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특허 상세정보

Hydroconversion multi-metallic catalysts and method for making thereof

국가/구분 United States(US) Patent 등록
국제특허분류(IPC7판) B01J-027/051    B01J-027/049    B01J-027/043    B01J-027/047    B01J-035/00    B01J-035/10   
출원번호 US-0019444 (2013-09-05)
등록번호 US-9327275 (2016-05-03)
발명자 / 주소
출원인 / 주소
대리인 / 주소
    Ross, Michael D.
인용정보 피인용 횟수 : 0  인용 특허 : 106
초록

The invention relates to a self-supported mixed metal sulfide (MMS) catalyst for hydrotreating hydrocarbon feedstock and to a method for preparing the catalyst. The MMS catalyst is characterized as having a BET surface area of at least 20 m2/g and a pore volume of at least 0.05 cm3/g. In one embodiment, the MMS catalyst is also characterized as having a multi-phased structure comprising five phases: a molybdenum sulfide phase, a tungsten sulfide phase, a molybdenum tungsten sulfide phase, an active nickel phase, and a nickel sulfide phase.

대표
청구항

1. A self-supported mixed metal sulfide (MMS) catalyst comprising molybdenum (Mo) sulfide, tungsten (W) sulfide, and nickel (Ni) sulfide; wherein the catalyst has a BET surface area of at least 20 m2/g and a pore volume of at least 0.05 cm3/g; andwherein the catalyst is characterized by a Ni surface concentration/Ni bulk concentration ratio of greater than 0.4 as characterized by XPS. 2. The self-supported MMS catalyst of claim 1, wherein the catalyst has a BET surface area of at least 30 m2/g. 3. The self-supported MMS catalyst of claim 2, wherein the c...

이 특허에 인용된 특허 (106)

  1. Jacobson Allan J. (169 Cedar La. Princeton NJ 08540) Ho Teh C. (887 Jason Ct. Bridgewater NJ 08807) Chianelli Russell R. (151 Station Rd. Somerville NJ 08876) Pecoraro Theresa (2145 Canyon Oak La. Da. Amorphous, iron promoted Mo and W sulfide hydroprocessing catalysts and process for their preparation. USP1989044820677.
  2. Jacobson Allan J. (Princeton NJ) Ho Teh C. (Bridgewater NJ) Chianelli Russel R. (Somerville NJ) Pecoraro Theresa A. (Danville CA). Amorphous, iron promoted Mo and W sulfide hydroprocessing catalysts and uses thereof. USP1987054666878.
  3. Soled, Stuart L.; Miseo, Sabato; Eijsbouts, Sonja; Plantenga, Frans L.. Bulk bimetallic catalysts, method of making bulk bimetallic catalysts and hydroprocessing using bulk bimetallic catalysts. USP2010017648941.
  4. Eijsbouts-Spickova, Sona; Leliveld, Robertus Gerardus; Cerfontain, Marinus Bruce; Plantenga, Frans L.; Vogt, Eelco Titus Carel; Louwen, Jacobus Nicolaas; Soled, Stuart Leon; Miseo, Sabato; Riley, Kenneth L.. Bulk catalyst comprising nickel tungsten metal oxidic particles. USP2011118067331.
  5. Chianelli Russell R. (Somerville NJ) Pecoraro Theresa A. (Danville CA). Carbon-containing molybdenum and tungsten sulfide catalysts. USP1985044508847.
  6. Chianelli Russell R. (Somerville NJ) Pecoraro Theresa A. (Danville CA). Carbon-containing molybdenum and tungsten sulfide catalysts. USP1989054826797.
  7. Bearden ; Jr. Roby (Baton Rouge LA) Aldridge Clyde L. (Baton Rouge LA). Catalyst for the hydroconversion of heavy hydrocarbons. USP1980104226742.
  8. Michel Robert E. (Wilmington DE) Kegelman Matthew R. (Wilmington DE) Sebelist Frederick J. (Hendersonville TN). Catalyst recovery. USP1990034910175.
