A catalyst composition comprising a cation and an anion of the formula Anq−Qpm+, wherein m, n, p, and q are positive integers, wherein m*p=n*q, wherein Qm+is an organo onium, and Aq−is an anion, provided that at least one Aq−is selected from the formula (I) wherein each R independently is H, halo, a
A catalyst composition comprising a cation and an anion of the formula Anq−Qpm+, wherein m, n, p, and q are positive integers, wherein m*p=n*q, wherein Qm+is an organo onium, and Aq−is an anion, provided that at least one Aq−is selected from the formula (I) wherein each R independently is H, halo, alkyl, aryl, aralkyl, or cycloalkyl, and which also may be halogenated, fluorinated, or perfluorinated, wherein two or more of R and R′ groups may together form a ring, wherein each R group independently may contain one or more heteroatom(s), wherein R′ can be the same as R, with the proviso that R′ cannot be halo, and wherein the catalyst composition is essentially free of hydrocarbon containing alcohol. Also provided are a fluoropolymer composition including this curative, a method of making a fluoropolymer, and fluoropolymer articles containing curable or cured fluoropolymer compositions.
대표청구항▼
1. A catalyst composition comprising a catalyst selected from tetra-alkylammonium 2-phenyl-1,1,1,3,3,3 hexafluoroisopropanoate, tetra-alkylammonium 1,1,1,3,3,3 hexafluoroisopropanoate, tetrabutylphosphonium 2-phenyl-1,1,1,3,3,3 hexafluoroisopropanoate, tetrabutylphosphonium 1,1,1,3,3,3 hexafluoroiso
1. A catalyst composition comprising a catalyst selected from tetra-alkylammonium 2-phenyl-1,1,1,3,3,3 hexafluoroisopropanoate, tetra-alkylammonium 1,1,1,3,3,3 hexafluoroisopropanoate, tetrabutylphosphonium 2-phenyl-1,1,1,3,3,3 hexafluoroisopropanoate, tetrabutylphosphonium 1,1,1,3,3,3 hexafluoroisopropanoate, tetrabutylphosphonium 2-methoxyphenyl-1,1,1,3,3,3 hexafluoroisopropanoate, and tetrabutylphosphonium 2-p-toluyl-1,1,1,3,3,3 hexafluoroisopropanoate, and wherein the catalyst composition is free of hydrocarbon containing alcohol. 2. The composition of claim 1 further comprising an organic or inorganic filler. 3. A fluoropolymer composition comprising a fluoropolymer and the catalyst composition of claim 1 wherein the fluoropolymer composition is free of hydrocarbon containing alcohol. 4. A fluoroelastomer composition comprising: a fluoroelastomer comprising nitrogen-containing cure sites; andthe catalyst composition of claim 1 wherein the fluoroelastomer composition is free of hydrocarbon containing alcohol. 5. The fluoroelastomer composition of claim 4 wherein the fluoroelastomer composition has a Mooney scorch time (t18) of at least 15 minutes according to ASTM D1646-96. 6. A fluoroelastomer composition comprising the catalyst composition of claim 1 and a fluoroelastomer, which may be perfluorinated, having interpolymerized units of a nitrogen-containing cure site monomer, which may be a nitrile-containing cure site monomer wherein the fluoroelastomer composition is free of hydrocarbon containing alcohol. 7. The fluoroelastomer composition of claim 4 further comprising a filler, optionally wherein the filler is selected from PTFE and/or perfluoroalkoxy/TFE copolymer (PFA). 8. The fluoroelastomer composition of claim 4 wherein the fluoroelastomer comprises interpolymerized units of tetrafluoroethylene and a perfluoroalkylvinylether, perfluoroalkoxyvinylether, perfluoroalkeneether, and/or perfluoroalkoxyalkeneether. 9. The fluoroelastomer composition according to claim 4 wherein the fluoroelastomer comprises interpolymerized units derived from tetrafluoroethylene, a fluorinated comonomer, and optionally one or more perfluorovinyl ethers. 10. A fluoroelastomer composition according to claim 9 wherein the fluorinated comonomer is selected from perfluoroolefins, partially-fluorinated olefins, non-fluorinated olefins, vinylidene fluoride, and combinations thereof. 