 25 wt. % of a Group V base oil component, based on the total weight of the blend components that are used to produce the lubricating composition, wherein the Group V base oil component is alkylated naphthalene, and from 65 wt. % to 85 wt. % of a Group IV base oil component, based on the total weight of the blend components that are used to produce the lubricating composition, wherein the Group IV base oil component is one or more polyalphaolefin base stocks, the method comprising the step of: adding to the lubricating composition from 0.25 wt. % to 1.5 wt. % of a trithiophosphate-containing compound, based on the total weight of the blend components that are used to produce the lubricating composition, wherein the trithiophosphate-containing compound is S,S,S-Tris-carbo-2-isooctyloxy-methyl trithiophosphate,adding to the lubricating composition from 0.25 wt. % to 1.5 wt. % of a alkylated diphenyl amine, based on the total weight of the blend components that are used to produce the lubricating composition,wherein the lubricating composition contains not greater than 5 wt. % of a Group I, Group II, or Group III base oil component, based on the total weight of the blend components that are used to produce the lubricating composition, andwherein the 210 hour oxidation stability test of the lubricating composition yields a value greater than 210 hours.
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