One embodiment is a pressure sensitive adhesive construct comprising: (a) a backing substrate; and(b) a pressure sensitive adhesive composition disposed on the backing substrate, wherein the pressure sensitive adhesive composition includes a product made from (i) at least one epoxidized vege
One embodiment is a pressure sensitive adhesive construct comprising: (a) a backing substrate; and(b) a pressure sensitive adhesive composition disposed on the backing substrate, wherein the pressure sensitive adhesive composition includes a product made from (i) at least one epoxidized vegetable oil and;(ii) a dimer acid or anhydride thereof, a trimer acid or anhydride thereof, a polymerized fatty acid or anhydride thereof, or a mixture thereof. A further embodiment is a pressure sensitive adhesive construct comprising: (A) a backing substrate; and(B) a pressure sensitive adhesive composition disposed on the backing substrate, wherein the pressure sensitive adhesive composition includes a product made from (i) at least one epoxidized vegetable oil and;(ii) a prepolymer or oligomer capped with a carboxylic acid group at both prepolymer or oligomer chain ends, or a branched prepolymer or oligomer with at least two of the prepolymer or oligomer branches and chain ends capped with a carboxylic acid group, wherein the carboxylic acid-capped prepolymer or oligomer is made from (a) a dibasic acid reacted with (b) a glycidyl or an epoxidized compound having at least two epoxy groups, a diol or polyol, a diamine, or a combination thereof.
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1. A pressure sensitive adhesive construct comprising: (A) a backing substrate; and(B) a pressure sensitive adhesive composition disposed on the backing substrate, wherein the pressure sensitive adhesive composition includes a product made from (i) at least one epoxidized vegetable oil and;(ii) a pr
1. A pressure sensitive adhesive construct comprising: (A) a backing substrate; and(B) a pressure sensitive adhesive composition disposed on the backing substrate, wherein the pressure sensitive adhesive composition includes a product made from (i) at least one epoxidized vegetable oil and;(ii) a prepolymer or oligomer capped with a carboxylic acid group at both prepolymer or oligomer chain ends, or a branched prepolymer or oligomer with at least two of the prepolymer or oligomer branches and chain ends capped with a carboxylic acid group, wherein the carboxylic acid-capped prepolymer or carboxylic acid-capped oligomer is made from (a) an excess of dibasic acid reacted with (b) a glycidyl or an epoxidized compound having at least two epoxy groups, or a combination thereof. 2. The construct of claim 1, wherein the epoxidized vegetable oil is epoxidized soybean oil. 3. The construct of claim 1, wherein the pressure sensitive adhesive composition includes at least about 50 weight percent of the product, based on the total weight of the pressure sensitive adhesive composition. 4. The construct of claim 1, wherein the pressure sensitive adhesive is disposed on the backing substrate at a coating level of 2 to 10 mg/cm2. 5. The construct of claim 1, wherein the dibasic acid comprises a dimer acid. 6. The construct of claim 5, wherein the dimer acid is a dimer of linoleic acid, oleic acid, or a mixture thereof. 7. The construct of claim 5, wherein the dimer acid is a dimer of an unsaturated fatty acid. 8. The construct of claim 1, wherein the dibasic acid comprises sebacic acid. 9. The construct of claim 1, wherein the dibasic acid is reacted with a diglycidyl ether. 10. The construct of claim 1, wherein the pressure sensitive adhesive composition comprises a polymer that is a reaction product of (i) and (ii). 11. The construct of claim 1, wherein the glycidyl or the epoxidized compound having at least two epoxy groups is selected from bisphenol A diglycidyl ether, bisphenol F diglycidyl ether, bisphenol A propoxylate diglycidyl ether, bisphenol A ethoxylate diglycidyl ether, diethylene glycol diglycidyl ether, 1,3-butanediol diglycidyl ether, 1,4-butanediol diglycidyl ether, poly(ethylene glycol) diglycidyl ether, poly(propylene glycol) diglycidyl ether, neopentyl glycol diglycidyl ether, glycerol diglycidyl ether, diglycidyl 1,2,3,6-tetrahydrophthalate, 1,2-cyclohexanedicarboxylate diglycidyl ether, 1,4-cyclohexanedimethanol diglycidyl ether, resorcinol diglycidyl ether, poly(dimethylsiloxane) terminated with diglycidyl ether, epoxidized linoleic acid ester, epoxidized vegetable oils with two epoxy functional groups, trimethylolpropane triglycidyl ether, trimethylolethane triglycidyl ether, N,N-Diglycidyl-4-glycidyloxyaniline, tris(4-hydroxyphenyl)methane triglycidyl ether, or tris(2,3-epoxypropyl) isocyanurate. 