A method of manufacturing aromatic hydrocarbons, which are suitable for the production of terephthalic acid, from tall oil-based raw material. According to the invention, the raw material that contains tall oil or its fraction is catalytically deoxygenated with hydrogen, and one or more aromatic hyd
A method of manufacturing aromatic hydrocarbons, which are suitable for the production of terephthalic acid, from tall oil-based raw material. According to the invention, the raw material that contains tall oil or its fraction is catalytically deoxygenated with hydrogen, and one or more aromatic hydrocarbons that can be converted into terephthalic acid are separated from the deoxygenated reaction yield. The deoxygenation catalyst is a NiMo catalyst and, in addition, a cracking catalyst can be used, such as an acidic zeolite catalyst. The separated hydrocarbon can be p-xylene, o-xylene or p-cymene. According to the invention, these can be converted by oxidation and, when needed, by a re-arrangement reaction into terephthalic acid that is suitable for the source material of the manufacture of bio-based polyethylene terephthalate.
대표청구항▼
1. A method of manufacturing aromatic hydrocarbons from a tall oil-based raw material, the method comprising: feeding, into a fixed catalyst bed, hydrogen gas and a bio oil, which consists of 2-90% of tall oil fatty acids, 2-98% of tall oil resin acids and, optionally, other vegetable oils;catalytic
1. A method of manufacturing aromatic hydrocarbons from a tall oil-based raw material, the method comprising: feeding, into a fixed catalyst bed, hydrogen gas and a bio oil, which consists of 2-90% of tall oil fatty acids, 2-98% of tall oil resin acids and, optionally, other vegetable oils;catalytically deoxygenating the bio oil in the bed with hydrogen;cooling the flow exiting the bed, and dividing the flow into a hydrocarbon-bearing liquid phase and a gas phase; andrecovering one or more aromatic hydrocarbons selected from a group comprising o-xylene, m-xylene, p-xylene and a cymene from the hydrocarbon-bearing liquid phase,wherein a deoxygenation catalyst and a cracking catalyst are used, which are different from each other and located sequentially apart from each other in the catalyst bed that is formed by a solid bed material. 2. The method according to claim 1, wherein the bio oil contains at least 25% of tall oil resin acids. 3. The method according to claim 1, wherein the bio oil has been separated from crude tall oil by distillation. 4. The method according to claim 1, wherein the catalyst of the deoxygenation stage is a NiMo catalyst. 5. The method according to claim 1, wherein the catalyst of the cracking stage is acidic. 6. The method of claim 5, wherein the acidic catalyst comprises an acidic zeolite catalyst. 7. The method of claim 6, wherein the acidic zeolite catalyst comprises a ZSM-5 catalyst. 8. The method according to claim 1, wherein oxygen compounds are removed from the raw material by use of hydrogen and the said deoxygenation or cracking catalyst or a combination thereof at 330-450° C. and a pressure of 50-100 bars. 9. The method according to claim 1, wherein the flows in the catalyst bed take place from top to bottom. 10. The method according to claim 1, wherein water is separated from the liquid phase of the reaction yield before further processing the hydrocarbon-bearing liquid. 11. The method according to claim 1, wherein one or more aromatic hydrocarbons are separated from the reaction yield by distillation. 12. The method according to claim 1, further comprising: separating an aromatic hydrocarbon selected from a group comprising o-xylene, m-xylene, p-xylene and a cymene from the liquid phase; andsubjecting the separated hydrocarbon to oxygenation and a possible rearrangement reaction, so that terephthalic acid is obtained as the end product. 13. The method according to claim 12, wherein oxygenation of the separated hydrocarbon is carried out with a chemical or biochemical oxidizer. 14. The method according to claim 13, wherein the chemical or biochemical oxidizer comprises chromic acid. 15. The method according to claim 12, wherein p-xylene is separated from the liquid phase and oxidized into terephthalic acid. 16. The method according to claim 12, wherein o-xylene is separated from the liquid phase and oxidized into phthalic acid, which thereafter is converted by means of the Raecke or Henkel rearrangement reaction into terephthalic acid using a salt catalyst. 17. The method according to claim 16, wherein the salt catalyst comprises a cobalt-magnesium salt. 18. The method according to claim 12, wherein in the rearrangement reaction, the reaction mixture is heated to a temperature of at least 300° C. in an inert gas atmosphere. 19. The method according to claim 18, wherein the reaction mixture is heated to a temperature of 330-500° C.
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이 특허에 인용된 특허 (2)
Haag Werner O. (Lawrenceville NJ) Rodewald Paul G. (Rocky Hill NJ) Weisz Paul B. (Yardley PA), Conversion of biological material to liquid fuels.
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