  9. Holzhauer Juergen K. (Naperville IL) Schammel Wayne P. (Naperville IL) Nowicki Neal R. (St. Charles IL). Catalyst recovery and recycle of catalysts in pseudocument oxidation process. USP1988114786752.
  10. Sawyer Willard H. (Baton Rouge LA) Mitchell ; III Howard L. (Baton Rouge LA). Catalysts from molybdenum polysulfide precursors and their preparation. USP1984024430442.
  11. Mitchell, III, Howard L.; Sawyer, Willard H.. Catalysts from molybdenum polysulfide precursors, their preparation and use. USP1985094542121.
  12. Sawyer, Willard H.; Mitchell, III, Howard L.. Catalysts from molybdenum polysulfide precursors, their preparation and use. USP1985094540481.
  13. Brons Glen ; Myers Ronald D.,CAX ; Bearden Roby. Continuous in-situ combination process for upgrading heavy oil. USP1999085935421.
  14. Ho Teh C. (Bridgewater NJ) McCandlish Larry E. (Highland Park NJ) Young ; II Archie R. (Montclair NJ) Osterhuber Edward J. (Phillipsburg NJ). Cr-promoted hydrotreating catalysts. USP1989054831002.
  15. William P. Addiego ; Wei Liu. Extruded honeycomb dehydrogenation catalyst and method. USP2002106461995.
  16. Lopez Jaime (Benicia CA) Pasek Eugene A. (Export PA) Cugini Anthony V. (Pittsburgh PA). Heavy oil hydroprocess including recovery of molybdenum catalyst. USP1988084762812.
  17. Lopez, Jaime; McKinney, Joel D.; Pasek, Eugene A.. Heavy oil hydroprocessing. USP1985124557821.
  18. Ferrughelli David T. ; Gorbaty Martin L.. Heavy oil upgrading process (LAW813). USP2001016171471.
  19. Kuperman, Alexander E.; Maesen, Theodorus; Dykstra, Dennis. Hydroconversion multi-metallic catalyst and method for making thereof. USP2011067964524.
  20. Aldridge Clyde L. (Baton Rouge LA) Lewis William E. (Baton Rouge LA) Bearden ; Jr. Roby (Baton Rouge LA) Mayer Francis X. (Baton Rouge LA). Hydroconversion process. USP1988084765882.
  21. Bearden ; Jr. Roby (Baton Rouge LA) Aldridge Clyde L. (Baton Rouge LA). Hydroconversion process using a sulfided molybdenum catalyst concentrate. USP1991085039392.
  22. Bearden ; Jr. Roby (Baton Rouge LA) Aldridge Clyde L. (Baton Rouge LA) Mayer Francis X. (Baton Rouge LA) Taylor James H. (Baton Rouge LA) Lewis William E. (Baton Rouge LA). Hydroconversion process using a sulfided molybdenum catalyst concentrate. USP1988044740295.
  23. Schlosberg Richard H. (Bridgewater NJ) Olmstead William N. (Berkeley Heights NJ). Hydroconversion process using aromatic metal chelate compositions. USP1989064836912.
  24. Demmin, Richard Alan; Riley, Kenneth Lloyd; Soled, Stuart Leon; Miseo, Sabato. Hydroconversion process using bulk group VIII/Group VIB catalysts. USP2003096620313.
  25. Maesen, Theodorus Ludovicus Michael; Kuperman, Alexander E.. Hydroconversion processes employing multi-metallic catalysts and method for making thereof. USP2010107807599.
  26. Bearden ; Jr. Roby (Baton Rouge LA) Aldridge Clyde L. (Baton Rouge LA). Hydrocracking with phosphomolybdic acid and phosphoric acid. USP1987014637870.
  27. Johnson David R. (San Francisco CA). Hydrodemetalation and hydrodesulfurization using a catalyst of specified macroporosity. USP1990124976848.