11. A fluoroelastomer composition according to claim 4 wherein said cure site monomer is selected from a compound of the formula CF2═CFO(CF2)LCN; CF2═CFO(CF2)uOCF(CF3)CN; CF2═CFO[CF2CF(CF3)O]q(CF2O)yCF(CF3)CN; or CF2═CF[OCF2CF(CF3)]rO(CF2)tCN; wherein L=2-12; q=0-4; r=1-2; y=0-6; t=1-4, and u=2-6; perfluoro(8-cyano-5-methyl-3,6-dioxa-1-octene), and CF2═CFO(CF2)5CN. 12. A fluoroelastomer composition according to claim 4 further comprising a filler, optionally selected from fluoropolymer filler, silica, carbon black, and combinations thereof. 13. The fluoroelastomer composition of claim 4 further comprising an additional curative, optionally wherein the additional curative is selected from ammonia-generating compounds, substituted triazine derivatives, unsubstituted triazine derivatives, peroxides, bis-aminophenols, bis-amidooximes, an organotin compound, or an amidine, bis-amidine, tris-amidine, or tetra-amidine, or a salt thereof. 14. A shaped article comprising the fluoroelastomer composition of claim 4. 15. A shaped article comprising the fluoroelastomer composition of claim 4. 16. The composition of claim 5 further comprising a fluoropolymer having interpolymerized units derived from monomers selected from the group consisting of perfluoroolefins, partially-fluorinated olefins, non-fluorinated olefins, vinylidene fluoride, perfluoroalkeneethers, and combinations thereof. 17. The composition of claim 16 further comprising a material selected from ammonium salts, ammonia-generating compounds, substituted triazine derivatives, unsubstituted triazine derivatives, peroxides optionally with a coagent, bis-aminophenols, bis-amidooximes, an organotin compound, or an amidine, bis-amidine, tris-amidine, or tetra-amidine, or a salt thereof; and wherein the coagent optionally is selected from triallyl cyanurate; triallyl isocyanurate; tri(methylallyl) isocyanurate; tris(diallylamine)-s-triazine; triallyl phosphite; N,N-diallyl acrylamide; hexaallyl phosphoramide; N,N,N′,N′-tetraalkyl tetraphthalamide; N,N,N′,N′- tetraallyl malonamide; trivinyl isocyanurate; 2,4,6-trivinyl methyltrisiloxane; and tri(5-norbornene-2-methylene)cyanurate. 18. A method of making a fluoropolymer composition comprising: forming a mixture comprising a catalyst composition according to claim 1 and a fluoroelastomer having interpolymerized units of a nitrogen-containing cure site monomer, which may be perfluorinated wherein the fluoroelastomer composition is free of hydrocarbon containing alcohol. 19. A method of making a fluoropolymer article comprising: (a) providing the mixture of claim 18,(b) shaping the mixture;(c) curing the shaped mixture to form an article; and optionally post-curing the article. 20. A method of making a fluoropolymer composition comprising: forming a mixture comprising a composition according to claim 4. 21. A method of making a fluoropolymer article comprising: (a) forming a mixture comprising a composition according to claim 20;(b) shaping the mixture;(c) curing the shaped mixture to form an article; and optionally post-curing the article. 22. A method of making the catalyst of claim 1, comprising providing a cation and an anion, wherein the anion is prepared by: (i) reacting a parent alcohol with a base, the base optionally being selected from a tetraalkyl phosphonium hydroxide or tetraalkyl ammonium hydroxide; or(ii) reacting a parent alcohol with a metal hydroxide or alkoxide, optionally selected from sodium methoxide, and in a solvent, adding an onium halide, optionally selected from an onium chloride, and removing the solvent, and optionally precipitating a salt. 23. A method of making the catalyst of claim 1, comprising providing a cation and an anion, wherein the anion is prepared by: (i) reacting a parent alcohol with a base, the base optionally being selected from a tetraalkyl phosphonium hydroxide or tetraalkyl ammonium hydroxide; or(ii) reacting a parent alcohol with a metal hydroxide or alkoxide, optionally selected from sodium methoxide, and in a solvent, adding an onium halide, optionally selected from an onium chloride, and removing the solvent, and optionally precipitating a salt.
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