An apparatus and method for enhancing the yield and purity of hydrogen when reforming hydrocarbons is disclosed in one embodiment of the invention as including receiving a hydrocarbon feedstock fuel (e.g., methane, vaporized methanol, natural gas, vaporized diesel, etc.) and steam at a reaction zone
An apparatus and method for enhancing the yield and purity of hydrogen when reforming hydrocarbons is disclosed in one embodiment of the invention as including receiving a hydrocarbon feedstock fuel (e.g., methane, vaporized methanol, natural gas, vaporized diesel, etc.) and steam at a reaction zone and reacting the hydrocarbon feedstock fuel and steam in the presence of a catalyst to produce hydrogen gas. The hydrogen gas is selectively removed from the reaction zone while the reaction is occurring by selectively diffusing the hydrogen gas through a porous ceramic membrane. The selective removal of hydrogen changes the equilibrium of the reaction and increases the amount of hydrogen that is extracted from the hydrocarbon feedstock fuel.
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1. A method for enhancing the yield and purity of hydrogen when reforming hydrocarbons, the method comprising: receiving a hydrocarbon feedstock fuel and steam at a reaction zone;reacting, at the reaction zone, the hydrocarbon feedstock fuel and steam to produce hydrogen gas;diffusing reactants and
1. A method for enhancing the yield and purity of hydrogen when reforming hydrocarbons, the method comprising: receiving a hydrocarbon feedstock fuel and steam at a reaction zone;reacting, at the reaction zone, the hydrocarbon feedstock fuel and steam to produce hydrogen gas;diffusing reactants and reaction products in the reaction zone through pores of a single layer ceramic porous membrane to a product zone, and selectively transporting hydrogen gas through the pores of the porous membrane from the reaction zone to the product zone while the reaction is occurring, wherein selectively transporting comprises diffusing the hydrogen gas through the pores of the porous membrane at a higher diffusion rate than diffusion rates of the reactants and other reaction products, and wherein a first surface of the single layer porous membrane is exposed to reaction zone and a second surface of the single layer porous membrane opposite the first surface is exposed to the product zone; andconveying the reactants and the reaction products that are not transported through the porous membrane to a combustion zone. 2. The method of claim 1, wherein the reaction zone and the product zone are in fluid communication through the pores of the porous membrane. 3. The method of claim 2, wherein the porous ceramic membrane is fabricated from a mixture of alumina powder and a phosphate-containing reagent to react with the alumina powder. 4. The method of claim 1, wherein reacting the hydrocarbon feedstock fuel and steam further comprises producing carbon monoxide at the reaction zone. 5. The method of claim 4, further comprising reacting the carbon monoxide with steam to produce hydrogen gas and carbon dioxide at the reaction zone. 6. The method of claim 1, where selectively transporting hydrogen gas through the pores of the porous membrane further comprises diffusing, at a diffusion rate significantly lower than the diffusion rate of hydrogen gas, other gases through the pores of the porous membrane. 7. The method of claim 6, wherein the other gases comprise at least one of carbon monoxide, carbon dioxide, steam, and gaseous hydrocarbon. 8. The method of claim 1, further comprising providing heat to the reaction zone to aid in reacting the hydrocarbon feedstock fuel and steam. 9. The method of claim 8, further comprising combusting at least one of residual hydrocarbon feedstock fuel, hydrogen gas, and carbon monoxide in the combustion zone to provide the heat to the reaction zone. 10. The method of claim 1, wherein the hydrocarbon feedstock fuel is selected from the group consisting of methane, vaporized methanol, natural gas, vaporized diesel, and combinations and sub-components thereof. 11. The method of claim 1, further comprising creating intimate contact between the hydrocarbon feedstock fuel, the steam, and a catalyst while the reaction is occurring. 12. A device for enhancing the yield and purity of hydrogen when reforming hydrocarbons, the device comprising: an inlet for receiving a hydrocarbon feedstock fuel and steam;a reaction zone in communication with the inlet to react the hydrocarbon feedstock fuel and the steam to produce hydrogen gas;a single layer porous ceramic membrane in communication with the reaction zone to diffuse reactants and reaction products through pores of the porous ceramic membrane and to selectively transport hydrogen gas through the pores of the porous ceramic membrane out of the reaction zone while the reaction is occurring, thereby increasing the extent of reaction between the hydrocarbon feedstock fuel and the steam, wherein the selective transport of hydrogen gas comprises diffusion of the hydrogen gas through the pores of the porous ceramic membrane at a higher diffusion rate than diffusion rates of the reactants and other reaction products;a product zone to receive the hydrogen gas transported through the porous ceramic membrane, and wherein a first surface of the single layer porous membrane is exposed to reaction zone and a second surface of the single layer porous membrane opposite the first surface is exposed to the product zone; anda combustion zone to combust the reactants and the reaction products that are not transported through the porous ceramic membrane. 13. The device of claim 12, wherein the porous ceramic membrane is fabricated from a mixture of alumina powder and a phosphate-containing reagent to react with the alumina powder. 14. The device of claim 12, wherein the reaction zone is further adapted to react carbon monoxide with the steam to produce hydrogen gas and carbon dioxide. 15. The device of claim 12, wherein the porous ceramic membrane is further adapted to transport other gases out of the reaction zone at a diffusion rate significantly lower than the hydrogen gas. 16. The device of claim 15, wherein the other gases comprise at least one of carbon monoxide, carbon dioxide, steam, and gaseous hydrocarbon. 17. The device of claim 12, wherein the combustion zone combusts at least one of residual hydrocarbon feedstock fuel, hydrogen gas, and carbon monoxide to provide heat to the reaction zone. 18. The device of claim 12, wherein the hydrocarbon feedstock fuel is selected from the group consisting of methane, vaporized methanol, natural gas, vaporized diesel, and combinations and sub-components thereof. 19. The device of claim 12, further comprising a porous ceramic layer infiltrated with a catalyst adjacent to the reaction zone. 20. A method for enhancing the yield and purity of hydrogen when reforming hydrocarbons, the method comprising: receiving a hydrocarbon feedstock fuel and steam at a reaction zone;reacting, at the reaction zone, the hydrocarbon feedstock fuel and steam to produce hydrogen gas;diffusing reactants and reaction products in the reaction zone through pores of a single layer porous ceramic membrane, and selectively transporting hydrogen gas from the reaction zone to a product zone by extracting one of hydrogen gas and hydrogen ions through a ceramic membrane while the reaction is occurring, wherein selectively transporting comprises diffusing the hydrogen gas through the pores of the porous membrane at a higher diffusion rate than diffusion rates of the reactants and other reaction products, and wherein a first surface of the single layer porous membrane is exposed to reaction zone and a second surface of the single layer porous membrane opposite the first surface is exposed to the product zone; andconveying the reactants and the reaction products that are not transported through the porous ceramic membrane to a combustion zone. 21. The method of claim 1, wherein the porous membrane is free of a discrete metallic layer.
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이 특허에 인용된 특허 (8)
Chellappa, Anand; Vencill, Thomas R.; Powell, Michael Roy; Godshall, Ned A., Compact devices for generating pure hydrogen.
Kapoor Akhilesh (South Orange NJ) Krishnamurthy Ramachandran (Chestnut Ridge NY) MacLean Donald L. (Clinton NJ), Hydrogen and carbon monoxide production by partial oxidation of hydrocarbon feed.
Helferich Richard L. (Clayton OH) Schenck Robert C. (Kettering OH), Methods for the manufacture of porous ceramic shapes containing membraneous surfaces.
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