Method for producing wood fibre-plastics composite products
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
C08L-063/00
B27N-001/00
B27N-003/04
C08J-005/04
B29B-009/04
B29B-009/14
출원번호
US-0381511
(2010-06-30)
등록번호
US-9283692
(2016-03-15)
우선권정보
NZ-578110 (2009-06-30)
국제출원번호
PCT/NZ2010/000131
(2010-06-30)
§371/§102 date
20120322
(20120322)
국제공개번호
WO2011/002314
(2011-01-06)
발명자
/ 주소
Warnes, Jeremy Martin
Fernyhough, Alan
출원인 / 주소
NEW ZEALAND FOREST RESEARCH INSTITUTE LIMITED
대리인 / 주소
Sughrue Mion, PLLC
인용정보
피인용 횟수 :
0인용 특허 :
12
초록▼
A process for producing a composite product comprising fibers of a lignocellulosic material or natural fibers and a plastics material utilizes a liquid or particulate binder formulation comprising a thermoset resin and a thermoplastic polymer, monomer, or oligomer. A composite product is formed for
A process for producing a composite product comprising fibers of a lignocellulosic material or natural fibers and a plastics material utilizes a liquid or particulate binder formulation comprising a thermoset resin and a thermoplastic polymer, monomer, or oligomer. A composite product is formed for use as or in forming a feedstock in plastics manufacture may be broken down under heat and mechanical shearing in a plastics extrusion machine to release the major fraction of the fibers, or the product may be useful as an intermediate product in other form or as an end product.
대표청구항▼
1. A process for producing a product comprising wood fibres, for use as or in forming a feedstock in plastics manufacture, which comprises applying to lose or divided wood fibres or wood fibre bundles, produced by mechanically or thermomechanically or chemo-thermomechanically or chemo-mechanically b
1. A process for producing a product comprising wood fibres, for use as or in forming a feedstock in plastics manufacture, which comprises applying to lose or divided wood fibres or wood fibre bundles, produced by mechanically or thermomechanically or chemo-thermomechanically or chemo-mechanically breaking down wood, a liquid or particulate binder formulation comprising a thermoset resin and a thermoplastic polymer, monomer, or oligomer, and consolidating the fibres into a solid product which may be subsequently broken down to release a major fraction of the fibres, the thermoset resin being selected from a formaldehyde-based polymer and an isocyanate, the solid product comprising less than 10 parts of the binder formulation per 100 parts of wood fibre by dried weight and from about 0.3 to about 5 parts of the thermoset resin per 100 parts of wood fibre by dried weight. 2. A process according to claim 1 wherein the binder formulation comprises less than 8 parts per 100 parts of fibre by dried weight. 3. A process according to claim 1 wherein the thermoplastic polymer, monomer, or oligomer is present relative to the thermoset resin in a weight ratio up to about 50:50. 4. A process according to claim 1 wherein the solid product may be broken down under heat and mechanical shearing in a plastics manufacturing process to release the major fraction of the fibres. 5. A process according to claim 4 wherein the major fraction of the fibres may be broken down with reduced damage to the fibres relative to breaking down in the same way of an equivalent solid product produced by the same process, but for an absence of the thermoplastic polymer, monomer, or oligomer in the binder formulation. 6. A process according to claim 1 wherein the binder formulation comprises a mixture of the thermoset resin and thermoplastic polymer, monomer, or oligomer or wherein the binder formulation comprises the thermoplastic polymer, monomer, or oligomer incorporated into the thermoset resin structure. 7. A process according to claim 1 which comprises separately applying the thermoset resin and the thermoplastic polymer, monomer, or oligomer components of the binder formulation to the fibres. 8. A process according to claim 1 comprising applying the binder formulation or components thereof to the fibres while conveying the fibres in a dry or wet air stream. 9. A process according to claim 1 wherein the fibres have an average fibre length or fibre-bundle length of at least about 0.8 mm. 10. A process according to claim 1, wherein a major fraction of the fibres have an aspect ratio of at least 10:1. 11. A process according to claim 1 including breaking down the solid product to produce pellets which are longer than the average fibre length of the fibres within the pellets. 