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The present invention provides curable compositions that are substantially free of metal catalysts including both tin and non-tin metal catalysts. The curable compositions employ a catalyst composition comprising the combination of a (i) carbodiimide functional compound, and (ii) an amino-containing

The present invention provides curable compositions that are substantially free of metal catalysts including both tin and non-tin metal catalysts. The curable compositions employ a catalyst composition comprising the combination of a (i) carbodiimide functional compound, and (ii) an amino-containing compound such as an amino silane functional compound and/or an organic amine compound. The combination of these materials, particularly when aged, accelerates the condensation curing of moisture curable silicones/non-silicones even in the absence of a metal-based catalyst.

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1. A composition for forming a cured polymer composition comprising: (A) a polymer having at least a reactive silyl group;(B) a crosslinker or chain extender chosen from an alkoxysilane, an alkoxysiloxane, an oximosilane, an oximosiloxane, an enoxysilane, an enoxysiloxane, an aminosilane, a carboxys

1. A composition for forming a cured polymer composition comprising: (A) a polymer having at least a reactive silyl group;(B) a crosslinker or chain extender chosen from an alkoxysilane, an alkoxysiloxane, an oximosilane, an oximosiloxane, an enoxysilane, an enoxysiloxane, an aminosilane, a carboxysilane, a carboxysiloxane, an alkylamidosilane, an alkylamidosiloxane, an arylamidosilane, an arylamidosiloxane, an alkoxyaminosilane, an alkarylaminosiloxane, an alkoxycarbamatosilane, an alkoxycarbamatosiloxane, and combinations of two or more thereof; and(C) a catalyst composition comprising (i) a carbodiimide functional compound, and (ii) an amino silane functional compound, an organic amine, or a combination thereof wherein the catalyst composition is aged for at least one hour prior to addition to the curable composition. 2. The composition of claim 1, wherein the carbodiimide functional compound is chosen from a monocarbodiimide, a polycarbodiimide, a silica grafted carbodiimide, a silylated carbodiimide, or a combination of two or more thereof. 3. The composition of claim 1, wherein the carbodiimide functional compound is chosen from a compound of the formula: R6—(N═C═N)—R7 wherein R6 and R7 are the same or different and can be chosen from a hydrogen, hydrocarbyl group, a nitrogen-containing hydrocarbyl group, an oxygen-containing hydrocarbyl group, and a silicon-containing hydrocarbyl group. 4. The composition of claim 3, wherein R6 and R7 are independently a C1-C12 aliphatic group, C6-C-18 aromatic group, or an aromatic-aliphatic group. 5. The composition of claim 1, wherein the amino silane functional compound (ii) is chosen from N-(2-aminoethyl)aminopropyltrimethoxysilane gamma-aminopropyltriethoxysilane, gamma-aminopropyltrimethoxysilane, bis(gamma-trimethoxysilylpropyl)amine, N-phenyl-gamma-aminopropyltrimethoxysilane, triaminofunctionaltrimethoxysilane, gamma-aminopropylmethyldimethoxysilane, gamma-aminopropylmethyldiethoxysilane, omega-bis-(aminoalkyl-diethoxysilyl)-polydimethylsiloxanes (Pn=1-7), alpha, omega-bis-(aminoalkyl-diethoxysilyl)-octa-methyltetrasiloxane, 4-amino-3,3,-dimethyl-butyl-tri-methoxysilane, and N-ethyl-3-tri-methoxy-silyl-2-methylpropanamine, 3-(diethyl-aminopropyl)-trimethoxysilane or a combination of two or more thereof. 6. The composition of claim 1, wherein the organic amine is chosen from a compound of the formula R8—NR9R10, wherein R8, R9, and R10 are the same or different and can be chosen from a hydrogen, a hydrocarbyl group, a nitrogen-containing hydrocarbyl group, an oxygen-containing hydrocarbyl group, or a combination of two or more thereof. 7. The composition of claim 6, wherein R8, R9, and R10 are independently chosen from a C1-C12 aliphatic group, a C6-C18 aromatic group, or an aromatic aliphatic group. 8. The composition of claim 1, wherein the catalyst composition (C) comprises the carbodiimide functional compound in an amount of from about 25 weight percent to about 90 weight percent, and the amino silane functional compound and/or the organic amine in an amount of from about 75 weight percent to about 10 weight percent. 