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The invention includes a cross-linking composition comprising a cross-linking compound and a cross-linking reaction additive selected from an organic acid and/or an acetate compound, wherein the cross-linking compound has the structure according to formula (IV): wherein the cross-linking reaction a

The invention includes a cross-linking composition comprising a cross-linking compound and a cross-linking reaction additive selected from an organic acid and/or an acetate compound, wherein the cross-linking compound has the structure according to formula (IV): wherein the cross-linking reaction additive is capable of reacting with the cross-linking compound to form a reactive oligomer intermediate, which is capable of cross-linking an organic polymer. Also included is an organic polymer composition for use in forming a cross-linked organic polymer, comprising a cross-linking compound of Formula (IV), a cross-linking reaction additive and at least one organic polymer. In one embodiment, the at least one organic polymer has at least one halogen-containing reactive group and is dehalogenated by reacting with an alkali metal compound. Methods for making such compositions as well as articles of manufacture formed from such methods and organic polymer compositions, wherein the compositions and methods control the cross-linking reaction rate of a crosslinking compound for use in cross-linking an organic polymer are also included.

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1. A composition comprising a cross-linking compound and a cross-linking reaction additive selected from an organic acid and/or an acetate compound, wherein the cross-linking compound has a structure according to formula (IV): wherein A is an arene moiety having a molecular weight of less than 10,0

1. A composition comprising a cross-linking compound and a cross-linking reaction additive selected from an organic acid and/or an acetate compound, wherein the cross-linking compound has a structure according to formula (IV): wherein A is an arene moiety having a molecular weight of less than 10,000 g/mol, R1 is selected from the group consisting of hydroxide (—OH), amine (—NH2), halide, ether, ester, or amide, and x is about 2.0 to about 6.0, wherein the cross-linking reaction additive is capable of reacting with the cross-linking compound to form a reactive intermediate in the form of an oligomer, which reactive intermediate oligomer is capable of cross-linking an organic polymer. 2. The composition according to claim 1, wherein the cross-linking compound has a structure selected from the group consisting of 3. The composition according to claim 1, wherein the arene moiety has a molecular weight of about 1,000 g/mol to about 9,000 g/mol. 4. The composition according to claim 3, wherein the arene moiety has a molecular weight of about 2,000 g/mol to about 7,000 g/mol. 5. The composition according to claim 1, wherein the cross-linking reaction additive is an organic acid selected from glacial acetic acid, formic acid, and/or benzoic acid. 6. The composition according to claim 1, wherein the cross-linking reaction additive is an acetate compound having a structure according to formula (II): wherein M is a Group I or a Group II metal; and R2 is a alkyl, aryl or aralkyl group, wherein the alkyl group comprises a hydrocarbon group of 1 to about 30 carbon atoms which has from 0 to about 10 ester or ether groups along or in a chain or structure of the group, and wherein R2 comprises 0 to about 10 functional groups selected from sulfate, phosphate, hydroxyl, carbonyl, ester, halide, mercapto or potassium. 7. The composition according to claim 6, wherein the acetate compound is selected from lithium acetate hydrate sodium acetate, and/or potassium acetate, and salts and derivatives thereof. 8. The composition according to claim 1, wherein the weight percentage ratio of the cross-linking compound to the cross-linking reaction additive is about 10:1 to about 10,000:1. 9. The composition according to claim 8, wherein the weight percentage ratio of the cross-linking compound to the cross-linking reaction additive is about 20:1 to about 1000:1. 10. The composition according to claim 1, further comprising at least one organic polymer, wherein the cross-linking reaction additive is capable of reacting with the cross-linking compound to form a reactive intermediate in the form of an oligomer, which reactive intermediate oligomer is capable of cross-linking the organic polymer. 11. The organic polymer composition according to claim 10, wherein the organic polymer is selected from poly(arylene ether)s, polysulfones, polyethersulfones, polyimides, polyamides, polyureas, polyurethanes, polyphthalamides, polyamide-imides, poly(benzimidazole)s and polyaramids. 