  28. Demmin,Richard Alan; Riley,Kenneth Lloyd; Soled,Stuart Leon; Miseo,Sabato. Hydrofining process using bulk group VIII/Group VIB catalysts. USP2007067232515.
  29. Mironov, Oleg; Kuperman, Alexander E.; Lopez, Jaime; Brait, Axel; Reynolds, Bruce; Chen, Kaidong. Hydroprocessing bulk catalyst and uses thereof. USP2010067737073.
  30. Mironov, Oleg; Kuperman, Alexander E.; Lopez, Jaime; Brait, Axel; Reynolds, Bruce; Chen, Kaidong. Hydroprocessing bulk catalyst and uses thereof. USP2010067737072.
  31. Mironov, Oleg; Kuperman, Alexander E.; Lopez, Jaime; Brait, Axel; Reynolds, Bruce; Chen, Kaidong. Hydroprocessing bulk catalyst and uses thereof. USP2011057947623.
  32. Pollitzer Ernest L. (Skokie IL) Hayes John C. (Palatine IL). Hydroprocessing of hydrocarbons. USP1977024009096.
  33. Soled,Stuart Leon; Miseo,Sabato; Krycak,Roman; Vroman,Hilda B.; Ho,Teh Chung; Riley,Kenneth Lloyd. Hydroprocessing using bulk Group VIII/Group VIB catalysts. USP2007107288182.
  34. Soled Stuart L. ; Riley Kenneth L. ; Schleicher Gary P.. Hydroprocessing using bulk Group VIII/Group VIB catalysts (HEN-9901). USP2000126162350.
  35. Soled, Stuart L.; Miseo, Sabato; Eijsbouts, Sonja; Plantenga, Frans L.. Hydroprocessing using bulk bimetallic catalysts. USP2011118062508.
  36. Hantzer, Slyvain S.; Riley, Kenneth Lloyd. Hydroprocessing using bulk group VIII/group vib catalysts. USP2004076758963.
  37. Soled, Stuart L.; Miseo, Sabato; Eijsbouts, Sonja; Plantenga, Frans L.. Hydroprocessing using hydrothermally-prepared bulk multimetallic catalysts. USP2010037686943.
  38. Jacobson Allan J. (Princeton NJ) Ho Teh C. (Bridgewater NJ) Chianelli Russell R. (Somerville NJ) Steger John J. (Pittstown NJ) Montagna Angelo A. (Summit all of NJ). Hydrotreating catalysts comprising a mixture of a sulfide of a promoter metal amorphous sulfide of trivalent chromium an. USP1988014721558.
  39. Riley, Kenneth Lloyd; Klein, Darryl Patrick; Hou, Zhiguo; Soled, Stuart Leon; Kerby, Michael Charles; McVicker, Gary Brice; Ellis, Edward Stanley; Touvelle, Michele Sue; Miseo, Sabato. Hydrotreating using bulk multimetallic catalysts. USP2004086783663.
  40. Shiroto Yoshimi (Yokohama JPX) Ono Takeo (Kawasaki JPX) Asaoka Sachio (Yokohama JPX) Nakamura Munekazu (Yokohama JPX). Hydrotreatment of heavy hydrocarbon oils containing asphaltenes, and catalysts therefor. USP1984044444655.
  41. Poloso,Anthony; Mika,Allen T. Impact strength improvement of regrind. USP2007027183005.
  42. Eadie Donald T. (North Vancouver CAX) Fefer Michael A. (Whitby CAX). Increasing VI of lube oil by hydrotreating using bulk Ni/Mn/Mo or Ni/Cr/Mo sulfide catalysts prepared from ligated metal. USP1992065122258.
  43. Davis, Stephen Mark; Matturro, Michael Gerard. Integrated bitumen production and gas conversion. USP2003036531516.
  44. Gardner Timothy J. ; Lott Stephen E. ; Lockwood Steven J. ; McLaughlin Linda I.. Material and system for catalytic reduction of nitrogen oxide in an exhaust stream of a combustion process. USP2000126165934.
