초록 ▼

Hardenable compositions are described comprising at least one multifunctional ethylenically unsaturated isocyanurate monomer and at least one multifunctional ethylenically unsaturated tricyclodecane monomer. In favored embodiments, the compositions further comprise filler and are suitable dental res

Hardenable compositions are described comprising at least one multifunctional ethylenically unsaturated isocyanurate monomer and at least one multifunctional ethylenically unsaturated tricyclodecane monomer. In favored embodiments, the compositions further comprise filler and are suitable dental restorations.

대표청구항 ▼

1. A hardenable dental composition comprising at least one isocyanurate monomer comprising at least two ethylenically unsaturated groups bonded to nitrogen atoms of a trivalent isocyanuric acid ring via a divalent linking group comprising a cyclic or aromatic moiety;at least one multifunctional ethy

1. A hardenable dental composition comprising at least one isocyanurate monomer comprising at least two ethylenically unsaturated groups bonded to nitrogen atoms of a trivalent isocyanuric acid ring via a divalent linking group comprising a cyclic or aromatic moiety;at least one multifunctional ethylenically unsaturated tricyclodecane monomer, and inorganic nanoparticles comprising silica, zirconia, or mixtures thereof. 2. The hardenable dental composition of claim 1 wherein the isocyanurate monomer and tricyclodecane monomer are liquids at 25° C. 3. The hardenable dental composition of claim 1 wherein the ethylenically unsaturated groups of the monomers are (meth)acrylate groups. 4. The hardenable dental composition of claim 1 wherein the isocyanurate and tricyclodecane monomers have a refractive index of at least 1.50. 5. The hardenable dental composition of claim 1 wherein the isocyanurate and tricyclodecane monomers have a molecular weight (Mw) ranging from about 600 to 1500 g/mole. 6. The hardenable dental composition of claim 1 wherein the isocyanurate monomer has the general structure whereinR1 is alkylene, arylene, or alkarylene, optionally including a heteroatom;R2 is hydrogen or methyl;Z is an alkylene, arylene, or alkarylene linking group comprising one or more moieties selected from urethane, ester, thioester, ether, thioether, and at least one Z comprises a cyclic or aromatic moiety; andat least one of R3 or R4 is 7. The hardenable dental composition of claim 6 wherein the isocyanurate monomer is a di(meth)acrylate isocyanurate monomer. 8. The hardenable dental composition of claim 6 wherein the isocyanurate monomer is a tri(meth)acrylate isocyanurate monomer. 9. The hardenable dental composition of claim 6 wherein Z comprises at least one ester moiety. 10. The hardenable dental composition of claim 1 wherein the multifunctional ethylenically unsaturated tricyclodecane monomer has a backbone unit (U) having the structure wherein one or two spacer unit(s) (S) are bonded to the backbone unit (U) via an ether linkage and at least one spacer unit (S) comprises a CH(Q)-OG chain wherein each group G comprising a (meth)acrylate moiety and Q comprises at least one group selected from hydrogen, alkyl, aryl, alkaryl and combinations thereof. 11. The hardenable dental composition of claim 10 wherein G is bonded to the spacer unit(s) (S) via a urethane moiety. 12. The hardenable dental composition according to claim 10 wherein the spacer unit(s) (S) comprises a moiety being selected from wherein m is 1 to 3; n is 1 to 3; and Q is hydrogen, methyl, phenyl, phenoxymethyl; or wherein M is phenyl. 13. The hardenable dental composition according to claim 10, wherein the tricyclodecane monomer is characterized by a structure according to formulas wherein a, b is 0 to 3; c, d is 0 to 3; (a+b) is 1 to 6, (c+d) is 1 to 6; and Q is independently selected from hydrogen, methyl, phenyl or phenoxymethyl. 14. The hardenable dental composition of claim 1 wherein the inorganic nanoparticles are in the form of nanoclusters. 15. The hardenable dental composition of claim 1 wherein the dental composition further comprises other (meth)acrylate monomers. 16. The hardenable dental composition of claim 15 wherein the other monomer comprises an isocyanurate or tricyclodecane monomer having a molecular weight no greater than 600 g/mole. 17. The hardenable dental composition of claim 1 wherein the hardened composition exhibits a Watts Shrinkage of less than about 2%. 18. The hardenable dental composition of claim 1 wherein the hardened composition exhibits a Diametral Tensile Strength is at least 75 MPa. 19. The hardenable dental composition of claim 1 wherein the hardened composition exhibits a stress deflection no greater than 2.0 microns. 20. A method of treating a tooth surface, the method comprising providing a hardenable dental composition according to claim 1,placing the dental composition on a tooth surface in the mouth of a subject; andhardening the hardenable dental composition. 21. A dental article comprising a hardenable dental composition according to claim 1, wherein the hardenable dental composition is at least partially hardened. 22. A method of treating a tooth surface, the method comprising providing an at least partially hardened dental article according to claim 21,adhering the dental article on a tooth surface in the mouth of a subject. 23. The hardenable dental composition of claim 1 wherein the hardened composition exhibits a stress deflection no greater than 1.6 microns.