9. The composition of claim 1, wherein the catalyst composition (C) comprises the carbodiimide functional compound in an amount of from about 60 weight percent to about 75 weight percent, and the amino silane functional compound and/or the organic amine in an amount of from about 25 weight percent to about 40 weight percent. 10. The composition of claim 1 comprising from about 0.005 to about 7 wt. % of the catalyst composition (C) per 100 wt. % of component (A). 11. The composition of claim 1 comprising from about 0.1 to about wt. % of the carbodiimide functional compound (C)(i) per 100 wt. % of component (A). 12. The composition of claim 1 comprising from about 0.1 to about 5 wt. % of the amino silane functional compound and/or the organic amine (C)(ii) per 100 wt. % of component (A). 13. The composition of claim 1 further comprising from about 0.1 to about 5 wt. % of an amino-containing adhesion promoter (D) per 100 wt. % of component (A). 14. The composition of claim 1, wherein the catalyst composition (C) is aged for at least two hours prior to addition to the curable composition. 15. The composition of claim 1, wherein the catalyst composition (C) is aged for at least three hours prior to addition to the curable composition. 16. The composition of claim 1, wherein the catalyst composition (C) is aged for at least seven hours prior to addition to the curable composition. 17. The composition of claim 1, wherein the catalyst composition (C) is aged for at least 24 hours prior to addition to the curable composition. 18. The composition of claim 1, wherein the catalyst composition (C) is aged for at least 1 to 48 hours prior to addition to the curable composition. 19. The composition of claim 1, comprising from about 0.1 to about 5 wt. % of amino-functional siloxane component (E) per 100 wt. % of component (A). 20. The composition of claim 1, wherein the polymer (A) has the formula (2) [R1aR23-aSi—Z—]n—X—Z—SiR1aR23-a  (2) where X is chosen from a polyurethane; a polyester; a polyether; a polycarbonate; a polyolefin; a polypropylene; a polyesterether; and a polyorganosiloxane having units of R3SiO1/2, R2SiO, RSiO3/2, and/or SiO4/2, n is 1 to 100,a is 0 to 2,R and R1 can be identical or different at the same Si-atom and chosen from a C1-C10-alkyl; a C1-C10 alkyl substituted with one or more of Cl, F, N, O or S; a phenyl; a C7-C16 alkylaryl; a C7-C16 arylalkyl; a C2-C4 polyalkylene ether; or a combination of two or more thereof,R2 is chosen from OH, a C1-C8-alkoxy, a C2-C18-alkoxyalkyl, an oximoalkyl, an enoxyalkyl, an aminoalkyl, a carboxyalkyl, an amidoalkyl, an amidoaryl, a carbamatoalkyl, or a combination of two or more thereof, andZ is a bond, a divalent unit selected from the group of a C1-C8 alkylene, or O. 21. The composition of claim 1 wherein the cross-linker component (B) is chosen from tetraethylorthosilicate (TEOS); a polycondensate of TEOS; methyltrimethoxysilane (MTMS); vinyl-trimethoxysilane; methylvinyldimethoxysilane; dimethyldiethoxysilane; vinyltriethoxysilane; tetra-n-propylorthosilicate; vinyltris(methylethylketoxime)silane; methyltris(methylethylketoxime)silane; trisacetamidomethylsilane; bisacetamidodimethylsilane; tris(N-methyl-acetamido)methylsilane; bis(N-methylacetamido)dimethylsilane; (N-methyl-acetamido)methyldialkoxysilane; trisbenzamidomethylsilane; trispropenoxymethylsilane; alkyldialkoxyamidosilanes; alkylalkoxybisamidosilanes; (CH3Si(OC2H5)(NCH3COC6H5)2; CH3Si(OC2H5)—(NHCOC6H5)2; methyldimethoxy(ethylmethylketoximo)silane; methylmethoxybis-(ethylmethylketoximo)silane; methyldimethoxy(acetaldoximo)silane; methyldimethoxy(N-methylcarbamato)silane; ethyldimethoxy(N-methylcarbamato)silane; methyldimethoxyisopropenoxysilane; trimethoxyisopropenoxysilane; methyltri-iso-propenoxysilane; methyldimethoxy(but-2-ene-2-oxy)silane; methyldimethoxy(1-phenylethenoxy)silane; methyldimethoxy-2(1-carboethoxypropenoxy)silane; methylmethoxydi-N-methylaminosilane; vinyldimethoxymethylaminosilane; tetra-N,N-diethylaminosilane; methyldimethoxymethylaminosilane; methyltricyclohexylaminosilane; methyldimethoxyethylaminosilane; dimethyldi-N,N-dimethylaminosilane; methyldimethoxyisopropylaminosilane dimethyldi-N,N-diethylaminosilane, ethyldimethoxy(N-ethylpropionamido)silane; methyldimethoxy(N-methylacetamido)silane; methyltris(N-methylacetamido)silane; ethyldimethoxy(N-methylacetamido)silane; methyltris(N-methylbenzamido)silane; methylmethoxybis(N-methylacetamido)silane; methyldimethoxy(caprolactamo)silane; trimethoxy(N-methylacetamido)silane; methyldimethoxyethylacetimidatosilane; methyldimethoxypropylacetimidatosilane; methyldimethoxy(N,N′,N′-trimethylureido)silane; methyldimethoxy(N-allyl-N′,N′-dimethylureido)silane; methyldimethoxy(N-phenyl-N′,N′-dimethylureido)silane; methyldimethoxyisocyanatosilane; dimethoxydii socyanatosilane; methyldimethoxythioisocyanatosilane; methylmethoxydithioisocyanatosilane, or a combination of two or more thereof. 