  45. Wachs,Israel E; Briand,Laura E. Methanol oxidation over bulk metal vanadate catalysts. USP2007037193117.
  46. H��lzle,Markus; Sprague,Michael Jolyon; Harth,Klaus; Sch��ssler,Martin; Karl,Martin; Boneberg,Stefan. Methanol reforming catalyst having a reduced volume shrinkage. USP2008067387983.
  47. Kobayashi, Kazuki; Kikkawa, Hirofumi; Ishizaka, Hiroshi; Sasaki, Goki; Nosaka, Hiroyuki. Method and apparatus for treating discharge gas. USP2010117833501.
  48. Sato Keiichi (Tokyo JPX) Kawaragi Yuji (Yokohama JPX). Method for recovering a Group VIII metal solid complex and hydroformylation method. USP1992035099047.
  49. Ward Vincent C. (5228 Memorial Dr. Houston TX 77007). Method for recovering metallics and non-metallics from spent catalysts. USP1991075030274.
  50. Hatfield W. Robert (Westfield NJ) Heck Ronald M. (Frenchtown NJ) Hsiung Thomas H. (Piscataway NJ). Method for recovering platinum in a nitric acid plant. USP1983114412859.
  51. Walker Douglas T. (Fullerton CA). Method for removing heavy metals from aqueous solutions by coprecipitation. USP1991055013453.
  52. Niitani, Takeshi; Sawamoto, Mitsuo; Andoh, Tsuyoshi. Method for removing metal and method for producing polymer. USP2010017649079.
  53. Cerroni, Manlio. Method for the recycling of municipal solid wastes. USP2010087772453.
  54. Ho Teh C. (Bridgewater NJ) McCandlish Larry E. (Highland Park NJ). Method of making self-promoted hydrotreating catalysts. USP1986064595672.
  55. Bearden ; Jr. Roby (Baton Rouge LA) Aldridge Clyde L. (Baton Rouge LA). Method of preparing a sulfided molybdenum catalyst concentrate. USP1991105053376.
  56. Eijsbouts, Sonja; Oogjen, Bob Gerardus; Homan Free, Hermannus Willem; Cerfontain, Marinus Bruce; Riley, Kenneth Lloyd; Soled, Stuart Leon; Miseo, Sabato. Mixed metal catalyst, its preparation by co-precipitation, and its use. USP2003106635599.
  57. Trubenbach Peter,DEX ; Hagemeyer Alfred,DEX ; Lauth Gunter,DEX ; Dingerdissen Uwe,DEX ; Brocker Franz Josef,DEX ; Flick Klemens,DEX. Monomodal and polymodal catalyst supports and catalysts having narrow pore size distributions and their production. USP1999085935897.
  58. Soled Stuart L. ; Miseo Sabato ; Krycak Roman ; Vroman Hilda ; Ho Teh C. ; Riley Kenneth L.. Nickel molybdotungstate hydrotreating catalysts. USP2000126156695.
  59. Soled Stuart L ; Miseo Sabato ; Krycak Roman ; Vroman Hilda ; Ho Teh C. ; Riley Kenneth L.. Nickel molybodtungstate hydrotreating catalysts (law444). USP2001106299760.
  60. H?lzle, Markus; Sprague, Michael Jolyon; Harth, Klaus; P?pel, Wolfgang J?rgen. Preparation of catalysts having low volume shrinkage. USP2005076919066.
  61. Marcantonio,Paul J.. Process for metals recovery from spent catalyst. USP2009027485267.
  62. de Boer Mark,NLX. Process for preparing a large pore hydroprocessing catalyst. USP2000026030915.
