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A system and method of treating an exhaust flow including nitrogen oxides (NOx) in a turbine engine power generation plant is provided. The turbine engine has a selective catalytic reduction system having a catalyst. During steady state operation of the engine, a reducing agent, such as ammonia, is

A system and method of treating an exhaust flow including nitrogen oxides (NOx) in a turbine engine power generation plant is provided. The turbine engine has a selective catalytic reduction system having a catalyst. During steady state operation of the engine, a reducing agent, such as ammonia, is supplied to an injector in an amount based on a measured molar flow of NOx in the exhaust flow. During a disturbance in the operation of the turbine engine, a reducing agent is supplied to the injector in an amount based on a predicted molar flow of NOx in the exhaust flow. In addition, the system can include a biasing feature in which additional reducing agent is supplied to the exhaust flow beyond the predicted molar flow of NOx. The system and method can mitigate NOx during transient engine operation, an operational mode in which emissions are difficult to predict and control.

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1. A method of treating an exhaust flow including nitrogen oxides in a turbine engine, the turbine engine having a selective catalytic reduction system having a catalyst, the turbine engine operating under steady state conditions, the method comprising the steps of: predicting a molar flow of nitrog

1. A method of treating an exhaust flow including nitrogen oxides in a turbine engine, the turbine engine having a selective catalytic reduction system having a catalyst, the turbine engine operating under steady state conditions, the method comprising the steps of: predicting a molar flow of nitrogen oxides in the exhaust flow;measuring a molar flow of nitrogen oxides in the exhaust flow;detecting a disturbance in the steady state operation of the turbine;determining the difference between the measured molar flow of nitrogen oxides in the exhaust flow and the predicted molar flow of nitrogen oxides in the exhaust flow to yield an error factor;applying the error factor to the predicted molar flow of nitrogen oxides in the exhaust flow so that the predicted molar flow equals the measured molar flow; andresponsive to detecting a disturbance, supplying a reducing agent to the exhaust flow upstream of the catalyst relative to the direction of exhaust flow and based on the predicted molar flow of nitrogen oxides with the error factor applied in the exhaust flow. 2. The method of claim 1 wherein the disturbance is a load ramp. 3. The method of claim 1 wherein the disturbance is a change in at least one of pilot fuel flow rate, duct burner fuel flow rate and premix fuel flow rate. 4. The method of claim 1 wherein the reducing agent is ammonia. 5. The method of claim 1 further including the step of selectively biasing the amount of reducing agent supplied to the exhaust flow upstream of the catalyst. 6. The method of claim 5 wherein the step of selectively biasing the supply of reducing agent is discontinued so that the supply of reducing agent to the exhaust flow upstream of the selective catalytic reduction system is based solely on the predicted molar flow of nitrogen oxides in the exhaust flow of the turbine. 7. The method of claim 1 further including the steps of: discontinuing the supplying step based on the predicted molar flow of nitrogen oxides in the exhaust flow of the turbine;measuring the molar flow of nitrogen oxides in the exhaust flow upstream of the selective catalytic reduction system;supplying a reducing agent to the exhaust flow upstream of the catalyst relative to the direction of exhaust flow and based on the measured molar flow of nitrogen oxides in the exhaust flow. 8. The method of claim 7 wherein the discontinuing step is performed after one of a predetermined amount of time has elapsed or the end of the disturbance. 9. The method of claim 1 wherein the predicting step comprises: determining a compressor molar flow rate;determining a fuel molar flow rate; anddetermining an exhaust molar flow rate by adding the determined compressor molar flow rate and the determined fuel molar flow rate. 10. The method of claim 9 wherein the step of determining a compressor molar flow rate comprises: determining a reference compressor mass flow rate;determining a weight of dry air inducted in engine;determining at least one correction factor;adjusting the determined reference compressor mass flow rate by the determined weight of dry air inducted in engine and the determined correction factor; anddividing the adjusted reference compressor mass flow rate by the molecular weight of air. 11. The method of claim 10 wherein the correction factor is at least one of a pressure correction factor and a gas turbine degradation factor. 12. The method of claim 10 wherein the turbine engine includes a compressor section with an evaporative cooler, wherein the evaporative cooler has an operational status of one of on or off, and further including the steps of: determining the operational status of the evaporative cooler;adjusting the steps of determining the reference compressor mass flow rate and the weight of dry air inducted in engine based on the operational status of the evaporative cooler. 13. The method of claim 9 wherein the step of determining a fuel molar flow rate comprises: measuring fuel flow in the turbine engine including at least one of pilot fuel flow and premix fuel flow; anddividing the measured fuel flow by the molecular weight of the fuel. 14. The method of claim 13 wherein the step of determining a fuel molar flow rate further includes measuring fuel flow in a duct burner. 15. The method of claim 1 wherein, when a disturbance is detected, further including the steps of holding the current error factor constant. 16. A selective catalytic reduction system for treating an exhaust flow including nitrogen oxides in a turbine engine comprising: a turbine engine having an exhaust section fluidly connected to receive an exhaust flow from a turbine section of the engine;a selective catalytic reduction system having an injector and a catalyst, the catalyst being disposed in the exhaust flow and downstream of the injector relative to the direction of exhaust flow;a reducing agent supply source in fluid communication with the injector by a fluid conduit;a flow control valve disposed along the fluid conduit; andan electronic control circuit operatively connected to flow control valve, the electronic control circuit comprising instructions which;determine the difference between a measured molar flow of nitrogen oxides in the exhaust flow and a predicted molar slow of nitrogen oxides in the exhaust flow to yield an error factor;apply the error factor to the predicted molar flow of nitrogen oxides in the exhaust flow so that the predicted molar flow equals the measured molar flowduring steady state operation of the turbine engine, direct the flow control valve to supply a reducing agent to the injector in an amount based on the measured molar flow of nitrogen oxides in the exhaust flow,during a disturbance in the operation of the turbine engine, direct the flow control valve to supply a reducing agent to the injector in an amount based on the predicted molar flow of nitrogen oxides with the applied error factor in the exhaust flow. 17. The system of claim 16 wherein the predicted molar flow of nitrogen oxides is determined by the summation of a compressor molar flow rate and a fuel molar flow rate. 18. The system of claim 17, wherein the error factor is the difference between the predicted molar flow of nitrogen oxides and the measured molar flow of nitrogen oxides upstream of the selective catalytic reduction system relative to the direction of the exhaust flow.