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A process for separating a carbon dioxide from a gas stream is disclosed. The process can include passing the gas stream over a sorbent that adsorbs the carbon dioxide by concentration swing adsorption and adsorptive displacement. The sorbent can be regenerated and the carbon dioxide recaptured by d

A process for separating a carbon dioxide from a gas stream is disclosed. The process can include passing the gas stream over a sorbent that adsorbs the carbon dioxide by concentration swing adsorption and adsorptive displacement. The sorbent can be regenerated and the carbon dioxide recaptured by desorbing the carbon dioxide from the sorbent using concentration swing adsorption and desorptive displacement. A carbon dioxide separation system is also disclosed. Neither the system nor the process rely on temperature swing or pressure swing adsorption.

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1. A process for separating CO2 from a gas stream, comprising a) passing a gas stream comprising CO2 over a sorbent to adsorb the CO2 to the sorbent,b) recovering the CO2 by desorbing the CO2 from the sorbent,wherein the process does not include pressure swing adsorption or temperature swing adsorpt

1. A process for separating CO2 from a gas stream, comprising a) passing a gas stream comprising CO2 over a sorbent to adsorb the CO2 to the sorbent,b) recovering the CO2 by desorbing the CO2 from the sorbent,wherein the process does not include pressure swing adsorption or temperature swing adsorption,wherein step b) includes desorption of the CO2 from the sorbent by a combination of concentration swing desorption and desorptive displacement, the concentration swing desorption comprising partial pressure purge desorption and the desorptive displacement comprising a process wherein an adsorbed CO2 molecule is displaced from the sorbent by steam during the desorption step. 2. The process of claim 1, wherein step a) includes adsorption of CO2 by concentration swing adsorption and adsorptive displacement. 3. The process of claim 1, wherein steps a) and b) are conducted at a constant pressure. 4. The process of claim 1, wherein steps a) and b) are conducted at approximately isothermal conditions. 5. The process of claim 1, wherein the temperature of the sorbent decreases during step a) by no more than about 20° C. 6. The process of claim 1, wherein the temperature of the sorbent increases during step b) by no more than about 20° C. 7. The process of claim 1, wherein the sorbent comprises an alkalized substrate. 8. The process of claim 1, wherein the sorbent comprises an alkalized alumina. 9. A sorbent based CO2 adsorption process, comprising the steps of a) preparing a sorbent comprising an alkalized substrate,b) passing a gas stream containing CO2 across the sorbent to adsorb the CO2 onto the alkalized substrate,c) recovering the CO2 from the sorbent by passing steam across the alkalized substrate to displace the carbon dioxide adsorbed on the alkalized substrate with water. 10. The process of claim 9, wherein the process does not include pressure swing adsorption or temperature swing adsorption. 11. The process of claim 9, wherein step b) comprises adsorption of CO2 by concentration swing adsorption and adsorptive displacement. 12. The process of claim 9, wherein step c) comprises recovering the CO2 by a combination of concentration swing desorption and desorptive displacement. 13. The process of claim 9, wherein the alkalized substrate comprises a substrate and at least one alkali or alkaline earth component. 14. The process of claim 9, wherein the alkalized substrate comprises an alumina component and at least one alkali or alkaline earth component. 15. The process of claim 9, wherein the alkalized substrate consists essentially of an alumina component and at least one alkali or alkaline earth component. 16. The process of claim 9, wherein the temperature of the sorbent decreases during step b) by no more than about 20° C. 17. The process of claim 9, wherein the temperature of the sorbent increases during step c) by no more than about 20° C. 18. A CO2 separation system, comprising: a CO2 feed stream;a CO2 adsorption zone;a CO2 desorption zone;one or more CO2 sorbent beds,wherein the one or more sorbent beds alternates between the CO2 adsorption zone and the CO2 desorption zone, and wherein the one or more sorbent beds adsorbs CO2 from the CO2 feed stream in the adsorption zone and desorbs CO2 in the desorption zone;wherein the CO2 separation system does not include a pressure swing or a temperature swing adsorption, andwherein the desorption zone operates as a concentration swing and a desorptive displacement, the concentration swing comprising partial pressure purge desorption and the desorptive displacement comprising a process wherein an adsorbed CO2 molecule is displaced from the sorbent by steam during the desorption step. 19. The system of claim 18, further comprising an inlet and an outlet for the adsorption zone where the CO2 feed stream enters the adsorption zone via the inlet and a purified gas stream exits the adsorption zone via the outlet. 