Disclosed are processes for preparing 1,2-cyclohexanediol, and mixtures of 1,2-cyclohexanediol and 1,6-hexanediol, by hydrogenating 1,2,6-hexanetriol.
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1. A process comprising contacting 1,2,6-hexanetriol with hydrogen in the presence of a hydrogenation catalyst at a temperature in the range of from about 120° C. to about 300° C. and at a pressure in the range of from about 200 psi to about 3000 psi to form a product mixture comprising 1,2-cyclohex
1. A process comprising contacting 1,2,6-hexanetriol with hydrogen in the presence of a hydrogenation catalyst at a temperature in the range of from about 120° C. to about 300° C. and at a pressure in the range of from about 200 psi to about 3000 psi to form a product mixture comprising 1,2-cyclohexanediol. 2. The process of claim 1, wherein the hydrogenation catalyst comprises a transition metal selected from the group consisting of platinum, nickel, cobalt, rhodium, silver, copper, ruthenium, iron, palladium, and mixtures thereof. 3. The process of claim 1, wherein the catalyst comprises copper. 4. The process of claim 1, wherein the catalyst comprises CuO. 5. The process of claim 1, wherein the catalyst comprises from 2 weight percent to 98 weight percent CuO, and further comprises from 98 weight percent to 2 weight percent of at least one oxide selected from the group consisting of zinc oxide, magnesium oxide, barium oxide, chromium oxide, silica, alumina, zirconium dioxide, nickel oxide, manganese oxide, sodium oxide, potassium oxide, cerium oxide, lanthanum oxide, iron oxide, silver oxide, and cobalt oxide, based on the total weight of the catalyst. 6. The process of claim 5, wherein the catalyst further comprises at least one oxide selected from the group consisting of zirconium dioxide, lanthanum oxide, cerium oxide, zinc oxide, magnesium oxide, silica and alumina. 7. The process of claim 5, wherein the catalyst further comprises zinc oxide. 8. The process of claim 5, wherein the catalyst comprises BaO/CuO/Cr2O3/SiO2, BaO/CuO/Cr2O3, BaO/CuO/MnO2/Cr2O3, CuO/SiO2, CuO/Al2O3, CuO/NiO/Al2O3, CuO/Cr2O3/MnO2, CuO/Cr2O3, CuO/MnO2, CuO/Cr2O3, CuO/SiO2/Cr2O3/MgO, CuO/NiO, NiO/CuO/K2O/Cr2O3/CaF2, CuO/ZnO, CuO/ZnO/Al2O3, or CuO/ZnO/CeO2/Al2O3/Na2O/C. 9. The process of claim 5, wherein the catalyst comprises CuO/La2O3/ZrO2, CuO/La2O3/Al2O3, CuO/CeO2/ZrO2 or CuO/MgO. 10. The process of claim 1, wherein the product mixture further comprises 1,6-hexanediol. 11. The process of claim 1, wherein the product mixture further comprises one or more of 2-hydroxymethyltetrahydropyran, 1,5-hexanediol, and 1,5-pentanediol. 12. The process of claim 1, wherein product mixture further comprises both 1,2-cyclohexanediol and 1,6-hexanediol, and the molar ratio of 1,2-cyclohexanediol to 1,6-hexanediol is in the range of from about 0.1 to 20. 13. The process of claim 8, wherein the temperature is within the range of from about 200° C. to about 290° C., and the pressure is within the range of from about 800 psi to about 1500 psi. 14. The process of claim 9, wherein the temperature is within the range of from about 200° C. to about 290° C., and the pressure is within the range of from about 800 psi to about 1500 psi.
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