IPC분류정보
국가/구분 |
United States(US) Patent
등록
|
국제특허분류(IPC7판) |
|
출원번호 |
US-0363301
(2006-02-24)
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등록번호 |
US-8580216
(2013-11-12)
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발명자
/ 주소 |
- Malyala, Rajashekharam V.
- Golden, Stephen J.
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출원인 / 주소 |
|
대리인 / 주소 |
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인용정보 |
피인용 횟수 :
2 인용 특허 :
10 |
초록
▼
A catalyst system and a method for reducing nitrogen oxides in an exhaust gas by reduction with a hydrocarbon or oxygen-containing organic compound reducing agent are provided. The catalyst system contains a silver catalyst and a modifier catalyst, where the modifier catalyst contains a modifier oxi
A catalyst system and a method for reducing nitrogen oxides in an exhaust gas by reduction with a hydrocarbon or oxygen-containing organic compound reducing agent are provided. The catalyst system contains a silver catalyst and a modifier catalyst, where the modifier catalyst contains a modifier oxide, where the modifier oxide is selected from the group consisting of iron oxide, cerium oxide, copper oxide, manganese oxide, chromium oxide, a lanthanide oxide, an actinide oxide, molybdenum oxide, tin oxide, indium oxide, rhenium oxide, tantalum oxide, osmium oxide, barium oxide, calcium oxide, strontium oxide, potassium oxide, vanadium oxide, nickel oxide, tungsten oxide, and mixtures thereof. The modifier oxide is supported on an inorganic oxide support or supports, where at least one of the inorganic oxide supports is an acidic support. The catalyst system of the silver catalyst and the modifier catalyst provides higher NOx conversion than either the silver catalyst or the modifier catalyst alone.
대표청구항
▼
1. A catalyst system for removing nitrogen oxides from an exhaust gas by reduction with a reducing agent selected from the group consisting of hydrocarbons and oxygen-containing organic compounds, wherein said exhaust gas contains nitrogen oxides and oxygen in an amount larger than a stoichiometric
1. A catalyst system for removing nitrogen oxides from an exhaust gas by reduction with a reducing agent selected from the group consisting of hydrocarbons and oxygen-containing organic compounds, wherein said exhaust gas contains nitrogen oxides and oxygen in an amount larger than a stoichiometric amount relative to unburned components in said exhaust gas, said catalyst system having an inlet side and an outlet side, said catalyst system comprising: a first catalyst comprising: approximately 0.2 to approximately 15 weight percent of at least one silver component selected from the group consisting of silver and silver compounds; andat least one first inorganic oxide support, wherein the silver component is supported on the first inorganic oxide support; anda second catalyst comprising: approximately 1 to approximately 30 weight percent of a modifier oxide comprising cerium oxide, copper oxide and manganese oxide, wherein the catalyst system does not comprise tungsten oxide or vanadium oxide; andat least one second inorganic oxide support comprising at least one zeolite, wherein at least one of the second inorganic oxide supports is an acidic inorganic oxide support, wherein the modifier oxide is supported on the second inorganic oxide support, wherein the weight percent of the silver component is on the basis of silver metal relative to the weight of the first inorganic oxide support, and wherein the weight percent of the modifier oxide is on the basis of the corresponding metal relative to the weight of the second inorganic oxide support said first catalyst and said second catalyst being disposed in that order from the inlet side to the outlet side of said catalyst system. 2. The catalyst system of claim 1, wherein at least a portion of the at least one zeolite is at least partially exchanged with at least one element selected from the group consisting of a Group 1A element, a Group 1B element, a Group IIA element, A Group IIB element, a Group IIIB element, a rare earth, and mixtures thereof. 3. The catalyst system of claim 1, wherein at least a portion of the at least one zeolite is in a form selected from the group consisting of the ammonium form and the protonic form. 4. The catalyst system of claim 1, wherein the at least one zeolite is selected from the group consisting of ZSM-5 and beta-zeolite and mixtures of these. 5. The catalyst system of claim 1, wherein at least one of the first catalyst and the second catalyst is supported on a substrate. 6. The catalyst system of claim 1, wherein at least one of the first catalyst and the second catalyst is formed into a shape. 7. The catalyst system of claim 6, wherein at least one of the first catalyst and the second catalyst is an extruded catalyst. 8. The catalyst system of claim 1, wherein said second catalyst further comprises an oxygen storage material. 9. The catalyst system of claim 8, wherein said oxygen storage material is a cerium oxide-based material. 10. The catalyst system of claim 1, wherein said reducing agent comprises ethanol. 11. The catalyst system of claim 1, wherein the modifier oxide is selected from the group consisting of iron oxide, cerium oxide, or mixtures of cerium and copper oxide. 12. The catalyst system of claim 11, wherein the modifier oxide comprises cerium oxide or a combination of copper oxide and cerium oxide. 