12. The organic polymer composition according to claim 11, wherein the organic polymer is a poly(arylene ether) including polymer repeating units having the following structure: (—O—Ar1—O—Ar2—)m(—O—Ar3—O—Ar4—)n wherein Ar1, Ar2, Ar3 and Ar4 are identical or different aryl radicals, m=0 to 1.0, and n=1−m. 13. The organic polymer composition according to claim 12, wherein the organic polymer is a poly(arylene ether), m is 1 and n is 0 and the polymer has repeating units having the structure of formula (V): 14. The organic polymer composition according to claim 10, wherein the cross-linking reaction additive is an organic acid selected from glacial acetic acid, formic acid and/or benzoic acid. 15. The organic polymer composition according to claim 10, wherein the cross-linking reaction additive is an acetate compound having a structure according to formula (II): wherein M is a Group I or a Group II metal; and R2 is a alkyl, aryl or aralkyl group, wherein the alkyl group comprises a hydrocarbon group of 1 to about 30 carbon atoms which has from 0 to about 10 ester or ether groups along or in a chain or structure of the group, and wherein R2 comprises 0 to about 10 functional groups selected from sulfate, phosphate, hydroxyl, carbonyl, ester, halide, mercapto or potassium. 16. The organic polymer composition according to claim 10, wherein the weight percentage ratio of the organic polymer to the combined weight of the cross-linking compound and the cross-linking reaction additive is about 1:1 to about 100:1. 17. The organic polymer composition according to claim 16, wherein the weight percentage ratio of the organic polymer to the combined weight of the cross-linking compound and the cross-linking reaction additive is about 3:1 to about 10:1. 18. The organic polymer composition according to claim 10, wherein the composition further comprises at least one additive selected from continuous or discontinuous, long or short, reinforcing fibers selected from carbon fibers, glass fibers, woven glass fibers, woven carbon fibers, aramid fibers, boron fibers, polytetrafluorethylene fibers, ceramic fibers, polyamide fibers; and one or more fillers selected from carbon black, silicate, fiberglass, calcium sulfate, boron, ceramic, polyamide, asbestos, fluorographite, aluminum hydroxide, barium sulfate, calcium carbonate, magnesium carbonate, silica, alumina, aluminum nitride, borax (sodium borate), activated carbon, pearlite, zinc terephthalate, graphite, talc, mica, silicon carbide whiskers or platelets, nanofillers, molybdenum disulfide, fluoropolymer, carbon nanotubes and fullerene tubes. 19. The organic polymer composition according to claim 18, wherein the composition comprises about 0.5% to about 65% by weight of the at least one additive. 20. The organic polymer composition according to claim 10, wherein the composition further comprises a stabilizer, a flame retardant, a pigment, a plasticizer, a surfactant, and or a dispersant. 21. A molded article formed from the composition according to claim 10. 22. The molded article according to claim 21, wherein the article is molded using extrusion, injection molding, blow molding, blown film molding, compression molding or injection/compression molding. 23. An article of manufacture formed from the composition according to claim 10, wherein the article of manufacture is selected from acid-resistant coatings; chemical-casted films; extruded films; solvent-casted films; blown films; encapsulated products; insulation; packaging; composite cells; connectors; sealing assemblies, including O-rings, V-rings, U-cups, gaskets; bearings; valve seats; adapters; wiper rings; chevron back-up rings; and tubing. 24. An organic polymer composition for use in forming a cross-linked organic polymer, comprising: an organic polymer; anda reactive cross-linking oligomer which is a reaction product of a cross-linking compound having the structure of formula (IV): wherein A is an arene moiety having a molecular weight of less than 10,000 g/mol, R1 is selected from a group consisting of hydroxide (—OH), amine (—NH2), halide, ether, ester, or and amide, and x is about 2.0 to about 6.0, and a cross-linking reaction additive selected from an organic acid and/or an acetate compound. 25. A molded article formed from the composition of claim 24. 26. A method of controlling the cross-linking reaction rate of a cross-linking compound for use in cross-linking an organic polymer, comprising: a) providing a cross-linking composition comprising a cross-linking compound and a cross-linking reaction additive selected from an organic acid and/or an acetate compound, wherein the cross-linking compound has the structure according to formula (IV): wherein A is an arene moiety having a molecular weight of less than 10,000 g/mol, R1 is selected from a group consisting of hydroxide (—OH), amine (—NH2), halide, ether, ester, or amide, and x is about 2.0 to about 6.0, wherein the cross-linking reaction additive is capable of reacting with the cross-linking compound to form a reactive intermediate in the form of an oligomer for cross-linking an organic polymer; and b) heating the cross-linking composition such that oligomerization of the cross-linking compound occurs. 27. The method according to claim 26, wherein step (b) further comprises heating the cross linking composition before heat molding. 28. The method according to claim 26, wherein the cross-linking reaction additive is an organic acid selected from glacial acetic acid, formic acid and/or benzoic acid, and/or an acetate compound selected from lithium acetate, hydrate sodium acetate, and/or potassium acetate, and salts and derivatives thereof. 29. The method according to claim 26, further comprising combining the cross-linking compound and the cross-linking reaction additive in solid form in step (a). 