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Deep desulfurization of hydrocarbon feeds containing undesired organosulfur compounds to produce a hydrocarbon product having low levels of sulfur, i.e., 15 ppmw or less of sulfur, is achieved by hydrotreating the feed under mild conditions, and separating the hydrotreated effluent into an aromatic-

Deep desulfurization of hydrocarbon feeds containing undesired organosulfur compounds to produce a hydrocarbon product having low levels of sulfur, i.e., 15 ppmw or less of sulfur, is achieved by hydrotreating the feed under mild conditions, and separating the hydrotreated effluent into an aromatic-rich fraction which contains a substantial amount of the aromatic refractory and sterically hindered sulfur-containing compounds, and an aromatic-lean fraction. The aromatic-rich fraction is contacted with isomerization catalyst, and the isomerized aromatic-rich fraction is recycled to the mild hydrotreating process.

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1. A method of processing a hydrocarbon feed to reduce the concentration of undesired organosulfur compounds comprising: subjecting the hydrocarbon feed to a mild hydrotreating process effective to convert labile organosulfur compounds and produce a hydrotreated effluent containing converted compoun

1. A method of processing a hydrocarbon feed to reduce the concentration of undesired organosulfur compounds comprising: subjecting the hydrocarbon feed to a mild hydrotreating process effective to convert labile organosulfur compounds and produce a hydrotreated effluent containing converted compounds and unconverted sterically hindered refractory aromatic organosulfur compounds;separating the hydrotreated effluent into an aromatic-lean fraction that is recovered as a hydrotreated hydrocarbon product and an aromatic-rich fraction that contains sterically hindered refractory aromatic organosulfur compounds;contacting the aromatic-rich fraction with an isomerization catalyst in the presence of hydrogen to remove steric hindrance of certain compounds and produce an isomerized effluent including isomerate and any remaining unreacted hydrogen;flashing the isomerized effluent to produce a light isomerized effluent and a heavy isomerized effluent;recovering the light isomerized effluent; andrecycling at least a portion of the heavy isomerized effluent to the mild hydrotreating process. 2. The method of claim 1, further comprising, prior to contacting the aromatic-rich fraction with an isomerization catalyst, contacting the aromatic-rich fraction with an adsorbent material to reduce the nitrogen content to produce an adsorption effluent. 3. The method of claim 1, wherein separating the hydrotreated effluent into an aromatic-lean fraction and an aromatic-rich fraction comprises: subjecting the hydrotreated effluent and an effective quantity of extraction solvent to an extraction zone to produce an extract containing a major proportion of the aromatic content of the hydrotreated effluent and a portion of the extraction solvent anda raffinate containing a major proportion of the non-aromatic content of the hydrotreated effluent and a portion of the extraction solvent;separating at least substantial portion of the extraction solvent from the raffinate and retaining the aromatic-lean fraction;separating at least substantial portion of the extraction solvent from the extract and retaining the aromatic-rich fraction. 4. The method of claim 1, wherein the aromatic-lean fraction includes aliphatic organosulfur compounds. 5. The method of claim 4, wherein the aliphatic organosulfur compounds include one or more compounds selected from the group consisting of sulfides, disulfides, and mercaptans. 6. The method of claim 1, wherein the aromatic-rich fraction includes one or more compounds selected from the group consisting of benzothiophene, alkylated derivatives of benzothiophene, dibenzothiophene, alkyl derivatives of dibenzothiophene, benzonaphtenothiophene, and alkyl derivatives of benzonaphtenothiophene. 7. The method of claim 1, wherein the aromatic-rich fraction includes one or more compounds selected from the group consisting of aromatic nitrogen compounds including pyrrole, quinoline, acridine, carbazole and their derivatives. 8. The method of claim 2, wherein the step of contacting the aromatic-rich fraction with an adsorbent material comprises a. passing the aromatic-rich fraction through a first of two packed columns;b. transferring the aromatic-rich fraction from the first column to the second column while discontinuing passage through the first column;c. desorbing and removing nitrogen-containing compounds and/or poly-nuclear aromatic compounds from the adsorbent material in the first column to thereby regenerate the adsorbent material;d. transferring the aromatic-rich fraction from the second column to the first column while discontinuing the flow through the second column;e. desorbing and removing nitrogen-containing compounds and/or poly-nuclear aromatic compounds from the adsorbent material in the second column to thereby regenerate the adsorbent material; andf. repeating steps (a)-(e), whereby the processing of the aromatic-rich fraction is continuous. 