  63. Eijsbouts, Sonja; Oogjen, Bob Gerardus; Homan Free, Harmannus Willem; Cerfontain, Marinus Bruce; Riley, Kenneth Lloyd; Soled, Stuart Leon; Miseo, Sabato. Process for preparing a mixed metal catalyst composition. USP2003116652738.
  64. Eijsbouts, Sonja; Oogjen, Bob Gerardus; Homan Free, Harmannus Willem; Cerfontain, Marinus Bruce; Riley, Kenneth Lloyd; Soled, Stuart Leon; Miseo, Sabato. Process for preparing a mixed metal catalyst composition. USP2003036534437.
  65. Plantenga, Frans Lodewijk; Eijsbouts, Sonja; Cerfontain, Marinus Bruce. Process for preparing an additive-based mixed metal catalyst, its composition and use. USP2003056566296.
  66. Erpenbach, Heinz; Gehrmann, Klaus; Lork, Winfried; Prinz, Peter. Process for purifying and recovering contaminated catalyst solution obtained in the carbonylation of methyl acetate and/or dimethylether. USP1985124556644.
  67. Bhaduri, Rahul S.. Process for recovering base metals from spent hydroprocessing catalyst. USP2010027658895.
  68. Oogjen, Bob Gerardus; Homan Free, Harmannus Willem; Sitters, Johannes Cornelis. Process for recovering group VIB metals from a catalyst. USP2011118057763.
  69. Erpenbach, Heinz; Gehrmann, Klaus; Lork, Winfried; Prinz, Peter. Process for recovering noble metals belonging to group VIII of the Periodic System of the elements from a contaminated catalyst solution originating from the carbonylation of methyl acetate and/or di. USP1985124557760.
  70. Gimzeski Edmund (London GB2). Process for recovering platinum group metals. USP1990044913736.
  71. Abulnaga, Baha E.; Guitian, Jose; Lindsay, Sara Ouzts. Process for recovering ultrafine solids from a hydrocarbon liquid. USP2010037674369.
  72. Jasra,Raksh Vir; Ghosh,Pushpito Kumar; Bajaj,Hari Chand; Boricha,Arvindkumar Balvantrai. Process for recovery of palladium from spent catalyst. USP2009017473406.
  73. Rao,Madhukar Bhaskara. Process for recovery, purification, and recycle of argon. USP2008047361316.
  74. Gibson,Philip Edward; Parker,Kenny Randolph; Jenkins, Jr.,Howard Wood. Process for removal of impurities from an oxidizer purge stream. USP2007097273559.
  75. Parker,Kenny Randolph; Lin,Robert. Process for removal of impurities from mother liquor in the synthesis of carboxylic acid using pressure filtration. USP2007107282151.
  76. Bhaduri, Rahul S.; Stiksma, John; Berezowsky, Roman. Process for separating and recovering base metals from used hydroprocessing catalyst. USP2010117837960.
  77. Bhaduri, Rahul S.; Stiksma, John; Berezowsky, Roman. Process for separating and recovering base metals from used hydroprocessing catalyst. USP2010127846404.
  78. Plantenga, Frans Lodewijk; Eijsbouts, Sonja; Cerfontain, Marinus Bruce. Process for the hydroprocessing of hydrocarbon feedstocks. USP2005036860987.
  79. Dogterom,Ronald Jan; Grotenbreg,Robert Adrianus Wilhelmus; Niesen,Gerardus Petrus Lambertus. Process for the production of hydrocarbons. USP2009037507770.
  80. Bnger Heinrich (Siegburg DEX) Cordes Rudolf (Niederkassel DEX) Hoffmann Gerhard (Niederkassel DEX). Process for the recovery and reuse of heavy metal oxidation catalyst from residues in the Witten DMT process. USP1984084464477.
  81. Kanel, Jeffrey Scott; Okrasinski, Stanley John. Process for the recovery of phosphorus and iodine containing catalyst components. USP2009067541499.
  82. Day Joseph G. (Holmer Green GB2). Process for the recovery of platinum group metals from refractory ceramic substrates. USP1984014428768.