30. The method according to claim 26, further comprising combining the cross-linking compound and the cross-linking reaction additive in a solvent in step (a) and reacting the cross-linking compound and the cross-linking reaction additive to form a reactive oligomerized cross-linking compound. 31. The method according to claim 30, further comprising (c) adding the reactive oligomerized cross-linking compound to an organic polymer to form a cross-linkable composition and(d) cross-linking the organic polymer composition to form a cross-linked organic polymer. 32. The method according to claim 31, further comprising adding at least one additive in step (c). 33. The method according to claim 26, wherein the organic polymer is selected from poly(arylene ether)s, polysulfones, polyethersulfones, polyimides, polyamides, polyureas, polyurethanes, polyphthalamides, polyamide-imides, poly(benzimidazole)s and/or polyaramids. 34. The method according to claim 33, wherein the organic polymer is a poly(arylene ether) including polymer repeating units having the following structure: (—O—Ar1—O—Ar2—)m(—O—Ar3—O—Ar4—)n wherein Ar1, Ar2, Ar3 and Ar4 are identical or different aryl radicals, m=0 to 1.0, n=1−m. 35. An organic polymer composition for use in forming a cross-linked organic polymer, comprising: a dehalogenated organic polymer andat least one cross-linking compound; wherein the dehalogenated organic polymer is formed by a process comprising reacting an organic polymer having at least one halogen-containing reactive group with an alkali metal compound to break a bond between the organic polymer having the at least one halogen-containing reactive group and a halogen atom in the at least one halogen-containing reactive group to form an intermediate. 36. The organic polymer composition according to claim 35, wherein the dehalogenated organic polymer is a debrominated organic polymer. 37. The organic polymer composition according to claim 35, wherein the cross-linking compound has a structure according to formula (IV): wherein A is an arene moiety having a molecular weight of less than 10,000 g/mol R1 is selected from a group consisting of hydroxide (—OH), amine (—NH2), halide, ether, ester, or amide, and x is about 2.0 to about 6.0. 38. The organic polymer composition according to claim 35, further comprising a cross-linking reaction additive selected from an organic acid and/or an acetate compound, wherein the cross-linking reaction additive is capable of reacting with the cross-linking compound to form a reactive intermediate in the form of an oligomer, which reactive intermediate oligomer is capable of cross-linking the dehalogenated organic polymer. 39. The organic polymer composition according to claim 35, wherein the dehalogenated organic polymer is a polymer selected from poly(arylene ether)s, polysulfones, polyethersulfones, polyimides, polyamides, polyureas, polyurethanes, polyphthalamides, polyamide-imides, poly(benzimidazole)s and polyaramids. 40. The organic polymer composition according to claim 39, wherein the dehalogenated organic polymer is a poly(arylene ether) including polymer repeating units in its backbone having the following structure: (—O—Ar1—O—Ar2—)m(—O—Ar3—O—Ar4—)n wherein Ar1, Ar2, Ar3 and Ar4 are identical or different aryl radicals, m=0 to 1.0, and n=1−m. 41. The organic polymer composition according to claim 40, wherein the dehalogenated organic polymer is a poly(arylene ether), m is 1 and n is 0 and the polymer has repeating units along its backbone having the structure of formula (V): 42. The organic polymer composition according to claim 35, wherein the composition further comprises at least one additive selected from continuous or discontinuous, long or short, reinforcing fibers selected from carbon fibers, glass fibers, woven glass fibers, woven carbon fibers, aramid fibers, boron fibers, polytetrafluorethylene fibers, ceramic fibers, polyamide fibers; and one or more fillers selected from carbon black, silicate, fiberglass, calcium sulfate, boron, ceramic, polyamide, asbestos, fluorographite, aluminum hydroxide, barium sulfate, calcium carbonate, magnesium carbonate, silica, alumina, aluminum nitride, borax (sodium borate), activated carbon, pearlite, zinc terephthalate, graphite, talc, mica, silicon carbide whiskers or platelets, nanofillers, molybdenum disulfide, fluoropolymer, carbon nanotubes and fullerene tubes. 43. The organic polymer composition according to claim 35, wherein the dehalogenated organic polymer is formed by reacting an organic polymer having at least one halogen-containing reactive group with an alkali metal compound to break a bond between the organic polymer having the at least one halogen-containing reactive group and a halogen atom in the at least one halogen-containing reactive group, and to form an intermediate; andreacting the intermediate with acetic acid to form the dehalogenated organic polymer. 44. The organic polymer composition according to claim 43, wherein the alkali metal compound is selected from the group consisting of R3—M′, wherein M′ is an alkali metal and R3 is H or a branched or straight chain organic group selected from alkyl, alkenyl, aryl and aralkyl groups of from 1 to about 30 carbon atoms having from 0 to about 10 ester or ether groups along or in a chain or structure of the group, and wherein R3 may be substituted or unsubstituted. 45. The organic polymer composition according to claim 44, wherein the alkali metal compound is t-butyllithium. 