9. The method of claim 1, further comprising recycling at least a portion of the heavy isomerized effluent to the step of separating the hydrotreated effluent into an aromatic-lean fraction and an aromatic-rich fraction. 10. A method of processing a hydrocarbon feed to reduce the concentration of undesired organosulfur compounds comprising: subjecting the hydrocarbon feed to a mild hydrotreating process effective to convert labile organosulfur compounds and produce a hydrotreated effluent containing converted compounds and unconverted sterically hindered refractory aromatic organosulfur compounds;separating the hydrotreated effluent into an aromatic-lean fraction that is recovered as a hydrotreated hydrocarbon product and an aromatic-rich fraction that contains sterically hindered refractory aromatic organosulfur compounds;contacting the aromatic-rich fraction with an isomerization catalyst in the presence of hydrogen to remove steric hindrance of certain compounds and produce an isomerized effluent including isomerate and any remaining unreacted hydrogen;flashing the isomerized effluent to produce a light isomerized effluent and a heavy isomerized effluent;recovering the light isomerized effluent; andrecycling at least a portion of the heavy isomerized effluent to the step of separating the hydrotreated effluent into an aromatic-lean fraction and an aromatic-rich fraction. 11. The method of claim 10, further comprising, prior to contacting the aromatic-rich fraction with an isomerization catalyst, contacting the aromatic-rich fraction with an adsorbent material to reduce the nitrogen content to produce an adsorption effluent. 12. The method of claim 10, further comprising recycling at least a portion of the heavy isomerized effluent back to the step of mild hydrotreating. 13. The method of claim 10, wherein separating the hydrotreated effluent into an aromatic-lean fraction and an aromatic-rich fraction comprises: subjecting the hydrotreated effluent and an effective quantity of extraction solvent to an extraction zone to produce an extract containing a major proportion of the aromatic content of the hydrotreated effluent and a portion of the extraction solvent anda raffinate containing a major proportion of the non-aromatic content of the hydrotreated effluent and a portion of the extraction solvent;separating at least substantial portion of the extraction solvent from the raffinate and retaining the aromatic-lean fraction;separating at least substantial portion of the extraction solvent from the extract and retaining the aromatic-rich fraction. 14. The method of claim 10, wherein the aromatic-lean fraction includes aliphatic organosulfur compounds. 15. The method of claim 14, wherein the aliphatic organosulfur compounds include one or more compounds selected from the group consisting of sulfides, disulfides, and mercaptans. 16. The method of claim 10, wherein the aromatic-rich fraction includes one or more compounds selected from the group consisting of benzothiophene, alkylated derivatives of benzothiophene, dibenzothiophene, alkyl derivatives of dibenzothiophene, benzonaphtenothiophene, and alkyl derivatives of benzonaphtenothiophene. 17. The method of claim 10, wherein the aromatic-rich fraction includes one or more compounds selected from the group consisting of aromatic nitrogen compounds including pyrrole, quinoline, acridine, carbazole and their derivatives. 18. The method of claim 10, wherein the step of contacting the aromatic-rich fraction with an adsorbent material comprises a. passing the aromatic-rich fraction through a first of two packed columns;b. transferring the aromatic-rich fraction from the first column to the second column while discontinuing passage through the first column;c. desorbing and removing nitrogen-containing compounds and/or poly-nuclear aromatic compounds from the adsorbent material in the first column to thereby regenerate the adsorbent material;d. transferring the aromatic-rich fraction from the second column to the first column while discontinuing the flow through the second column;e. desorbing and removing nitrogen-containing compounds and/or poly-nuclear aromatic compounds from the adsorbent material in the second column to thereby regenerate the adsorbent material; andf. repeating steps (a)-(e), whereby the processing of the aromatic-rich fraction is continuous.