Antifouling compositions including dioxaborinanes and uses thereof
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
A01N-055/08
C09D-005/16
C08K-003/00
C08K-003/38
출원번호
US-0761576
(2013-02-07)
등록번호
US-9095141
(2015-08-04)
발명자
/ 주소
Carlson, William B.
Phelan, Gregory D.
출원인 / 주소
EMPIRE TECHNOLOGY DEVELOPMENT LLC
대리인 / 주소
Foley & Lardner LLP
인용정보
피인용 횟수 :
0인용 특허 :
25
초록▼
An antifouling composition including a compound having a dioxaborinane moiety is provided. Methods of killing, or deterring the growth of, one or more organisms on an article include coating or impregnating the article with the antifouling composition, where the organisms live in fresh water or salt
An antifouling composition including a compound having a dioxaborinane moiety is provided. Methods of killing, or deterring the growth of, one or more organisms on an article include coating or impregnating the article with the antifouling composition, where the organisms live in fresh water or salt water.
대표청구항▼
1. An antifouling composition comprising: a first monomer represented by Formula IA: wherein: L is absent, alkylenyl, alkenylenyl, or arylene, wherein the alkylenyl and alkenylenyl are optionally interrupted with one or more oxygen or sulfur atoms;X1 is absent, amino, oxo, thio, or phosphino;PG1 is
1. An antifouling composition comprising: a first monomer represented by Formula IA: wherein: L is absent, alkylenyl, alkenylenyl, or arylene, wherein the alkylenyl and alkenylenyl are optionally interrupted with one or more oxygen or sulfur atoms;X1 is absent, amino, oxo, thio, or phosphino;PG1 is an acrylyl, methacrylyl, epoxyl, isocycanyl, styrenyl, oxyvinyl, thiovinyl, ketovinyl, ketoalkyl, ketoalkoxy, ketoaryl, or cycloalkenyl;R5 and R6 are independently H, alkyl, alkenyl, aryl, or —C(O)R7;R7 is alkyl, alkenyl, or aryl; andwherein: the composition further comprises a carrier, resin, stabilizer, corrosion inhibitor, or a combination of any two or more thereof. 2. The antifouling composition of claim 1, wherein PG1 is C(O)C(R10)═CH2, C(O)CH═CH2, O—CH═CH2, S—CH═CH2, N═C═O, and R10 is a C1-C8 alkyl. 3. The antifouling composition of claim 1, wherein PG1 is C(O)C(R10)═CH2; and R10 is H, C1-C8 alkyl, aryl, or CN. 4. The antifouling composition of claim 3, wherein PG1 is C(O)CH═CH2. 5. The antifouling composition of claim 1, wherein X1 is NH, O, S, or PH. 6. The antifouling composition of claim 1, wherein L is C1-C10 alkylenyl or arylene, wherein the C1-C10 alkylenyl is optionally interrupted with one or more oxygen or sulfur atoms. 7. The antifouling composition of claim 1, wherein R5 is —C(O)alkyl and R6 is C(O)alkyl. 8. The antifouling composition of claim 1, wherein L is C1-C10 alkyl. 9. The antifouling composition of claim 1, wherein X1 is O. 10. The antifouling composition of claim 1, further comprising a polymerization product of the first monomer represented by Formula IA, and a second monomer, wherein the second monomer comprises a polymerizable group PG2, which is configured to polymerize with PG1. 11. The antifouling composition of claim 10, wherein the polymerization product comprises 0.1 wt % to 25 wt % of the first monomer represented by Formula IA. 12. The antifouling composition of claim 10, wherein the second monomer is an acrylate or a methacrylate. 13. The antifouling composition of claim 12, wherein the second monomer is represented by Formula II: wherein: R8 is H; CN; CF3; CH3; or phenyl; andR9 is H; C1-C22 alkyl; aryl; Na+, Li+, or K′. 14. An article coated or impregnated with an antifouling composition, wherein the antifouling composition comprises: a first monomer represented by Formula IA: wherein: L is absent, alkylenyl, alkenylenyl, or arylene, wherein the alkylenyl and alkenylenyl are optionally interrupted with one or more oxygen or sulfur atoms;X1 is absent, amino, oxo, thio, or phosphino;PG1 is an acrylyl, methacrylyl, epoxyl, isocycanyl, styrenyl, oxyvinyl, thiovinyl, ketovinyl, ketoalkyl, ketoalkoxy, ketoaryl, or cycloalkenyl;R5 and R6 are independently H, alkyl, alkenyl, aryl, or —C(O)R7;R7 is alkyl, alkenyl, or aryl; andwherein: the composition further comprises a carrier, resin, stabilizer, corrosion inhibitor, or a combination of any two or more thereof. 15. A method of killing or deterring the growth of one or more organisms on an article, wherein the organisms grow in an aqueous environment, wherein the method includes contacting the article with an antifouling composition comprising: a first monomer represented by Formula IA: wherein: L is absent, alkylenyl, alkenylenyl, or arylene, wherein the alkylenyl and alkenylenyl are optionally interrupted with one or more oxygen or sulfur atoms;X1 is absent, or is amino, oxo, thio, or phosphino;PG1 is an acrylyl, methacrylyl, epoxyl, isocycanyl, styrenyl, oxyvinyl, thiovinyl, ketovinyl, ketoalkyl, ketoalkoxy, ketoaryl, or cycloalkenyl;R5 and R6 are independently H, alkyl, alkenyl, aryl, or —C(O)R7;R7 is alkyl, alkenyl, or aryl;wherein: the composition further comprises a carrier, a resin, a stabilizer, corrosion inhibitor, or a combination of any two or more thereof; andexposing the article to an aqueous environment. 16. The antifouling composition of claim 10, comprising the polymerization product of wherein: PG2a is the polymerized form of the second monomer comprising the polymerization group PG2;L is an alkylene or arylene group; andn and n′ represent the repeat units of the polymerization product.
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