A binder based predominantly on molasses which incorporates both polymeric and monomeric polycarboxylic acid components to form a composite including both melanoidin and polyester polymeric structures. The binder incorporates the chemical profile of molasses with a mixture of polycarboxylic acids wh
A binder based predominantly on molasses which incorporates both polymeric and monomeric polycarboxylic acid components to form a composite including both melanoidin and polyester polymeric structures. The binder incorporates the chemical profile of molasses with a mixture of polycarboxylic acids which combines to form a strong and weatherable binder composition which may be used to bind loosely or non-assembled matter.
대표청구항▼
1. A composite melanoidin and polyester binder comprising products of reacting molasses with polyacrylic acid and citric acid in the presence of a sodium hypophosphite catalyst, wherein amine functional compounds from the molasses react with reducing sugars from the molasses under influence of the c
1. A composite melanoidin and polyester binder comprising products of reacting molasses with polyacrylic acid and citric acid in the presence of a sodium hypophosphite catalyst, wherein amine functional compounds from the molasses react with reducing sugars from the molasses under influence of the citric acid and hypophosphite catalyst to form melanoidin products,the melanoidin products are linked by an esterification reaction between the polyacrylic acid and the melanoidin products, anda ratio of the polymeric polyacrylic acid to the citric acid is from about 0.25 to about 1.5 by weight. 2. The composite melanoidin and polyester binder of claim 1, wherein the polyacrylic acid has a molecular weight of about 2000 to about 6000 g/mol. 3. The composite melanoidin and polyester binder of claim 1, wherein the binder includes between about 0.02% and about 2% Nitrogen as determined by elemental analysis. 4. The composite melanoidin and polyester binder of claim 1, wherein a solution of the molasses with the polyacrylic acid and the citric acid in the presence of the sodium hypophosphite catalyst has a pH from about 6 to about 11. 5. The composite melanoidin and polyester binder of claim 1, wherein an aqueous extract of the binder has a pH from about 3 to about 7. 6. A binder composition comprising a polymeric product of a reaction between molasses, a polymeric polycarboxylic acid, and a monomeric polycarboxylic acid, wherein the polymeric product comprises predominantly molasses. 7. The binder composition of claim 6, wherein the molasses is selected from a group consisting of a sugar cane molasses, a sugar beet molasses, starch molasses, citrus molasses and hemicellulose extract. 8. The binder composition of claim 6, wherein the polymeric polycarboxylic acid is selected from a group consisting of a polyacrylic acid, polymethacrylic acid, polymaleic acid, copolymers thereof, and mixtures thereof. 9. The binder composition of claim 6, wherein the polymeric polycarboxylic acid has a molecular weight of about 2000 to about 6000 g/mol. 10. The binder composition of claim 6, wherein the monomeric polycarboxylic acid is selected from a group consisting of citric acid, maleic acid, tartaric acid, malic acid, succinic acid, and mixtures thereof. 11. The binder composition of claim 6, wherein a ratio of the molasses to a combination of the molasses, the polymeric polycarboxylic acid, and the monomeric polycarboxylic acid is from about 0.5 to about 0.9 by weight. 12. The binder composition of claim 11, wherein a ratio of the monomeric polycarboxylic acid to the combination of the molasses, the polymeric polycarboxylic acid, and the monomeric polycarboxylic acid is from about 0.05 to about 0.4 by weight. 13. The binder composition of claim 12, wherein a ratio of the polymeric polycarboxylic acid to the combination of the molasses, the polymeric polycarboxylic acid, and the monomeric polycarboxylic acid is from about 0.01 to about 0.4 by weight. 