초록 ▼

Bisurea gelling agents that impart a number of unexpected benefits within various gelled formulations and exhibit great versatility in terms of gelling capabilities for many types of solvents are provided. Such gelling agents should include pendant groups, such as sterically hindering alkyl groups a

Bisurea gelling agents that impart a number of unexpected benefits within various gelled formulations and exhibit great versatility in terms of gelling capabilities for many types of solvents are provided. Such gelling agents should include pendant groups, such as sterically hindering alkyl groups attached to polyoxyalkylenated moieties that allow the gelling agent to be compatible with the target liquid system at elevated temperatures, while controlling and/or limiting the network formation and strength during the cooling cycle. Alternatively, novel gelling agents having two urea groups but that are asymmetrical in configuration have been produced in order to provide the same control in temperature, compatibility, and efficiency. Final gelled formulations, such as antiperspirant sticks and other like consumer items, are provided as well within this invention.

대표청구항 ▼

1. A gelled solvent system comprising at least one gelling agent represented by the structure of Formula (I) wherein R is a C3-C18 linear, branched, or cyclic moiety; and R′ and R″ may be the same or different and are selected from the group consisting of C1-C36 linear or branched alkanes or aryl al

1. A gelled solvent system comprising at least one gelling agent represented by the structure of Formula (I) wherein R is a C3-C18 linear, branched, or cyclic moiety; and R′ and R″ may be the same or different and are selected from the group consisting of C1-C36 linear or branched alkanes or aryl alkanes, α-methyl branched C2-C36 alkanes, α-methyl branched C2-C36 ethers, β-methyl branched C2-C36 alkanes, and β-methyl branched C2-C36 ethers;wherein if R′ and R″ are the same, then both of said groups is selected from the group consisting of α-methyl branched C2-C18 ethers and β-methyl branched C2-C18 ethers;wherein L and L′ may be same or different and are selected from the group consisting of ethylene oxide chains, propylene oxide chains, and mixtures thereof, and the chains may comprise one or a plurality of repeat units;wherein the system is a pourable liquid above the dissolution temperature and the system is a stable gel below the gelling temperature;wherein the system is pH stable in the range from pH=2 to pH=12; andwherein the system is water resistant and has superior adhesion properties. 2. The gelled solvent system of claim 1, wherein said system comprises at least about 1% of a wax component by weight and at least about 0.1% to about 20% by weight of said at least one gelling agent. 3. The gelled solvent system of claim 1, wherein when said system comprises a fragrance, and wherein the fragrance evaporation rate is lower than that of a solvent system without the gelling agent. 4. The gelled solvent system of claim 1, wherein the at least one gelling agent exhibits a gel temperature of at least 20° C. and a dissolution temperature of at most 200° C. in a non-polar solvent. 5. The gelled solvent system of claim 1, wherein said system includes at least one non-polar solvent. 6. The gelled solvent system of claim 5, wherein the non-polar solvent has a dielectric constant of less than or equal to 15.0. 7. The gelled solvent system of claim 5, wherein the non-polar solvent has a dielectric constant of less than or equal to 10.0. 8. The gelled solvent system of claim 5, wherein the non-polar solvent has a dielectric constant of less than or equal to 5.0. 9. The gelled solvent system of claim 5, wherein the non-polar solvent has a dielectric constant of less than or equal to 4.0. 10. The gelled solvent system of claim 5, wherein the non-polar solvent is an aprotic solvent. 11. The gelled solvent system of claim 1, wherein the gelled solvent system is clear. 12. The gelled solvent system of claim 1, wherein the gelled solvent system contains between about 0.001% and about 20.0% of the at least one gelling agent. 13. The gelled solvent system of claim 1, wherein the gelled solvent system contains between about 0.001% and about 15.0% of the at least one gelling agent. 14. The gelled solvent system of claim 1, wherein the gelled solvent system contains between about 0.001% and about 10.0% of the at least one gelling agent. 