Production of tetrahydrofuran-2, 5-dimethanol from isosorbide
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
C07D-307/04
C07D-307/12
출원번호
US-0729401
(2012-12-28)
등록번호
US-8884035
(2014-11-11)
발명자
/ 주소
de Silva, Wathudura Indika Namal
Korovessi, Ekaterini
Menning, Carl Andrew
Murphy, Joseph E
Ritter, Joachim C
Sengupta, Sourav Kumar
Stauffer, Christina S
출원인 / 주소
E I du Pont de Nemours and Company
인용정보
피인용 횟수 :
4인용 특허 :
30
초록▼
Disclosed herein are processes comprising contacting isosorbide with hydrogen in the presence of a first hydrogenation catalyst to form a first product mixture comprising tetrahydrofuran-2,5-dimethanol. The processes can further comprise heating the first product mixture in the presence of hydrogen
Disclosed herein are processes comprising contacting isosorbide with hydrogen in the presence of a first hydrogenation catalyst to form a first product mixture comprising tetrahydrofuran-2,5-dimethanol. The processes can further comprise heating the first product mixture in the presence of hydrogen and a second hydrogenation catalyst to form a second product mixture comprising 1,6-hexanediol. The first and second hydrogenation catalysts can be the same or different.
대표청구항▼
1. A process comprising: a) contacting isosorbide with hydrogen in the presence of a first hydrogenation catalyst at a first temperature between about 150° C. and about 400° C. and at a first pressure between about 500 psi to about 5000 psi to form a first product mixture comprising tetrahydrofuran-
1. A process comprising: a) contacting isosorbide with hydrogen in the presence of a first hydrogenation catalyst at a first temperature between about 150° C. and about 400° C. and at a first pressure between about 500 psi to about 5000 psi to form a first product mixture comprising tetrahydrofuran-2,5-dimethanol. 2. The process of claim 1, wherein the first product mixture further comprises 1,6-hexanediol. 3. The process of claim 1, further comprising: b) heating the first product mixture in the presence of hydrogen and a second hydrogenation catalyst at a second temperature between about 120° C. and about 350° C. to form a second product mixture comprising 1,6-hexanediol. 4. The process of claim 3, wherein the first and second hydrogenation catalysts are the same. 5. The process of claim 1, wherein the catalyst comprises copper. 6. The process of claim 1, wherein the catalyst comprises CuO. 7. The process of claim 1, wherein the catalyst comprises from 2 weight percent to 98 weight percent CuO, and further comprises from 98 weight percent to 2 weight percent of at least one oxide selected from the group consisting of zinc oxide, magnesium oxide, barium oxide, chromium oxide, silica, alumina, zirconium dioxide, nickel oxide, manganese oxide, sodium oxide, potassium oxide, cerium oxide, lanthanum oxide, iron oxide, silver oxide, and cobalt oxide, based on the total weight of the catalyst. 8. The process of claim 7, wherein the catalyst further comprises magnesium oxide. 9. The process of claim 7, wherein the catalyst further comprises zinc oxide. 10. The process of claim 1, wherein the catalyst comprises BaO/CuO/Cr2O3/SiO2, BaO/CuO/Cr2O3, BaO/CuO/MnO2/Cr2O3, CuO/SiO2, CuO/Al2O3, CuO/NiO/Al2O3, CuO/Cr2O3/MnO2, CuO/Cr2O3, CuO/MnO2, CuO/Cr2O3, CuO/SiO2/Cr2O3/MgO, CuO/NiO, or NiO/CuO/K2O/Cr2O3/CaF2. 11. The process of claim 1, wherein the catalyst comprises CuO/ZnO/Al2O3. 12. The process of claim 1, wherein the first product mixture further comprises one or more of 1,2,6-hexanetriol and 2-hydroxymethyltetrahydropyran. 13. The process of claim 3, wherein the second product mixture further comprises one or more of 1,2,6-hexanetriol, 1,2-cyclohexanediol, 1,5-pentanediol, and 1,5-hexanediol. 14. The process of claim 7, wherein the first temperature is between about 200° C. and about 290° C. and the first pressure is between about 1000 psi and about 2000 psi. 15. The process of claim 3, wherein the second hydrogenation catalyst comprises from 2 weight percent to 98 weight percent CuO, and further comprises from 98 weight percent to 2 weight percent of at least one oxide selected from the group consisting of zinc oxide, magnesium oxide, barium oxide, chromium oxide, silica, alumina, zirconium dioxide, nickel oxide, manganese oxide, sodium oxide, potassium oxide, cerium oxide, lanthanum oxide, iron oxide, silver oxide, and cobalt oxide, based on the total weight of the catalyst.
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