14. The binder composition of claim 6, further comprising a catalyst selected from a group consisting of an alkali metal polyphosphate, an alkali metal dihydrogen phosphate, a polyphosphoric acid, an alkyl phosphinic acid, and an oligomer or a polymer bearing phosphorous-containing groups and mixtures thereof. 15. The binder composition of claim 6, further comprising sodium hypophosphite as a catalyst. 16. The binder composition of claim 14, wherein a ratio of the catalyst to a combination of the molasses, the polymeric polycarboxylic acid, and the monomeric polycarboxylic acid is from about 0.01 to about 0.1 by weight. 17. A method of binding loosely or non-assembled matter comprising the steps of mixing a solution comprising a molasses, a monomeric polycarboxylic acid, a polymeric polycarboxylic acid, and a catalyst,disposing the solution on a collection of matter, anddrying the solution to form a dehydrated reactive mixture, wherein the dehydrated reactive mixture binds the collection of matter. 18. The method of binding loosely or non-assembled matter of claim 17, further comprising the step of curing the dehydrated reactive mixture. 19. The method of binding loosely or non-assembled matter of claim 18, wherein the curing step includes heating the dehydrated reactive mixture to temperatures of from about 150° C. to about 315° C. 20. The method of binding loosely or non-assembled matter of claim 18, wherein the drying step and the curing step occur substantially contemporaneously. 21. The method of binding loosely or non-assembled matter of claim 17, wherein the collection of matter are mineral fibers selected from a group consisting of glass fibers and rock wool fibers. 22. The method of binding loosely or non-assembled matter of claim 17, wherein a shell bone longitudinal tensile strength test result average for a weathered and a dry sample exceeds about 1.8 MN/m2 and 2.3 MN/m2 respectively.
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Arfaei Ahmad (Chelmsford MA) Darwin David C. (Columbia MD) Gartner Ellis M. (Silver Spring MD) Chun Byong-Wa (Columbia MD) Koyata Hideo (Waltham MA) Kuo Lawrence L. (Columbia MD), Cement admixture product having improved rheological properties and process of forming same.
Darwin David Charles (Columbia MD) Gartner Ellis Martin (Silver Spring MD) Chun Byong-Wa (Columbia MD) Koyata Hideo (Waltham MA) Kuo Lawrence Lu (Columbia MD), Cement admixture product having improved rheological properties and process of forming same.
Sehl, Louis C.; Trollsas, Olof Mikael; Wallace, Donald G.; Toman, David; DeLustro, Frank A.; Schroeder, Jacqueline A.; Chu, George H., Compositions and systems for forming crosslinked biomaterials and methods of preparation of use.
William A. Haile ; Leron R. Dean ; Richard L. McConnell ; Mark E. Tincher ; Alan W. White ; Charles M. Buchanan, Copolyesters and fibrous materials formed therefrom.
Eck Herbert (Burghausen DEX) Ball Peter (Emmerting DEX) Lutz Hermann (Emmerting DEX) Hopf Heinrich (Burghausen DEX), Crosslinkable polymer powder compositions.
Schmitt George J. (Madison NJ) Prevorsek Dusan C. (Morristown NJ) Chin Hong B. (Parsippany NJ) Lem Kwok W. (Randolph NJ), Curable phenolic and polyamide blends.
Taylor Thomas John ; Kielmeyer William Henry ; Golino Carlo Martin ; Rude Carl A., Emulsified furan resin based glass fiber binding compositions, process of binding glass fibers, and glass fiber compositions.
Berdan ; II Clarke ; Grant Larry J., Fibrous insulation having integrated mineral fibers and organic fibers, and building structures insulated with such fibr.
Prestrelski Steven J. (1971 W. Middlefield Rd. ; Unit #5 Mountain View CA 94043) Zhang Mei Z. (444 Via Colinas Thousand Oaks CA 91362), Formulation of a reconstituted protein, and method and kit for the production thereof.
Tanaka Hideaki (Ibaraki JPX) Oba Hiroyuki (Ibaraki JPX) Sato Tomoaki (Ibaraki JPX) Hasegawa Tomohisa (Ibaraki JPX), Gas barrier film and production process thereof.