20. The system of claim 18, further comprising an inlet and an outlet for the desorption zone, wherein a stream comprising steam enters the desorption zone via the inlet and a CO2 enriched stream exits via the outlet. 21. The system of claim 18, further comprising a purge zone after the desorption zone, wherein the one or more sorbent beds enters the purge stage and is purged via a stripping gas stream. 22. The system of claim 18, wherein the one or more sorbent beds comprises a sorbent, and the sorbent comprises a substrate and at least one alkali or alkaline earth component. 23. The system of claim 18, wherein the one or more sorbent beds comprises a sorbent, and the sorbent comprises an alumina component and at least one alkali or alkaline earth component. 24. The system of claim 18, wherein the adsorption zone operates as a concentration swing and adsorptive displacement. 25. The system of claim 18, wherein the adsorption zone has an adsorption inlet and an adsorption outlet, the desorption zone has a desorption inlet and a desorption outlet, and the adsorption inlet and adsorption outlet are in opposing positions from the desorption inlet and the desorption outlet, relative to the one or more sorbent beds. 26. The system of claim 18, wherein the one or more sorbent beds comprises at least two sorbent beds, and the at least two sorbent beds rotate through each of the adsorption and desorption zones. 27. The system of claim 18, wherein the one or more sorbent beds comprises a plurality of sorbent beds rotating in series through the adsorption zone, desorption zone, and optionally though a purge stage after the desorption zone. 28. A method for purifying a CO2 gas stream to increase the concentration of the CO2 in a product stream, comprising the steps of a) preparing a sorbent bed having an inlet and an outlet,b) passing a gas stream containing CO2 across the sorbent bed to adsorb the CO2 to the sorbent, andc) recovering a CO2-enriched stream by passing steam across the CO2 containing sorbent,wherein the method does not include a pressure swing adsorption or temperature swing adsorption process, andwherein the CO2 is recovered by a combination of concentration swing desorption and desorptive displacement, the concentration swing desorption comprising partial pressure purge desorption and the desorptive displacement comprising a process wherein an adsorbed CO2 molecule is displaced from the sorbent by steam during the desorption step. 29. The method of claim 28, wherein the CO2 is adsorbed in step b) by a concentration swing adsorption and adsorptive displacement. 30. The method of claim 28, wherein greater than 80% by volume of the CO2 has been recovered in the CO2-enriched stream. 31. The method of claim 28, wherein greater than 85% by volume of the CO2 has been recovered in the CO2-enriched stream. 32. The method of claim 28, wherein greater than 90% by volume of the CO2 has been recovered in the CO2-enriched stream. 33. A method for removing CO2 to purify a gas stream, comprising the steps of a) preparing a sorbent bed having an inlet and an outlet,b) passing a gas stream containing CO2 across the sorbent bed from inlet to outlet to adsorb the CO2 to the sorbent,c) recovering the purified gas stream depleted of CO2 at the outlet, andd) regenerating the sorbent bed by passing steam across the CO2 containing sorbent,wherein the method does not include a pressure swing adsorption or temperature swing adsorption process, andwherein the sorbent bed is regenerated by a combination of concentration swing desorption and desorptive displacement, the concentration swing desorption comprising partial pressure purge desorption and the desorptive displacement comprising a process wherein an adsorbed CO2 molecule is displaced from the sorbent by steam during the desorption step. 34. The method of claim 33, wherein the CO2 is adsorbed in step b) by a concentration swing adsorption and adsorptive displacement. 35. The method of claim 33, wherein the amount of CO2 in the purified gas stream has been reduced by at least 80% by volume. 36. The method of claim 33, wherein the amount of CO2 in the purified gas stream has been reduced by at least 85% by volume. 37. The method of claim 33, wherein the amount of CO2 in the purified gas stream has been reduced by at least 90% by volume.