Coated articles and/or devices with optical out-coupling layer stacks (OCLS), and/or methods of making the same
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
G06F-003/045
H01B-007/02
출원번호
US-0488779
(2012-06-05)
등록번호
US-8608525
(2013-12-17)
발명자
/ 주소
Veerasamy, Vijayen S.
출원인 / 주소
Guardian Industries Corp.
대리인 / 주소
Nixon & Vanderhye P.C.
인용정보
피인용 횟수 :
1인용 특허 :
18
초록▼
Certain example embodiments relate to organic light emitting diode (OLED) inclusive devices, and/or methods of making the same. A substrate supports a transparent conductive coating (TCC) based layer, and first and second organic layers disposed thereon. A reflective conductive layer is supported by
Certain example embodiments relate to organic light emitting diode (OLED) inclusive devices, and/or methods of making the same. A substrate supports a transparent conductive coating (TCC) based layer, and first and second organic layers disposed thereon. A reflective conductive layer is supported by the organic layers. An out-coupling layer stack (OCLS) interposed between the organic layers and a viewer of the device includes a hybrid organic-inorganic polymer matrix having scatterers dispersed throughout in a manner such that each scatterer is located in the far field of its nearest neighbor. The scatterers are dispersed to have a high Zeta potential, and promote Mie-like scattering of light passing through the OCLS. Mie-like scattering caused by the OCLS may help to frustrate the wave-guiding modes in the glass, e.g., by breaking down the in-phase coherence.
대표청구항▼
1. A method of making an electronic device, the method comprising: disposing an optical out-coupling layer stack (OCLS), directly or indirectly, on a substrate;disposing a layer comprising a transparent conductive coating (TCC), directly or indirectly, on the OCLS;disposing one or more light emittin
1. A method of making an electronic device, the method comprising: disposing an optical out-coupling layer stack (OCLS), directly or indirectly, on a substrate;disposing a layer comprising a transparent conductive coating (TCC), directly or indirectly, on the OCLS;disposing one or more light emitting layers, directly or indirectly, on the layer comprising the TCC; anddisposing a layer comprising conductive material, directly or indirectly, on the one or more light emitting layers,wherein the OCLS comprises an isotropic layer matrix including an organo-metallic chelate hybrid material and a matrix core including dispersed scatterers,wherein the OCLS has an index of refraction of at least about 1.8, andwherein the dispersed scatterers have a Mie-like scattering efficiency of greater than 1, leading to an index matching out-coupling efficiency for the OCLS of greater than 1. 2. The method of claim 1, wherein the matrix includes a polymeric monomer to which oxo-clusters are added. 3. The method of claim 2, wherein the oxo-clusters include Ti, Hf, and/or Zr oxo-clusters. 4. The method of claim 2, wherein polymerization of the monomer is performed in the presence of 10-30% by weight of Zr4O2(OMc)12. 5. The method of claim 1, wherein the matrix at least initially has an organic surface including Ti16O16(OEt)32 that is modified and/or is modifiable by via alcoholysis. 6. The method of claim 5, wherein the alcoholysis creates new functional clusters including Ti16O16(OEt)32-x(OR)x. 7. The method of claim 6, wherein R is a methacrylate or styrene, and x is the number of modified alkoxys, x being between 4 and 16, inclusive. 8. The method of claim 1, wherein the scatterers are generally spherical and/or generally cylindrical. 9. The method of claim 1, wherein a filling density of the scatterers is in a range of values such that the scatterers are mono-dispersed with an inter-particle distance d of about 3 diameters or major distances. 10. The method of claim 9, wherein each scatterer is located in the far field of its nearest neighbor and there is no systematic phase relationship, except for coherent exact forward scattering. 11. The method of claim 9, wherein the refractive index for the OCLS is 1.8-1.9, and the absorption coefficient for the OCLS is at or near 0. 12. The method of claim 1, wherein the electronic device is an organic light emitting diode (OLED) inclusive device, wherein the one or more light emitting layers comprises first and second organic layers, and wherein the layer comprising conductive material is reflective. 13. The method of claim 1, further comprising disposing a planarization layer between the matrix and the layer comprising the TCC. 14. The method of claim 13, wherein the RMS roughness of the planarization layer is less than 1.0 nm. 15. The method of claim 14, wherein the planarization layer comprises a zinc-based chelate. 16. A method of making an organic light emitting diode (OLED) inclusive device, the method comprising: disposing a layer comprising a transparent conductive coating (TCC), directly or indirectly, on a glass substrate;disposing first and second organic layers, directly or indirectly, on the layer comprising the TCC;disposing a layer comprising a conductive material, directly or indirectly, on the one or more light emitting layers, the layer comprising conductive material being reflective; anddisposing an optical out-coupling layer stack (OCLS), directly or indirectly, on the substrate, the OCLS including an isotropic layer matrix including an organo-metallic chelate hybrid matrix with scatterers dispersed therein,wherein a relative refractive index m of the OCLS, a size r of the scatterers, and a concentration of the scatterers (1/s3) are selected so as to increase the total integrated light out-coupled from the device to a level where total out-coupling efficiency for the device is greater than it would, if no OCLS were provided. 17. The method of claim 16, wherein the matrix includes a polymeric monomer to which oxo-clusters are added. 18. The method of claim 17, wherein the scatterers are generally spherical and have a Zeta potential greater than 70 mV. 19. The method of claim 16, wherein a filling density of the scatterers is in a range of values such that the scatterers are mono-dispersed with an inter-particle distance d of about 3 diameters or major distances. 20. The method of claim 16, wherein the OCLS is located on a surface of the substrate opposite the first and second organic layers.
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