22. The composition of claim 1, comprising about 1 to about 10 wt. % of the crosslinker component (B) based on 100 wt. % of the polymer component (A). 23. The composition of claim 1, wherein the cross-linker component (B) is chosen from a silane or a siloxane, the silane or siloxane having two or more reactive groups that can undergo hydrolysis and/or condensation reaction with polymer (A) or on its own in the presence of water and a filler component (F). 24. The composition of claim 1, wherein the polymer component (A) is chosen from a polyorganosiloxane comprising divalent units of the formula [R2SiO] in the backbone, wherein R is chosen from a C1-C10-alkyl; a C1-C10 alkyl substituted with one or more of Cl, F, N, O or S; a phenyl; a C7-C16 alkylaryl; a C7-C16 arylalkyl; a C2-C4 polyalkylene ether; or a combination of two or more thereof. 25. The composition of claim 24, wherein the polymer component (A) has the formula (3): R23-aR1aSi—Z—[R2SiO]x[R12SiO]y—Z—SiR1aR23-a  (3) whereby x is 0 to 10000;y is 0 to 1000;a is 0 to 2;R is methyl;R1 is chosen from a C1-C10-alkyl; a C1-C10 alkyl substituted with one or more of Cl, F, N, O or S; a phenyl; a C7-C16 alkylaryl; a C7-C16 arylalkyl; a C2-C4 polyalkylene ether; or a combination of two or more thereof;R2 is chosen from OH, a C1-C8-alkoxy, a C2-C18-alkoxyalkyl, an oximoalkyl, an enoxyalkyl, an aminoalkyl, a carboxyalkyl, an amidoalkyl, an amidoaryl, a carbamatoalkyl, or a combination of two or more thereof, andZ is —O—, a bond, or —C2H4—. 26. The composition of claim 1, wherein the composition is provided as a one part composition. 27. The composition of claim 1, wherein the composition is provided as a two part composition comprising a first portion (P1) and a second portion (P2). 28. A method of providing a cured material comprising combining the first portion and the second portion of claim 27 and curing the mixture. 29. The composition of claim 1 comprising: 100 wt. % of component (A),0.1 to about 10 wt. % of at least one crosslinker (B),0.01 to about 7 wt. % of the catalyst composition (C),0 to about 5 wt. % of an amino-functional siloxane (E),0 to about 300 wt. % of a filler component (F),0.01 to about 8 wt. % of an auxiliary component (G), wherein the auxiliary component is chosen from a plastizer, a pigment, a stabilizer, an anti-microbial, a fungicide, a biocide, a solvent, or a combination of two or more thereof,whereby this composition can be stored in the absence of humidity and is curable in the presence of humidity upon exposure to ambient air. 30. The cured polymer material of claim 29 in the form of an elastomeric or duromeric seal, an adhesive, a coating, an encapsulant, a shaped article, a mold, and an impression material. 31. A method of providing a cured material comprising exposing the composition of claim 1 to ambient air. 32. A cured polymer material formed from the composition of claim 1. 33. A method of forming a cured composition comprising: adding a catalyst composition to (a) a polymer having at least a reactive silyl group; and(b) a cross-linker or chain extender chosen from an alkoxysilane, an alkoxysiloxane, an oximosilane, an oximosiloxane, an enoxysilane, an enoxysiloxane, an aminosilane, a carboxysilane, a carboxysiloxane, an alkylamidosilane, an alkylamidosiloxane, an arylamidosilane, an arylamidosiloxane, an alkoxyaminosilane, an alkarylaminosiloxane, an alkoxycarbamatosilane, an alkoxycarbamatosiloxane, and combinations of two or more thereof; wherein the catalyst composition comprises (i) a carbodiimide functional compound, and (ii) an amino silane functional compound, wherein the catalyst composition is aged for at least one hour prior to addition to the curable composition. 34. The method of claim 33, wherein the catalyst has been aged from about 2 hours to about 48 hours.