12. A process according to claim 1 wherein the thermoplastic polymer is polyethylene, polypropylene, polystyrene, polyvinyl alcohol, polyvinyl acetate, polyvinyl butyrate, polyester, polyacrylate, or starch based, or is a polymer or copolymer with one or more of a co-monomer with acid, anhydride, epoxy, amine, isocyanate, silane, or silanol functional group, or is a copolymer or terpolymer or other polymer of ethylene and/or propylene and/or butadiene and/or styrene and/or acrylonitrile, and one or more of vinyl acetate, vinyl butyrate, maleic anhydride/acid, acrylic or methacrylic acid or their esters, glycidyl methacrylate or acrylate. 13. A process according to claim 1 wherein the solid product has an internal bond strength of at least 0.5 MPa. 14. A process according to claim 1 including forming the fibres into a solid product by pressing the fibres to a solid product in planar form in a heated press. 15. A process according to claim 1 including breaking down said solid product to said pellets or granules by cutting or sawing the solid product. 16. A process for producing pellets or granules comprising wood fibres, for use as a feedstock in plastics manufacture, which comprises: conveying loose or divided wood fibres or wood fibre bundles, produced by mechanically or thermomechanically or chemo-thermomechanically or chemo-mechanically breaking down wood, in a dry or wet air stream and applying to the fibres, while so conveying the fibres, a liquid formulation comprising urea formaldehyde and one or more thermoplastic polymers, monomers, or oligomers, or a low amount of urea formaldehyde resin binder,forming the fibres into a solid product, andbreaking down the solid product to produce said pellets or granules,the pellets or granules comprising less than 10 parts of the liquid formulation per 100 parts of wood fibre by dried weight and from about 0.3 to about 5 parts of the urea formaldehyde per 100 parts of wood fibre by dried weight. 17. A panel product comprising wood fibres and a binder formulation, the binder formulation comprising a thermoset resin and a thermoplastic polymer, monomer, or oligomer, the thermoset resin being selected from a formaldehyde-based polymer and an isocyanate, the panel product comprising less than 10 parts of binder formulation per 100 parts of fibre by dried weight and from about 0.3 to about 5 parts of the thermoset resin per 100 parts of fibre by dried weight. 18. Pellets or granules comprising wood fibres and a binder formulation, the binder formulation comprising a thermoset resin and a thermoplastic polymer, monomer, or oligomer, the thermoset resin being selected from a formaldehyde-based polymer, and an isocyanate, the pellets or granules comprising less than 10 parts of binder formulation per 100 parts of fibre by dried weight and from about 0.3 to about 5 parts of the thermoset resin per 100 parts of fibre by dried weight. 19. A process for manufacture of plastics products or intermediates which includes introducing pellets or granules of claim 18 as a feedstock into a plastics extrusion or moulding machine. 20. A process according to claim 19 including also introducing into the plastics extrusion or moulding machine to mix with the fibres a coupling agent between the fibres and plastics material. 21. A process according to claim 19 including also introducing into the plastics extrusion or moulding machine as a coupling agent any one or more of an organic acid, maleated polyolefin, a maleic anhydride or acid, silane, silicate, titanate, chlorotriazine, anhydride, epoxide, isocyanate, acrylate, amide, imide, acrylic-modified polytetrafluoroethylene, a chloroparafin or abietic acid. 22. A process according to claim 19 wherein the thermoplastic polymer comprises polypropylene and the coupling agent comprises maleic anhydride polypropylene or the thermoplastic polymer comprises polyethylene and the coupling agent comprises maleic anhydride polyethylene. 23. A plastics-fibre composite product produced by the process of claim 19. 24. A panel according to claim 17 wherein the thermoplastic polymer, monomer, or oligomer is present relative to the thermoset resin in a weight ratio up to about 50:50. 25. Pellets or granules according to claim 18 wherein the thermoplastic polymer, monomer, or oligomer is present relative to the thermoset resin in a weight ratio up to about 50:50. 26. A process according to claim 19 wherein the thermoplastic polymer, monomer, or oligomer is present relative to the thermoset resin in a weight ratio up to about 50:50, 40:60, 20:80 or 10:90. 