Provided an antimicrobial substance that includes a base material layer, and a copper-tin alloy layer 5-200 nm in thickness disposed on the base material layer, the copper-tin alloy layer containing copper in an amount of more than 60 atomic percent but not more than 90 atomic percent, and containin
Provided an antimicrobial substance that includes a base material layer, and a copper-tin alloy layer 5-200 nm in thickness disposed on the base material layer, the copper-tin alloy layer containing copper in an amount of more than 60 atomic percent but not more than 90 atomic percent, and containing tin in an amount of not less than 10 atomic percent but less than 40 atomic percent. The copper-tin alloy layer includes a Cu41Sn11 crystalline phase, and a Cu3Sn crystalline phase. The Q value (Ω/(nm·Cu atomic percent)), which is derived by dividing the sheet resistance (Ω) of the copper-tin alloy layer by the thickness of the copper-tin alloy layer and the copper content (Cu atomic percent), is 1.5×10−4-6.0×10−4.
대표청구항▼
1. An antimicrobial raw material comprising: a substrate layer; anda copper-tin alloy layer disposed on the substrate layer, the copper-tin alloy layer containing over 60 atomic % to 90 atomic % of copper and 10 atomic % to less than 40 atomic % of tin, whereinthe copper-tin alloy layer comprises a
1. An antimicrobial raw material comprising: a substrate layer; anda copper-tin alloy layer disposed on the substrate layer, the copper-tin alloy layer containing over 60 atomic % to 90 atomic % of copper and 10 atomic % to less than 40 atomic % of tin, whereinthe copper-tin alloy layer comprises a Cu41Sn11 crystalline phase and a Cu3Sn crystalline phase; anda Q value (Ω/(nm·Cu atomic %)) obtained by dividing a sheet resistance (Ω) of the copper-tin alloy layer by a product of a thickness of the copper-tin alloy layer and a copper content (Cu atomic %) in the copper-tin alloy layer is 1.5×10−4 to 6.0×10−4. 2. The antimicrobial raw material according to claim 1, wherein the substrate layer is made of resin, natural fiber or paper, the resin, natural fiber or paper having a temperature under load of 115° C. or below as measured in accordance with ASTM-D648-56 under a load of 1,820 kPa. 3. The antimicrobial raw material according to claim 1, wherein a ratio of the Cu41Sn11 crystalline phase to the Cu3Sn crystalline phase in the copper-tin alloy layer, Cu41Sn11/Cu3Sn, is 0.002 to 0.040. 4. The antimicrobial raw material according to claim 1, wherein a surface roughness Rz of a surface of the copper-tin alloy layer, the surface being remote from the substrate layer, is 14.4 to 15.9 nm. 5. The antimicrobial raw material according to claim 1, wherein the substrate layer is made of polyethylene terephthalate, polyethylene naphthalate, polypropylene, polyethylene, or polyimide. 6. The antimicrobial raw material according to claim 1, wherein the copper-tin alloy layer is formed by simultaneous vapor deposition using an evaporation source composed of a copper-tin alloy containing over 60 atomic % to 85 atomic % of copper and 15 atom % to less than 40 atom % of tin. 7. The antimicrobial raw material according to claim 1, wherein the copper-tin alloy layer covers the entire or part of an outermost surface of the antimicrobial raw material. 8. The antimicrobial raw material according to claim 1, wherein the substrate layer is a nonwoven fabric, woven fabric or yarn. 9. A method of producing the antimicrobial raw material according to claim 1, comprising: providing an evaporation source composed of a copper-tin alloy containing over 60 atomic % to 85 atomic % of copper and 15 atom % to less than 40 atom % of tin;heating a substrate disposed so as to face the evaporation source; andallowing a metal vapor, generated by gasifying the copper-tin alloy from the evaporation source, to contact the substrate heated to form thereon a copper-tin alloy layer. 10. The method of producing the antimicrobial raw material according to claim 9, wherein the heating of the substrate brings a temperature of the substrate to 100 to 125° C. 11. The method of producing the antimicrobial raw material according to claim 9, wherein the substrate is made of resin, natural fiber or paper, the resin, natural fiber or paper having a deflection temperature under load of 115° C. or below as measured in accordance with ASTM-D648-56 under a load of 1,820 kPa. 12. An antimicrobial material comprising the antimicrobial raw material according to claim 1. 13. The antimicrobial material according to claim 12, wherein the antimicrobial material is used as a touch panel protection film. 14. The antimicrobial material according to claim 12, wherein the antimicrobial material is used as medical material. 15. The antimicrobial material according to claim 12, wherein the antimicrobial material is used as purification material.
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이 특허에 인용된 특허 (7)
Burrell Robert E.,CAX ; Morris Larry Roy,CAX, Anti-microbial coating for medical devices.
Pavlich Mary J. (Morristown NJ), Polyurethane foam impregnated with or coated with fabric conditioning agent, anti-microbial agent and anti-discolorant.
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