12. The construct of claim 1, wherein the prepolymer or oligomer includes repeating units having a structure of: wherein each of R1, R2, R3, R4, R5, R6, R7, and R8 independently represents hydrogen or a substituted or unsubstituted alkyl or heteroalkyl group. 13. The construct of claim 1, wherein (B)(ii)(b) is a glycidyl. 14. A pressure sensitive adhesive construct comprising: (I) a backing substrate; and(II) a pressure sensitive adhesive composition disposed on the backing substrate, wherein the pressure sensitive adhesive composition comprises a a reaction product made by reacting (A) an epoxidized vegetable oil with;(B) a component selected from: (i) a dimer acid or anhydride thereof, a trimer acid or anhydride thereof, or a mixture thereof;(ii) a prepolymer or oligomer capped with a carboxylic acid group at both prepolymer or oligomer chain ends, or a branched prepolymer or oligomer with at least two of the prepolymer or oligomer branches and chain ends capped with a carboxylic acid group, wherein the carboxylic acid-capped prepolymer or oligomer is made from a (a) an excess of a dibasic acid reacted with (b) a glycidyl or an epoxidized compound having at least two epoxy groups, or a combination thereof; or(iii) a combination of (i) and (ii). 15. The construct of claim 14, wherein component (B)(i) comprises a dimer acid. 16. The construct of claim 15, wherein the dimer acid is a dimer of linoleic acid, oleic acid, or a mixture thereof. 17. The construct of claim 15, wherein the dimer acid is a dimer of an unsaturated fatty acid. 18. The construct of claim 14, wherein the epoxidized vegetable oil is epoxidized soybean oil. 19. The construct of claim 14 wherein component (B) is a dimer acid. 20. The construct of claim 19, wherein the dimer acid is a dimer of an unsaturated fatty acid. 21. The construct of claim 14, wherein the glycidyl or the epoxidized compound having at least two epoxy groups is selected from bisphenol A diglycidyl ether, bisphenol F diglycidyl ether, bisphenol A propoxylate diglycidyl ether, bisphenol A ethoxylate diglycidyl ether, diethylene glycol diglycidyl ether, 1,3-butanediol diglycidyl ether, 1,4-butanediol diglycidyl ether, poly(ethylene glycol) diglycidyl ether, poly(propylene glycol) diglycidyl ether, neopentyl glycol diglycidyl ether, glycerol diglycidyl ether, diglycidyl 1,2,3,6-tetrahydrophthalate, 1,2-cyclohexanedicarboxylate diglycidyl ether, 1,4-cyclohexanedimethanol diglycidyl ether, resorcinol diglycidyl ether, poly(dimethylsiloxane) terminated with diglycidyl ether, epoxidized linoleic acid ester, epoxidized vegetable oils with two epoxy functional groups, trimethylolpropane triglycidyl ether, trimethylolethane triglycidyl ether, N,N-Diglycidyl-4-glycidyloxyaniline, tris(4-hydroxyphenyl)methane triglycidyl ether, or tris(2,3-epoxypropyl) isocyanurate. 22. The construct of claim 14, wherein the prepolymer or oligomer includes repeating units having a structure of: wherein each of R1, R2, R3, R4, R5, R6, R7, and R8 independently represents hydrogen or a substituted or unsubstituted alkyl or heteroalkyl group. 23. The construct of claim 14, wherein (B)(ii)(b) is a glycidyl. 24. A method for making a pressure sensitive adhesive construct comprising: reacting (i) at least one epoxidized vegetable oil with (ii) a prepolymer or oligomer capped with a carboxylic acid group at both prepolymer or oligomer chain ends, or a branched prepolymer or oligomer with at least two of the prepolymer or oligomer branches and chain ends capped with a carboxylic acid group, wherein the carboxylic acid-capped prepolymer or carboxylic acid-capped oligomer is made from (a) an excess of dibasic acid reacted with (b) a glycidyl or an epoxidized compound having at least two epoxy groups, or a combination thereof; andforming on a backing substrate a pressure sensitive adhesive from the resulting reaction product. 