Tanaka Hideaki (Ibaraki-ken JPX) Oba Hiroyuki (Ibaraki-ken JPX) Sato Tomoaki (Ibaraki-ken JPX) Hasegawa Tomohisa (Ibaraki-ken JPX), Gas barrier film and production process thereof.
Golino Carlo M. (Evergreen CO) Taylor Thomas J. (Englewood CO) Kielmeyer William H. (Englewood CO) Thiessen Leo K. (Littleton CO) Rude Carl A. (Lafayette IN), Glass fiber binding compositions, process of binding glass fibers, and glass fiber compositions.
Fahey Dennis M. (Lexington NC), Glass fibers with reduced tendency to form gumming deposits and sizing composition comprising two starches with differen.
Hartmann Heinrich (Limburgerhof DEX) Denzinger Walter (Speyer DEX) Kroener Michael (Mannheim DEX) Nilz Claudia (Dannstadt-Schauernheim DEX) Linhart Friedrich (Heidelberg DEX) Stange Andreas (Mannheim, Graft polymers of natural substances containing saccharide structures or derivatives thereof and ethylenically unsaturat.
Dubin Leonard (Skokie IL) Epperly W. Robert (New Canaan CT) Sprague Barry Normand (Bethlehem CT) von Harpe Thure (Meerbusch DEX), Hardness suppression in urea solutions.
Holmes-Farley Stephen Randall ; Petersen John S., Hydrophilic nonamine-containing and amine-containing copolymers and their use as bile acid sequestrants.
Woiszwillo James E. ; Brown Larry R. ; Scott Terrence L. ; Di Jie ; Sudhalter Judith ; Blizzard Charles D., Macromolecular microparticles and methods of production and use.
Woiszwillo James E. ; Brown Larry R. ; Scott Terrence L. ; Di Jie ; Sudhalter Judith ; Blizzard Charles D. ; Riske Frank J., Macromolecular microparticles and methods of production and use.
Beckman,Eric J.; Carroll,W. Eamon; Chapman,Toby; Minnich,Kristen E.; Sagl,Dennis; Goddard,Richard J., Method for increasing the strength of a cellulosic product.
Colaco Camilo,GBX ; Roser Bruce J.,GBX ; Sen Shevanti,GBX, Method for stabilization of biological substances during drying and subsequent storage and compositions thereof.
Gershun Aleksei V. ; Woyciesjes Peter M., Method of inhibiting cavitation-erosion corrosion of aluminum surfaces using carboxylic acid based compositions comprising polymerizable-acid graft polymers.
Hall Herbert L. (1371 Pleasant Valley Rd. Newark OH 43055) Scott James W. (1738 Stonewall Dr. Newark OH 43055), Method of making an insulation assembly.
Qin Jian (Appleton WI) Gross James R. (Appleton WI) Mui William J. (Neenah WI) Ning Xin (Appleton WI) Schroeder Wen Z. (Appleton WI) Sun Tong (Neenah WI), Modified polysaccharides having improved absorbent properties and process for the preparation thereof.
Hansen Michael R. (515 N. 149th Seattle WA 98133) Young ; Sr. Richard H. (13910 147th Pl. SE. Renton WA 98059), Non-polymeric organic binders for binding particles to fibers.
Krasnobajew Victor (Zollikerberg CHX) Boeniger Regula (Greifensee CHX), Novel condensation products having high activity to insolubilize proteins and protein-insolubilized products.
Kiely Donald E. (2521 Chatwood Rd. Birmingham AL 35226) Chen Liang (4010 N. Brandywine Dr. ; #620 Peoria IL 61614) Morton David W. (716-F 24th Ave. NW. Birmingham AL 35215), Polyaldaramide polymers useful for films and adhesives.
Chen, Liang; Bullock, Kathleen M.; Downey, William E.; Pellegrin, Michael T.; Delaviz, Yadollah; Guigley, Kevin; Cline, Harry B., Polycarboxylic acid based co-binder.