13. A catalyst system of claim 1, wherein, at a given ratio of reducing agent to the nitrogen oxides, an activity of said catalyst system improves over time. 14. A catalyst system of claim 1, wherein an amount of said reducing agent that is required to reduce said nitrogen oxides decreases over time. 15. A method for removing nitrogen oxides from an exhaust gas by reduction with a reducing agent selected from the group consisting of hydrocarbons and oxygen-containing organic compounds, wherein said exhaust gas contains nitrogen oxides and oxygen in an amount larger than a stoichiometric amount relative to unburned components in said exhaust gas, said method comprising: disposing a catalyst system having an inlet side and an outlet side in a flow path of said exhaust gas containing from 1 to 1000 ppm of NOx;introducing into said exhaust gas at least one reducing agent selected from the group consisting of hydrocarbons and oxygen-containing organic compounds on the inlet side of said catalyst system;bringing the resulting exhaust gas containing the reducing agent into contact with said catalyst system at a temperature of approximately 150° C. to approximately 650° C., thereby reacting said nitrogen oxides with said reducing agent to remove said nitrogen oxides by reduction; said catalyst system comprising: a first catalyst comprising: approximately 0.2 to approximately 15 weight percent of at least one silver component selected from the group consisting of silver and silver compounds; andat least one first inorganic oxide support, wherein the silver component is supported on the first inorganic oxide support; anda second catalyst comprising: approximately 1 to approximately 30 weight percent of a modifier oxide selected from the group consisting of iron oxide, cerium oxide, mixtures of cerium oxide and copper oxide, manganese oxide, and mixtures thereof, wherein the catalyst system does not comprise tungsten oxide or vanadium oxide; andat least one second inorganic oxide support comprising at least one zeolite, wherein at least one of the second inorganic oxide supports is an acidic inorganic oxide support, wherein the modifier oxide is supported on the second inorganic oxide support, wherein the weight percent of the silver component is on the basis of silver metal relative to the weight of the first inorganic oxide support, and wherein the weight percent of the modifier oxide is on the basis of the corresponding metal relative to the weight of the second inorganic oxide support, said first catalyst and said second catalyst being disposed in that order from the inlet side to the outlet side of said catalyst system. 16. The method of claim 15, wherein the exhaust gas containing from 1 to 1000 ppm of NOx and ethanol as said reducing agent, is brought into contact with said catalyst system at a temperature of approximately 300° C. to approximately 500° C. 17. An exhaust gas treatment apparatus comprising: a catalyst system for removing nitrogen oxides from an exhaust gas by reduction with a reducing agent selected from the group consisting of hydrocarbons and oxygen-containing organic compounds, wherein said exhaust gas contains nitrogen oxides and oxygen in an amount larger than a stoichiometric amount relative to unburned components in said exhaust gas, said catalyst system having an inlet side and an outlet side, said catalyst system comprising: a first catalyst comprising: approximately 0.2 to approximately 15 weight percent of at least one silver component selected from the group consisting of silver and silver compounds; andat least one first inorganic oxide support, wherein the silver component is supported on the first inorganic oxide support; anda second catalyst comprising: approximately 1 to approximately 30 weight percent of a modifier oxide selected from the group consisting of iron oxide, cerium oxide, mixtures of cerium oxide and copper oxide, manganese oxide, and mixtures thereof, wherein the catalyst system does not comprise tungsten oxide or vanadium oxide; andat least one second inorganic oxide support comprising at least one zeolite, wherein at least one of the second inorganic oxide supports is an acidic inorganic oxide support, wherein the modifier oxide is supported on the second inorganic oxide support, wherein the weight percent of said the silver component is on the basis of silver metal relative to the weight of the first inorganic oxide support, and wherein the weight percent of the modifier oxide is on the basis of the corresponding metal relative to the weight of the second inorganic oxide support, said first catalyst and said second catalyst being disposed in that order from the inlet side to the outlet side of said catalyst system, and further wherein the catalyst system does not comprise an oxidation catalyst downstream from the second catalyst;an exhaust gas source;a reservoir of reducing agent; anda means for introducing reducing agent from said reservoir into the exhaust gas generated by said exhaust gas source, wherein said exhaust gas contains nitrogen oxides and wherein said reducing agent is introduced into said exhaust gas on the inlet side of said catalyst system. 18. A method for removing nitrogen oxides from an exhaust gas by reduction with an alcohol reducing agent, wherein said exhaust gas contains nitrogen oxides and oxygen in an amount larger than a stoichiometric amount relative to unburned components in said exhaust gas, said method comprising: disposing a catalyst system having an inlet side and an outlet side in a flow path of said exhaust gas;introducing into said exhaust gas said at least one reducing agent selected from the group consisting of hydrocarbons and oxygen-containing organic compounds on the inlet side of said catalyst system;bringing the resulting exhaust gas containing the reducing agent into contact with said catalyst system at a temperature of approximately 150° C. to approximately 650° C., thereby reacting said nitrogen oxides with said reducing agent to remove said nitrogen oxides by reduction;said catalyst system comprising a first catalyst comprising a selective catalytic reduction catalyst; anda second catalyst comprising: approximately 1 to approximately 30 weight percent of a modifier oxide mixture comprising mixtures of cerium oxide and copper oxide, wherein the wherein the catalyst system does not comprise tungsten oxide or vanadium oxide; andat least one second inorganic oxide support comprising at least one zeolite, wherein at least one of the second inorganic oxide supports is an acidic inorganic oxide support, wherein the modifier oxide is supported on the second inorganic oxide support, wherein the weight percent of the modifier oxide is on the basis of the corresponding metal relative to the weight of the second inorganic oxide support, said first catalyst and said second catalyst being disposed in that order from the inlet side to the outlet side of said catalyst system.
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