25. The method of claim 24, wherein the method comprises: initially reacting the epoxidized vegetable oil with component (ii) to produce a second prepolymer product;applying the second prepolymer product onto a backing substrate or a release liner; andfurther reacting the second prepolymer product to produce the pressure sensitive adhesive composition. 26. The method of claim 25, wherein initially reacting the epoxidized vegetable oil with component (ii) comprises heating a mixture of the epoxidized vegetable oil and component (ii) at a temperature of 30 to 300° C. 27. The method of claim 25, wherein the further reacting of the second prepolymer product comprises heating the prepolymer product disposed on the backing substrate at a temperature of 100 to 300° C. 28. The method of claim 25, wherein: the second prepolymer product is applied onto a release liner or a backing substrate;a backing substrate is placed onto a surface of the prepolymer coating opposing the release liner, or a release liner is placed on a surface of the prepolymer coating opposing the backing substrate, to form a release liner/second prepolymer product/backing substrate assembly;pressure is applied to the resulting assembly; andat least the second prepolymer product on the backing substrate or release liner is heated to produce the pressure sensitive adhesive composition. 29. The method of claim 24, wherein the epoxidized vegetable oil is initially reacted with at least one monobasic acid or anhydride resulting in a modified epoxidized vegetable oil; and the modified epoxidized vegetable oil is reacted with component (ii). 30. The method of claim 29, wherein the amount of monobasic acid or anhydride reacted with the epoxidized vegetable oil is sufficient to leave 1.5 to 6 of epoxy groups per one mole of the modified epoxidized vegetable oil. 31. The method of claim 24, wherein the amount of component (ii) reacted with the epoxidized vegetable oil is in a molar ratio of component (ii) carboxylic acid groups to epoxidized vegetable oil epoxy groups of from 3:1 to 1:3. 32. The method of claim 24, further comprising reacting the epoxidized vegetable oil with a monobasic acid or anhydride thereof to produce a modified epoxidized vegetable oil that is reacted with component (ii). 33. The method of claim 24, wherein the dibasic acid comprises a dimer acid. 34. The method of claim 33, wherein the dimer acid is a dimer of an unsaturated fatty acid. 35. The method of claim 24, wherein the dibasic acid comprises sebacic acid. 36. A method for making a pressure sensitive adhesive composition comprising: (a) reacting (i) a dibasic acid with (ii) at least one agent to provide a prepolymer or oligomer capped with a carboxylic acid group at both prepolymer or oligomer chain ends, or a branched prepolymer or oligomer with at least two of the prepolymer or oligomer branches and prepolymer or oligomer chain ends capped with a carboxylic acid group, wherein the at least one agent comprises a diglycidyl ether, an epoxidized compound having at least two epoxy groups, or a combination thereof; and(b) reacting at least one epoxidized vegetable oil with the carboxylic acid-capped prepolymer or carboxylic acid-capped oligomer to produce a pressure sensitive adhesive composition. 37. The method of claim 36, wherein the dibasic agent comprises a dimer acid, and the at least one agent comprises a diglycidyl ether. 38. The method of claim 36, wherein the dibasic agent comprises sebacic acid, and the at least one agent comprises a diglycidyl ether. 39. The method of claim 36, wherein the amount of carboxylic acid-capped prepolymer or carboxylic acid-capped oligomer reacted with the epoxidized vegetable oil is in a molar ratio of carboxyl groups to epoxy groups of 3:1 to 1:3. 40. The method of claim 36, wherein the dibasic acid is a dimer of an unsaturated fatty acid.
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이 특허에 인용된 특허 (9)
McLafferty John J. (Hicksville NY) Wang Sue L. (Flushing NY), 1-methyl imidazole catalyzed carboxyl terminated polyester.
Kimball ; deceased Michael E. (late of Westbrook ME by Edward A. Kimball ; legal representative), Epoxy adhesives and methods of using cured compositions therefrom.
Dhaler,Didier; Lievre,Andr?; Mirou,Christian; Guyot,Christophe, Heat-curable silicone adhesive complex whereof the interface has release force capable of being modulated.
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