15. The gelled solvent system of claim 1, wherein the gelled solvent system contains between about 0.001% and about 5.0% of the at least one gelling agent. 16. The gelled solvent system of claim 1, wherein the gelled solvent system contains between about 0.001% and about 4.0% of the at least one gelling agent. 17. An antiperspirant gel formulation comprising: (i) at least one gelling represented by the structure of Formula (I) wherein R is a C3-C18 linear, branched, or cyclic moiety; and R′ and R″ may be the same or different and are selected from the group consisting of C1-C36 linear or branched alkanes or aryl alkanes, α-methyl branched C2-C36 alkanes, α-methyl branched C2-C36 ethers, β-methyl branched C2-C36 alkanes, and β-methyl branched C2-C36 ethers;wherein if R′ and R″ are the same, then both of said groups is selected from the group consisting of α-methyl branched C2-C18 ethers and β-methyl branched C2-C18 ethers;wherein L and L′ may be same or different and are selected from the group consisting of ethylene oxide chains, propylene oxide chains, and mixtures thereof, and the chains may comprise one or a plurality of repeat units;(ii) at least one antiperspirant solvent component, and(iii) at least one antiperspirant active;wherein the gel formulation is a pourable liquid above the dissolution temperature and the system is a stable gel below the gelling temperature;wherein the gel formulation is pH stable in the range from pH=2 to pH=12; andwherein the gel formulation is water resistant and has superior adhesion properties. 18. The antiperspirant gel formulation of claim 17, wherein the formulation is clear. 19. A cosmetic gel formulation comprising at least one gelling agent represented by the structure of Formula (I), at least one cosmetic solvent component, and at least one cosmetic active. 20. The cosmetic gel formulation of claim 19, wherein the formulation is clear. 21. A candle gel formulation comprising: (i) at least one gelling represented by the structure of Formula (I) wherein R is a C3-C18 linear, branched, or cyclic moiety; and R′ and R″ may be the same or different and are selected from the group consisting of C1-C36 linear or branched alkanes or aryl alkanes, α-methyl branched C2-C36 alkanes, α-methyl branched C2-C36 ethers, β-methyl branched C2-C36 alkanes, and β-methyl branched C2-C36 ethers;wherein if R′ and R″ are the same, then both of said groups is selected from the group consisting of α-methyl branched C2-C18 ethers and β-methyl branched C2-C18 ethers;wherein L and L′ may be same or different and are selected from the group consisting of ethylene oxide chains, propylene oxide chains, and mixtures thereof, and the chains may comprise one or a plurality of repeat units; and(ii) at least one candle solvent component;wherein the gel formulation is a pourable liquid above the dissolution temperature and the system is a stable gel below the gelling temperature;wherein the gel formulation is pH stable in the range from pH=2 to pH=12; andwherein the gel formulation is water resistant and has superior adhesion properties. 22. The candle gel formulation of claim 21, wherein the formulation is clear. 23. A gelled solvent system comprising at least one gelling agent represented by the structure of Formula (I) wherein R is a C3-C18 linear or branched alkylene chain or an aromatic ring; and R′ and R″ may be the same or different and are selected from the group consisting of C1-C36 linear or branched alkanes or aryl alkanes, α-methyl branched C2-C36 alkanes, α-methyl branched C2-C36 ethers, β-methyl branched C2-C36 alkanes, and β-methyl branched C2-C36 ethers;wherein if R′ and R″ are the same, then both of said groups is selected from the group consisting of α-methyl branched C2-C18 ethers and β-methyl branched C2-C18 ethers;wherein L and L′ may be same or different and are selected from the group consisting of ethylene oxide chains, propylene oxide chains, and mixtures thereof, and the chains may comprise one or a plurality of repeat units;wherein the system is a pourable liquid above the dissolution temperature and the system is a stable gel below the gelling temperature;wherein the system is pH stable in the range from pH=2 to pH=12; andwherein the system is water resistant and has superior adhesion properties. 