46. The organic polymer composition according to claim 43, wherein the halogen-containing reactive group is a bromine-containing reactive group. 47. The organic polymer composition according to claim 43, wherein the organic polymer having at least one halogen-containing end group is reacted with the alkali metal compound in a solvent and the organic polymer having the at least one halogen-containing end group is dried prior to reacting in the solvent. 48. A molded article formed from the composition according to claim 35. 49. A method of controlling the cross-linking reaction rate of an organic polymer having at least one halogen-containing reactive group during a cross-linking reaction, comprising: a) reacting the organic polymer having at least one halogen-containing reactive group with an alkali metal compound to break a bond between the organic polymer having the at least one halogen-containing reactive group and a halogen atom in the at least one halogen-containing reactive group, and to form an intermediate having carbocation;b) reacting the intermediate having the carbocation with acetic acid to form a dehalogenated organic polymer; andc) crosslinking the dehalogenated organic polymer using a crosslinking reaction. 50. The method according to claim 49, wherein the at least one halogen-containing reactive group is a terminal group and the organic polymer having the at least one halogen-containing reactive group is a polymer selected from poly(arylene ether)s, polysulfones, polyethersulfones, polyimides, polyamides, polyureas, polyurethanes, polyphthalamides, polyamide-imides, poly(benzimidazole)s, and polyaramids. 51. The method according to claim 49, wherein the at least one halogen-containing reactive group is represented by —R4—(X)p, wherein R4 is carbon or a branched or straight chain organic group selected from alkyl, alkenyl, aryl and aralkyl groups of from 1 to about 30 carbon atoms having from 0 to about 10 ester or ether groups along or in a chain or structure of the group, and wherein R4 may be substituted or unsubstituted; and X is a halogen atom and p is an integer that is 1 or 2. 52. The method according to claim 49, wherein the alkali metal compound is selected from the group consisting of R3—M′, wherein M′ is an alkali metal and R3 is H or a branched or straight chain organic group selected from alkyl, alkenyl, aryl and aralkyl groups of from 1 to about 30 carbon atoms having from 0 to about 10 ester or ether groups along or in a chain or structure of the group, and wherein R3 may be substituted or unsubstituted. 53. The method according to claim 52, wherein the alkali metal compound is t-butyllithium. 54. The method according to claim 49, wherein the organic polymer having the at least one halogen-containing end group is reacted with the alkali metal compound in a solvent. 55. The method according to claim 54, wherein the solvent is capable of dissolving the organic polymer having the at least one halogen-containing reactive group and is free of functional groups that react with the halogen in the halogen-containing reactive group under reaction conditions for step (a). 56. The method according to claim 55, wherein the solvent is selected from a heptane, a hexane, tetrahydrofuran, and a diphenyl ether. 57. The method according to claim 54, wherein the organic polymer having the at least one halogen-containing end group is dried prior to reacting with the alkali metal compound in the solvent. 58. The method according to claim 49, wherein step (a) occurs at a temperature of less than about −20° C. 59. The method according to claim 58, wherein step (a) occurs at a temperature of less than about −70° C. for a period of about 2 hours. 60. The method according to claim 49, wherein step (c) further comprises: reacting the dehalogenated organic polymer with a cross-linking compound. 61. The method according to claim 60, wherein step (c) further comprises providing a cross-linking reaction additive selected from an organic acid and/or an acetate compound, wherein the cross-linking reaction additive is capable of reacting with the cross-linking compound to form a reactive intermediate in the form of an oligomer, which reactive intermediate oligomer is capable of cross-linking the dehalogenated organic polymer. 62. The method according to claim 61, further comprising before step (c) heating the cross-linking compound and the cross-linking reaction additive in a separate composition such that oligomerization of the cross-linking compound occurs to form the reactive intermediate oligomer. 63. The method according to claim 49, further comprising heat molding the cross-linked organic polymer to form a heat-molded article of manufacture. 64. The method according to claim 63, wherein the article of manufacture is heat molded using extrusion, injection molding, blow molding, blown film molding, compression molding or injection/compression molding. 65. The method according to claim 63, wherein the article of manufacture is selected from acid-resistant coatings; chemical-casted films; extruded films; solvent-casted films; blown films; encapsulated products; insulation; packaging; composite cells; connectors; sealing assemblies, including O-rings, V-rings, U-cups, gaskets; bearings; valve seats; adapters; wiper rings; chevron back-up rings; and tubing.