초록 ▼

This invention describes the use of a fluidized bed reactor in the carbonation of a solid, inorganic and alkaline particulate material which contains alkaline metal salts. It also describes a method for treating cement kiln dust (CKD) containing alkaline metal salts. The treatment method comprises t

This invention describes the use of a fluidized bed reactor in the carbonation of a solid, inorganic and alkaline particulate material which contains alkaline metal salts. It also describes a method for treating cement kiln dust (CKD) containing alkaline metal salts. The treatment method comprises two steps: (a) a hydration step; and (b) a carbonation step, wherein the carbonation step is carried out in a fluidized bed reactor. In a preferred aspect of the present invention, the treated CKD is used as an aggregate in sulfur polymer concrete (SPC). Accordingly, the present invention also provides a method for producing SPC, which method comprises heating and mixing treated CKD of the present invention, elemental sulfur and modified sulfur to produce a mixture. The SPC can be used as a barrier to restrict permeation of matter, e.g. in a containment construction for storing matter such as hazardous waste.

대표청구항 ▼

1. A method for the carbonation of a solid, inorganic and alkaline particulate material which contains alkaline metal salts, which method uses a fluidized bed reactor to effect the carbonation, wherein the material is hydrated cement kiln dust (CKD) having a moisture content of 20% by weight or less

1. A method for the carbonation of a solid, inorganic and alkaline particulate material which contains alkaline metal salts, which method uses a fluidized bed reactor to effect the carbonation, wherein the material is hydrated cement kiln dust (CKD) having a moisture content of 20% by weight or less. 2. A method for treating CKD containing alkaline metal salts, which method comprises (1) a hydration step, (2) a drying step and (3) a carbonation step, wherein the carbonation step is carried out in a fluidized bed reactor, and wherein if the hydrated CKD resulting from step (2) comprises particles greater than 10 mm in size at their widest point the method further comprises a fractionating step between steps (2) and (3), which fractionating step involves removing particles greater than 10 mm in size at their widest point. 3. A method according to claim 2 wherein in the hydration step the CKD is mixed with water at a temperature of 35-40° C. for a total time of at least 20 minutes, wherein the weight ratio of CKD to water is from 1:1 to 3:1. 4. A method for treating CKD according to claim 2 in which the hydration step involves mixing the CKD and the water at 400 to 800 rpm for 10 to 30 minutes. 5. A method according to claim 2 wherein in the drying step the moisture content of the hydrated CKD is reduced to less than 20% by weight. 6. A method according to claim 5 wherein the drying step involves heating the hydrated CKD to reduce the moisture content of the hydrated CKD to 7 to 12% by weight. 7. A method according to claim 2 in which the drying step is done at 70 to 90° C. for a period of 12 to 48 hours. 8. A method according to claim 2 which includes a fractionating step after the drying step but before the carbonation step, which fractionating step involves removing particles greater than 2 mm at their widest point, and is carried out by sieving. 9. A method according to claim 2 wherein the carbonation step comprises exposing the hydrated CKD to a source of carbon dioxide. 10. A method according to claim 9 wherein in step (3) the hydrated CKD is exposed to carbon dioxide gas at a pressure of 1 to 2 bar for 20 to 60 minutes. 11. A method according to claim 2 wherein the flow rate of the gas fed into the fluidized bed reactor in the carbonation step is at least 2 liter/min. 12. A method according to claim 2 wherein the carbonation step is carried out at 20 to 30° C. 13. A method according to claim 9 in which during the carbonation step carbon dioxide gas is injected into the base of the reactor chamber of the fluidized bed reactor via one or more inlets located around a conical distributor in the base of the reactor chamber. 14. A method according to claim 2 wherein the pH of the CKD to be treated is from 12 to 12.5. 15. A method according to claim 2 wherein at least 25 g of CO2 is consumed in carbonation for each 100 g of hydrated CKD. 16. A method according to claim 15 wherein the amount of CO2 consumed in carbonation for each 100 g of hydrated CKD is measured using thermo-gravimetric analyzer, a temperature range of 50 to 1000° C. and a heating rate of 20° C./min. 17. A method according to claim 16 wherein the measured amount of CO2 consumed in carbonation represents at least 90% of the theoretical maximum amount. 18. A method according to claim 2, which is a method for treating waste CKD containing alkaline metal salts comprising the steps of: a.) providing a mass of CKD containing alkaline metal salts and a mass of water;b.) mixing the kiln dust and water to form a mixture containing calcium hydroxide by the hydration process;c.) drying the mixture from step b;d.) fractionating the dried mixture from step c by sieving;e.) providing a fluidized bed reactor; andf.) carbonating the dried fractionated and hydrated mixture from step d with cement kiln exhaust gas containing a pollutant selected from the group consisting of acidic oxides of sulfur, nitrogen, carbon, halogen compounds and mixtures thereof in the fluid bed reactor to form a stable material. 19. A fluidized bed reactor apparatus suitable for use in the carbonation step as defined in claim 2, wherein the fluidized bed reactor has a reactor chamber, and in the lower half of the reactor chamber there are one or more inlets for entry of gas into the reactor chamber, the inlets being located around a conical distributor in the base of the reactor chamber. 20. Treated CKD which leaches less than 200 mg/l SO42−, less than 800 mg/l Cl−, less than 15 mg/l Cr, less than 1 mg/l Sr, less than 300 mg/l Ca, less than 1000 mg/l K and/or less than 150 mg/l Na, when tested according to the British Standard BS EN12457: 2002, using the short term (6 hr) test with a ratio of water to CKD of 2 L/Kg. 21. Treated CKD according to claim 20, which has a pH of less than 10. 22. Treated CKD according to claim 20, which has a mean particle size of less than 5 μm. 23. Treated CKD obtained or obtainable by a method as defined in claim 2. 24. A method of using treated CKD as defined in claim 20 (i) as an aggregate in concrete, (ii) in the neutralization of acid mine drainage or acidic soils, (iii) in a clinker making process, (iv) in the stabilization of soft soils, (v) in the treatment of expansive/swelling soils, (vi) backfilling, (vii) as a sub-base material, (viii) as a pozzolanic activator, or (ix) in asphalt pavement. 25. A method according to claim 24 wherein the treated CKD is used as an aggregate in sulfur polymer concrete (SPC) and the SPC is obtained or obtainable from a mixture comprising said treated CKD, elemental sulfur and modified sulfur. 26. A method according to claim 25 wherein said mixture further comprises fiber glass. 27. A method for manufacturing lime cement, which method uses treated CKD as defined in claim 20. 28. A method of producing SPC, which method comprises heating and mixing treated CKD as defined in claim 20, elemental sulfur and modified sulfur to produce a mixture. 29. A method according to claim 28, which further comprises mixing sand and/or glass fibers with the other components in producing the mixture. 30. A method according to claim 29, which comprises mixing 40-45% by weight of the elemental sulfur, 0.2-2% by weight of the modified sulfur, 20-25% by weight of the treated CKD, 30-40% by weight of the sand and 0-1% by weight of the glass fibers, wherein the % by weight is based on the total weight of the mixture. 31. A method according to claim 28, which comprises subjecting the mixture to a temperature of 130-150° C. for 30 minutes to 2 hours. 32. A method according to claim 28, which comprises mixing together (i) sand which has been pre-heated to a temperature of 170-180° C., (ii) treated CKD which has been pre-heated to a temperature of 95-105° C., and (iii) a mixture of the elemental sulfur and modified sulfur, and then subjecting the mixture of (i), (ii) and (iii) to a temperature of 130-150° C. for 20-40 minutes, casting the resulting mixture into a mold and allowing it to cool.