24. The gelled solvent system of claim 23, wherein the at least one gelling agent exhibits a gel temperature of at least 20° C. and a dissolution temperature of at most 200° C. in a non-polar solvent. 25. The gelled solvent system of claim 23, wherein said system includes at least one non-polar solvent. 26. A gelled solvent system comprising at least one gelling agent represented by the structure of Formula (I) wherein R is a C3-C18 linear, branched or cyclic moiety selected from the group consisting of unsubstituted or substituted phenyl, phenyl ether, and phenyl methylene; and R′ and R″ may be the same or different and are selected from the group consisting of C1-C36 linear or branched alkanes, α-methyl branched C2-C36 alkanes or aryl alkanes, α-methyl branched C2-C36 ethers, β-methyl branched C2-C36 alkanes, and β-methyl branched C2-C36 ethers;wherein if R′ and R″ are the same, then both of said groups is selected from the group consisting of α-methyl branched C2-C18 ethers and β-methyl branched C2-C18 ethers;wherein L and L′ may be same or different and are selected from the group consisting of ethylene oxide chains, propylene oxide chains, and mixtures thereof, and the chains may comprise one or a plurality of repeat units;wherein the system is a pourable liquid above the dissolution temperature and the system is a stable gel below the gelling temperature;wherein the system is pH stable in the range from pH=2 to pH=12; andwherein the system is water resistant and has superior adhesion properties. 27. The gelled solvent system of claim 26, wherein the at least one gelling agent exhibits a gel temperature of at least 20° C. and a dissolution temperature of at most 200° C. in a non-polar solvent. 28. The gelled solvent system of claim 26, wherein said system includes at least one non-polar solvent. 29. A gelled solvent system comprising a mixture of at least one gelling agent represented by the structure of Formula (I), wherein R is a C3-C18 linear, branched, or cyclic moiety; and R′ and R″ may be the same or different and are selected from the group consisting of C1-C36 linear or branched alkanes or aryl alkanes, α-methyl branched C2-C36 alkanes, α-methyl branched C2-C36 ethers, β-methyl branched C2-C36 alkanes, and β-methyl branched C2-C36 ethers;wherein if R′ and R″ and the same, then both of said groups is selected from the group consisting of α-methyl branched C2-C18 ethers and β-methyl branched C2-C18 ethers;wherein L and L′ may be same or different and are selected from the group consisting of ethylene oxide chains, propylene oxide chains, and mixtures thereof, and the chains may comprise one or a plurality of repeat units, and one compound represented by the structure of Formula (II) or Formula (III), wherein R is a C3-C18 linear, branched, or cyclic moiety; and R′ is selected from the group consisting of C2-C36 linear or branched alkanes or aryl alkanes, α-methyl branched C2-C36 alkanes, α-methyl branched C2-C36 ethers, β-methyl branched C2-C36 alkanes, and β-methyl branched C2-C36 ethers;wherein L′ is selected from the group consisting of ethylene oxide chains, propylene oxide chains, and mixtures thereof, and the chains may comprise one or a plurality of repeat units;wherein R″′ is selected from the group consisting of H, CH3, C2-C36 linear or branched alkanes or aryl alkanes, α-methyl branched C2-C36 alkanes, α-methyl branched C2-C36 ethers, β-methyl branched C2-C36 alkanes, and β-methyl branched C2-C36 ethers; wherein x=0 or 1 and L″ is selected from the group consisting of ethylene oxide chains, propylene oxide chains, and mixtures thereof, and the chains may comprise one or a plurality of repeat units, wherein R is a C3-C18 linear, branched, or cyclic moiety, and R′ and R″′ are selected from the group consisting of H, CH3, C2-C36 linear or branched alkanes or aryl alkanes, α-methyl branched C2-C36 alkanes, α-methyl branched C2-C36 ethers, β-methyl branched C2-C36 alkanes, and β-methyl branched C2-C36 ethers;wherein x=0 or 1 and y=0 or 1 and, L′ and L″ are selected from the group consisting of ethylene oxide chains, propylene oxide chains, and mixtures thereof, and the chains may comprise one or a plurality of repeat units;wherein the system is a pourable liquid above the dissolution temperature and the system is a stable gel below the gelling temperature;wherein the system is pH stable in the range from pH=2 to pH=12; andwherein the system is water resistant and has superior adhesion properties.