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A process by which molten solder is purified in-situ, making the soldering process more efficient and yielding better results, particularly for lead-free soldering. Lead-free solder becomes practical for use since the temperature for reliable soldering is reduced. A layer of active additive is maint

A process by which molten solder is purified in-situ, making the soldering process more efficient and yielding better results, particularly for lead-free soldering. Lead-free solder becomes practical for use since the temperature for reliable soldering is reduced. A layer of active additive is maintained on the surface of molten solder for scavenging metal oxide from the solder and assimilating metal oxide into a liquid layer. The active additive is an organic liquid having nucleophilic and/or electrophilic groups. As an example, a layer of dimer acid maintained on a wave soldering apparatus scavenges metal oxide from the bath, and assimilates dross that may form on the surface. Scavenging metal oxide cleanses the bath and lowers viscosity of the solder, and PC boards or the like soldered on the wave have reliable solder joints.

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1. A method of processing dross to recover molten solder entrained therein, comprising: (i) removing dross from a solder-bath, wherein the dross comprises entrained solder,(ii) placing the dross from (i) in a receptacle,(iii) adding a liquid active additive comprising a dimer acid mixture to the rec

1. A method of processing dross to recover molten solder entrained therein, comprising: (i) removing dross from a solder-bath, wherein the dross comprises entrained solder,(ii) placing the dross from (i) in a receptacle,(iii) adding a liquid active additive comprising a dimer acid mixture to the receptacle containing the dross to form a dross-active additive mixture, wherein the dimer acid mixture comprises a mixture of fatty acid dimers, monomers and trimers, and has an average carbon number in a range of about 24 to 60, and(iv) heating the dross-active additive mixture from (iii) to thereby assimilate dross in the liquid active additive and release molten solder from the dross. 2. The method of claim 1, wherein the dross-active additive mixture is stirred during heating. 3. The method of claim 1, whereby as a result of heating, a pool of released molten solder forms under a layer of the liquid active additive. 4. The method of claim 1, wherein the dimer acid mixture has an average carbon number in a range of about 28-44. 5. The method of claim 1, wherein the dimer acid mixture comprises a major portion of dimer acid. 6. The method of claim 1, wherein the dimer acid mixture comprises a small amount of monomers and trimers. 7. The method of claim 1, wherein the entrained solder comprises a lead-tin mixture. 8. The method of claim 1, wherein the entrained solder is a lead-free solder. 9. The method of claim 1, further comprising (v) recovering the released molten solder. 10. The method of claim 1, wherein the removing step comprises skimming dross off of a surface of a solder bath. 11. The method of claim 1, further comprising recovering the liquid active additive comprising assimilated dross. 12. The method of claim 11, further comprising roasting the recovered liquid active additive comprising assimilated dross. 13. The method of claim 1, wherein the liquid active additive is a viscous liquid. 14. The method of claim 1, where in step (iv), the dross-active additive mixture is heated above the melting point of the solder. 15. The method of claim 1, wherein the dimer acid mixture is prepared from a tall oil feedstock. 16. The method of claim 5, wherein the dimer acid mixture comprises from about 80-90% fatty acid dimers.