Lay Gustav (Bad Bellingen DEX) Rehm Johannes (Bad Krozingen DEX) Stepto Robert F. (Cheshire GBX) Thoma Markus (Reihen CHX) Sachetto Jean-Pierre (Arlesheim NJ CHX) Lentz David J. (Randolph NJ) Silbige, Polymer compositions containing destructurized starch.
Pankaj Shashikant Shah ; Stuart Andrew Shaw Craig ; Christina Sue Morrill ; Michael Torrey Wuesthoff, Polymerization of mono and disaccharides using low levels of polycarboxylic acids.
Shah, Pankaj Shashikant; Craig, Stuart Andrew Shaw; Morrill, Christina Sue; Wuesthoff, Michael Torrey, Polymerization of mono-and disaccharides using low levels of mineral acids.
Aravindakshan Perincheery (Maharashtra INX) Kumar Velayudhan N. G. (Maharashtra INX), Polysaccharide graft-polymers and the use in papermaking thereof.
Pfoehler Peter (Speyer DEX) Angel Maximilian (Mutterstadt DEX) Einwiller Andreas (Mannheim DEX) Schagerer Klaus (Gruenstadt DEX), Preparation of aqueous (meth)acrylate copolymer dispersions in two stages and their use as impregnating materials, coati.
Cook Jeffery T. (Cincinatti OH) Daniels Walter D. (Maineville OH) Rodriguez Pedro A. (Cincinnati OH) Graef Peter A. (Puyallup WA) Bolstad Clifford R. (Federal Way WA) Duncan William L. (Seattle WA), Process for preparing reduced odor and improved brightness individualized, polycarboxylic acid crosslinked fibers.
Vandichel Jean-Claude N. E. (Ottignies BEX) Aerts Rene (Ottignies BEX) Batt Alan M. (Ottignies BEX), Process for preparing soft flexible polyurethane foams and a polyol composition useful in said process.
Neigel Dennis (Whitehouse Station NJ) Kancylarz John (Plainsboro NJ), Process for the preparation of graft copolymers of cellulose derivatives and diallyl, dialkyl ammonium halides.
Bichot Bernard (Clermont FRX) Van Oers Gerardus P. M. (Etten-Leur FRX) Bakx Cornelis G. A. (Etten-Leur FRX), Recycling of fibrous products in a production line for manufacturing mats from fibers.
Sarama Robert Joseph ; Howie John Keeney ; Clay Reginald Sebastian, Reduced calorie cooking and frying oils having improved hydrolytic stability, and process for preparing.
Hansen, Erling; Nissen, Povl; Husemoen, Thor; Stanssens, Dirk Armand Wim, Resin for a mineral wool binder comprising the reaction product of an amine with a first and second anhydride.
Zeiszler Dennis E. (3502 22nd St. South Fargo ND 58104-6520), Structural building materials or articles obtained from crop plants or residues therefrom and/or polyolefin materials.
Luitjes Hendrikus,NLX ; De Spirt Silvan,NLX ; Frissen Augustinus Emmanuel,NLX ; Van Haveren Jacobus,NLX ; Kammelar Robert Willem Frederik,NLX, Sugar amines and sugar amides and use as glues.
Bernd Reck DE; Stefan Dreher DE; Wilhelm Friedrich Beckerle DE; Eckehardt Wistuba DE; Michael Seufert DE; Joachim Roser DE; Johannes Turk DE, Thermosetting aqueous compositions.
Levy Marie-Christine (Reims FRX), Utilization of a transacylation reaction between an esterified polysaccharide and a polyaminated or polyhydroxylated sub.
Butler George B. (Gainesville FL) Hogen-Esch Thieo E. (Gainesville FL) Meister John J. (Dallas TX) Pledger ; Jr. Huey (Gainesville FL), Water-soluble graft copolymers of starch-acrylamide and uses therefor.
Hansen Michael R. (Seattle WA) Young ; Sr. Richard H. (Federal Way WA), Wet laid fiber sheet manufacturing with reactivatable binders for binding particles to fibers.
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