An exhaust gas purification catalyst apparatus, which is superior in oxidation performance of, in particular, nitrogen monoxide, among hydrocarbons, carbon monoxide, nitrogen oxides and particulate components such as soot, included in exhaust gas from a lean burn engine, and combustion performance o
An exhaust gas purification catalyst apparatus, which is superior in oxidation performance of, in particular, nitrogen monoxide, among hydrocarbons, carbon monoxide, nitrogen oxides and particulate components such as soot, included in exhaust gas from a lean burn engine, and combustion performance of light oil. The exhaust gas purification apparatus arranged with an oxidation catalyst (DOC) comprising a noble metal component for oxidizing carbon monoxide, hydrocarbons, in particular, nitrogen monoxide among nitrogen oxides, and for combusting light oil, a catalyzed soot filter (CSF) including a noble metal component for collecting a particulate component such as soot and removing by combustion (oxidation). The oxidation catalyst (DOC) has a catalyst layer where platinum (Pt), palladium (Pd) and barium oxide (BaO) are supported on alumina (Al2O3) having a pore size of 12 to 120 nm, and ratio of platinum and palladium is 1:1 to 11:2 in weight equivalent.
대표청구항▼
1. An exhaust gas purification apparatus, comprising: a first oxidation catalyst (DOC) comprising a noble metal component for oxidizing, in particular, nitrogen monoxide, among carbon monoxide, hydrocarbons, nitrogen oxides, and for combusting light oil,a catalyzed soot filter (CSF) comprising a nob
1. An exhaust gas purification apparatus, comprising: a first oxidation catalyst (DOC) comprising a noble metal component for oxidizing, in particular, nitrogen monoxide, among carbon monoxide, hydrocarbons, nitrogen oxides, and for combusting light oil,a catalyzed soot filter (CSF) comprising a noble metal component for collecting a particulate component such as soot and removing by combustion (oxidation),a second oxidation catalyst (DOC),a reducing agent spraying means for supplying a reducing agent selected from a urea component or an ammonia component, anda selective reduction catalyst (SCR) for removing by reduction of nitrogen oxides by contacting with the reducing agent,wherein the first oxidation catalyst (DOC), the catalyzed soot filter (CSF), the second oxidation catalyst (DOC), the reducing agent spraying means, and the selective reduction catalyst (SCR) are arranged in this order from the upstream side of an exhaust gas passage, in order to purify carbon monoxide, hydrocarbons, nitrogen oxides, and particulate components such as soot, in exhaust gas discharged from a diesel engine,the first oxidation catalyst (DOC) and the second oxidation catalyst (DOC) have a catalyst layer where platinum (Pt) and palladium (Pd) are supported on alumina (Al2O3) having a pore size of 12 to 120 nm, and ratio of platinum and palladium is 1:1 to 11:2 in weight equivalent, andthe catalyzed combustion filter (CSF) has a catalyst layer, where platinum (Pt) and palladium (Pd) are supported on alumina having a pore size of 12 to 120 nm, or a mixture of two or more kinds of alumina having different pore size within its range, and ratio of platinum and palladium is 1:1 to 11:4 in weight equivalent. 2. The exhaust gas purification apparatus according to claim 1, wherein the catalyst layer is coated onto an integral structure-type substrate, in one or more layers. 3. The exhaust gas purification apparatus according to claim 1, wherein the catalyst layer has a base layer composed of alumina, at the lower layer thereof. 4. The exhaust gas purification apparatus according to claim 1, wherein the alumina having the pore size of 12 to 120 nm is a mixture of two or more kinds of alumina having different pore size. 5. The exhaust gas purification apparatus according to claim 1, wherein barium oxide is included in the first oxidation catalyst (DOC) is in an amount of 0.5 to 4.0 g/L. 6. The exhaust gas purification apparatus according to claim 1, wherein the first oxidation catalyst (DOC) or the second oxidation catalyst (DOC) includes a coated amount of the catalyst layer of 50 to 300 g/L. 7. The exhaust gas purification apparatus according to claim 1, wherein the first oxidation catalyst (DOC) or the second oxidation catalyst (DOC) includes a total supported amount of the noble metals of 0.5 to 4.0 g/L in metal equivalent per volume. 8. The exhaust gas purification apparatus according to claim 1, wherein the catalyzed soot filter (CSF) includes a coated amount of the catalyst layer of 4 to 100 g/L. 9. The exhaust gas purification apparatus according to claim 1, wherein the catalyzed soot filter (CSF) includes a total supported amount of the noble metals of 0.05 to 2.0 g/L in metal equivalent per volume. 10. The exhaust gas purification apparatus according to claim 1, further comprising an ammonia oxidation catalyst (AMOX) arranged after the selective reduction catalyst (SCR).
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이 특허에 인용된 특허 (3)
Zhicheng Hu ; Ronald M. Heck ; Rudolf M. Smaling ; Alan R. Amundsen, Engine exhaust treatment apparatus and method of use.
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