27. A panel according to claim 17 wherein the thermoplastic polymer, monomer, or oligomer is present relative to the thermoset resin in a weight ratio up to about 40:60. 28. A panel according to claim 17 wherein the thermoplastic polymer, monomer, or oligomer is present relative to the thermoset resin in a weight ratio up to about 20:80. 29. A panel according to claim 17 wherein the thermoplastic polymer, monomer, or oligomer is present relative to the thermoset resin in a weight ratio up to about 10:90. 30. Pellets or granules according to claim 18 wherein the thermoplastic polymer, monomer, or oligomer is present relative to the thermoset resin in a weight ratio up to about 40:60. 31. Pellets or granules according to claim 18 wherein the thermoplastic polymer, monomer, or oligomer is present relative to the thermoset resin in a weight ratio up to about 20:80. 32. Pellets or granules according to claim 18 wherein the thermoplastic polymer, monomer, or oligomer is present relative to the thermoset resin in a weight ratio up to about 10:90. 33. A panel according to claim 17 wherein the formaldehyde-based polymer is urea formaldehyde. 34. A panel according to claim 27 wherein the formaldehyde-based polymer is urea formaldehyde. 35. A panel according to claim 28 wherein the formaldehyde-based polymer is urea formaldehyde. 36. A panel according to claim 29 wherein the formaldehyde-based polymer is urea formaldehyde. 37. Pellets or granules according to claim 18 wherein the formaldehyde-based polymer is urea formaldehyde. 38. Pellets or granules according to claim 30 wherein the formaldehyde-based polymer is urea formaldehyde. 39. Pellets or granules according to claim 31 wherein the formaldehyde-based polymer is urea formaldehyde. 40. Pellets or granules according to claim 32 wherein the formaldehyde-based polymer is urea formaldehyde. 41. A panel according to claim 17 wherein the thermoplastic polymer, monomer, or oligomer is present relative to the thermoset resin in a weight ratio of about 1:99 to about 50:50. 42. Pellets or granules according to claim 18 wherein the thermoplastic polymer, monomer, or oligomer is present relative to the thermoset resin in a weight ratio of about 1:99 to about 50:50. 43. A panel according to claim 17 wherein the thermoplastic polymer, monomer, or oligomer is present relative to the thermoset resin in a weight ratio of about 1:99 to about 40:60. 44. Pellets or granules according to claim 18 wherein the thermoplastic polymer, monomer, or oligomer is present relative to the thermoset resin in a weight ratio of about 1:99 to about 40:60. 45. A panel according to claim 17 wherein the thermoplastic polymer, monomer, or oligomer is present relative to the thermoset resin in a weight ratio of about 10:90 to about 50:50. 46. Pellets or granules according to claim 18 wherein the thermoplastic polymer, monomer, or oligomer is present relative to the thermoset resin in a weight ratio of about 10:90 to about 50:50. 47. A panel according to claim 17 wherein the thermoplastic polymer, monomer, or oligomer is present relative to the thermoset resin in a weight ratio of about 10:90 to about 40:60. 48. Pellets or granules according to claim 18 wherein the thermoplastic polymer, monomer, or oligomer is present relative to the thermoset resin in a weight ratio of about 10:90 to about 40:60. 49. A process according to claim 2 wherein the binder formulation comprises less than 5 parts per 100 parts of fibre by dried weight. 50. A process according to claim 10, wherein a major fraction of the fibres have an aspect ratio of at least 20:1.
연구과제 타임라인
LOADING...
LOADING...
LOADING...
LOADING...
LOADING...
이 특허에 인용된 특허 (12)
Chen,Gang Fung; Hupp,Stephen; Schell,Philip L., Adhesive additives and adhesive compositions containing an adhesive additive.
Kopp Otto (Neu-Ulm DEX) Holzer Helmut (Neu-Ulm DEX) Birnbaum geb. Schinko Charlotte (Neu-Ulm DEX), Carrier materials impregnated with thermosetting resins, process for their manufacture and their use.
Raj Govinda (3915 Louis-Pinard ; App. 3 Trois-Rivires ; Qubec CAX G8Y 2G2) Kokta Bohuslav V. (4045 de la Sapinire Trois-Rivires ; Qubec CAX G8Y 1B2), Process for chemical treatment of discontinuous cellulosic fibers and composites of polyethylene and treated fibers.
Ronden Clifford P.,CAX ; Morin Joseph C.,CAX, Process for the production of composites of co-mingled thermoset resin bonded wood waste blended with thermoplastic pol.
※ AI-Helper는 부적절한 답변을 할 수 있습니다.