  83. Riley,Kenneth L.; Soled,Stuart L.; Miseo,Sabato; Plantenga,Frans L.; Cerfontain,Marinus Bruce; Eijsbouts,Sonja; Brevoord,Eelko. Process for upgrading naphtha. USP2007067229548.
  84. Bhattacharyya, Alakananda; Mezza, Beckay J.. Process for using catalyst with rapid formation of iron sulfide in slurry hydrocracking. USP2011098025793.
  85. Hoboy, Loren P.; Wolf, Nick A.; Yoder, Tonya F.. Process to selectively recover metals from waste dusts, sludges and ores. USP2004086770249.
  86. Singhal Gopal H. (Houston TX) Nadkarni Ramachandra A. (Baytown TX). Recovery of catalyst from coal liquefaction residues. USP1984024434043.
  87. Imai Tamotsu (Mt. Prospect IL). Recovery of catalysts. USP1981114298499.
  88. Francis James N. (Houston TX) Veluswamy Lavanga R. (Houston TX). Recovery of coal liquefaction catalysts. USP1983114417972.
  89. Tilley George L. (Costa Mesa CA). Recovery of metal values from spent catalysts. USP1988014721606.
  90. Scaia, Mark D.; Eaton, David R.; Hoekstra, Roger J.; Haupfear, Eric A.. Recovery of noble metals from aqueous process streams. USP2010037687663.
  91. Stephenson David J. (Kempston GB2). Recovery of precious metal. USP1985044511539.
  92. Jean-Pierre Cuif FR. Recovery of precious metal and other values from spent compositions/materials. USP2002096455018.
  93. Farone, William A.; Azad, Maryam H.. Recovery of precious metals from low concentration sources. USP2003046551378.
  94. Rizkalla, Nabil; Rokicki, Andrzej. Recovery of rhenium. USP2010077763096.
  95. Hyatt David E. (Northglenn CO). Recovery or arsenic and antimony from spent antimony catalyst. USP1988024722774.
  96. Mayer Francis X. (Baton Rouge LA) Lewis William E. (Baton Rouge LA). Slurry hydroconversion process. USP1988014719002.
  97. Chakrabarty Tapantosh,CAX ; Mainak Ghosh,CAX. Slurry hydroprocessing. USP1999085935418.
  98. Hou, Zhiguo; Bearden, Jr., Roby; David, Ferrughelli Thomas; Miseo, Sabato; Gorbaty, Martin Leo; Soled, Stuart Leon. Slurry hydroprocessing using bulk multimetallic catalysts. USP2004036712955.
  99. Winter ; Jr. William E. (Baton Rouge LA) Sawyer Willard H. (Dallas TX). Slurry hydrotreating process. USP1991085037532.
  100. Howsmon Gregg J. ; Wittenbrink Robert J. ; Culross Claude C. ; Burns Louis F.. Small catalyst particle addition to slurry reactor. USP1999115977192.
  101. Ebel Robert Henry (Riverside CT) Lento ; Jr. Louis Leonard (Upper Saddle River NJ). Stable alumina catalyst support, process therefor, and promoted support. USP1977014003851.
  102. Farshid, Darush; Reynolds, Bruce. Systems and methods for producing a crude product. USP2011057943036.
  103. Powers, Christopher Alan; Reynolds, Bruce. Systems and methods for producing a crude product. USP2011118048292.
  104. Halbert Thomas R. (Annandale NJ) Chianelli Russell R. (Somerville NJ) Stiefel Edward I. (Bridgewater NJ) Jacobson Allan J. (Princeton NJ). Transition metal tris-dithiolene and related complexes as precursors to active catalysts. USP1991065026473.
  105. Schoenthal Galeon W. (Houston TX) Slaugh Lynn H. (Cypress TX). Wide pore alumina supports. USP1986044579728.
  106. Moyes,John; Houllis,Frank. Zinc recovery process. USP2008127465334.