Non-metal catalyzed room temperature moisture curable organopolysiloxane compositions
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
C08G-077/44
C08G-077/08
C08L-043/04
C08K-005/5419
C08K-005/544
C08L-101/10
출원번호
US-0890189
(2014-05-09)
등록번호
US-9605113
(2017-03-28)
국제출원번호
PCT/US2014/037486
(2014-05-09)
국제공개번호
WO2014/183029
(2014-11-13)
발명자
/ 주소
Patel, Mihirkumar Maheshbai
Dhanabalan, Anantharaman
Dinkar, Sumi
Sarkar, Alok
출원인 / 주소
MOMENTIVE PERFORMANCE MATERIALS INC.
대리인 / 주소
Waters, Joseph E.
인용정보
피인용 횟수 :
0인용 특허 :
70
초록▼
The present invention provides curable compositions that are free of metal catalysts including both tin and non-tin metal catalysts. The curable compositions employ a catalyst comprising curable polymers having reactive terminal silyl groups. In particular, a silylated carboxylic acid is an alternat
The present invention provides curable compositions that are free of metal catalysts including both tin and non-tin metal catalysts. The curable compositions employ a catalyst comprising curable polymers having reactive terminal silyl groups. In particular, a silylated carboxylic acid is an alternative to organotin or other metal catalysts. In addition, the catalyst may be used with an amino-containing adhesion promoter or a mixture of amine-containing adhesion promoters and an amino-containing siloxane. The combination of these materials accelerates the condensation curing of moisture curable silicones/non-silicones even in the absence of a metal-based catalyst.
대표청구항▼
1. A composition for forming a cured polymer composition comprising: (A) a polymer having at least a reactive silyl group;(B) a crosslinker or chain extender chosen from an alkoxysilane, an alkoxysiloxane, an oximosilane, an oximosiloxane, an enoxysilane, an enoxysiloxane, an aminosilane, a carboxys
1. A composition for forming a cured polymer composition comprising: (A) a polymer having at least a reactive silyl group;(B) a crosslinker or chain extender chosen from an alkoxysilane, an alkoxysiloxane, an oximosilane, an oximosiloxane, an enoxysilane, an enoxysiloxane, an aminosilane, a carboxysilane, a carboxysiloxane, an alkylamidosilane, an alkylamidosiloxane, an arylamidosilane, an arylamidosiloxane, an alkoxyaminosilane, an alkarylaminosiloxane, an alkoxycarbamatosilane, an alkoxycarbamatosiloxane, and combinations of two or more thereof;(C) a catalyst composition comprising a silylated carboxylic acid compound, wherein the silylated carboxylic acid is a silyl ester of a carboxylic acid comprising a silyl group bonded to a carboxylic acid compound;(D) an adhesion promoter;(E) optionally a cure accelerator; and(F) optionally a flow modifier or extender. 2. The composition of claim 1, wherein the carboxylic acid compound of the silylated carboxylic acid is chosen from an aliphatic carboxylic acid, an unsaturated carboxylic acid, or a combination of two or more thereof. 3. The composition of claim 1, wherein the carboxylic acid compound of the silylated carboxylic acid is chosen from a linear or branched C4-C30-alkyl carboxylic acid, or a combination of two or more such carboxylic acids. 4. The composition of claim 1, wherein the carboxylic acid compound is chosen from undecenoic acid, dodecenoic acid, tridecenoic acid, tetradecenoic acid, pentadecenoic acid, hexadecenoic acid, heptadecenoic acid, octadecenoic acid, nonadecenoic acid, eicosenoic acid, docosenoic acid, tetracosenoic acid, or a combination of two or more thereof. 5. The composition of claim 1, wherein the silyl group is an alkyl silyl group, an alkoxy silyl group, or a combination thereof. 6. The composition of claim 1, wherein the silyl group is a trialkyl silyl group comprising alkyl groups having 1 to 10 carbon atoms. 7. The composition of claim 1, wherein the catalyst composition comprises a trimethylsilyl ester of undecenoic acid. 8. The composition of claim 1, wherein the silylated carboxylic acid is of the formula: where R11 is CH3, an alkene, or a siloxane group of formula —((CH3)3Si—O)2—Si(CH3); R12, R13, and R11 are independently chosen from a C1-C10 alkyl, polysiloxane, an alkoxy group of the formula OR15, where R15 is a C1-C10 alkyl group; and t is 4-30. 9. The composition of claim 1, wherein the silylated carboxylic acid is of the formula: 10. The composition of claim 1 comprising from about 0.005 to about 7 pt. wt. of the catalyst composition (C) per 100 pt. wt. of component (A). 11. The composition of claim 1 comprising from about 0.1 to about 5 pt. wt. of the silylated carboxylic acid compound (C) per 100 pt. wt. of component (A). 12. The composition of claim 1, wherein the adhesion promoter (D) includes an amino silane functional compound and/or an organic amine. 13. The composition of claim 1, wherein the adhesion promoter (D) is chosen from an (aminoalkyl)trialkoxysilane, an (aminoalkyl)alkyldialkoxysilane, a bis(trialkoxysilylalkyl)amine, a tris(trialkoxysilylalkyl)amine, a tris(trialkoxysilylalkyl)cyanurate, and a tris(trialkoxysilylalkyl)isocyanurate, an (epoxyalkyl)alkyldialkoxysilane, an (epoxyalkyl)trialkoxysilane, an (epoxyalkylether)trialkoxysilane, or a combination of two or more thereof. 14. The composition of claim 1 further comprising from about 0.1 to about 5 pt. wt. of amino-containing adhesion promoter (D) per 100 pt. wt. of component (A). 15. The composition of claim 1 comprising from about 0.1 to about 5 pt. wt. of an amino-functional siloxane component (E) per 100 pt. wt. of component (A). 16. The polymer composition of claim 1, wherein the polymer (A) has the formula (2) [R1aR23-aSi—Z—]n—X—Z—SiR1aR23-a (2) where X is chosen from a polyurethane; a polyester; a polyether; a polycarbonate; a polyolefin; a polypropylene; a polyesterether; and a polyorganosiloxane having units of R3SiO1/2, R2SiO, RSiO3/2, and/or SiO4/2, n is 0 to 100,a is 0 to 2,R1 can be identical or different at the same Si-atom and chosen from a C1-C10-alkyl; a C1-C10 alkyl substituted with one or more of Cl, F, N, O or S; a phenyl; a C7-C16 alkylaryl; a C7-C16 arylalkyl; a C2-C4 polyalkylene ether; or a combination of two or more thereof,R2 is chosen from OH, a C1-C8-alkoxy, a C2-C18-alkoxyalkyl, an oximoalkyl, an enoxyalkyl, an aminoalkyl, a carboxyalkyl, an amidoalkyl, an amidoaryl, a carbamatoalkyl, or a combination of two or more thereof, andZ is a bond, a divalent unit selected from the group of a C1-C8 alkylene, or 0. 17. The composition of claim 1, wherein the cross-linker component (B) is chosen from a silane or a siloxane, the silane or siloxane having two or more reactive groups that can undergo hydrolysis and/or condensation reaction with polymer (A) or on its own in the presence of water and component (F). 18. The composition of claim 1 wherein the cross-linker component (B) is chosen from tetraethylorthosilicate (TEOS); a polycondensate of TEOS; methyltrimethoxysilane (MTMS); vinyl-trimethoxysilane; methylvinyldimethoxysilane; dimethyldiethoxysilane; vinyltriethoxysilane; tetra-n-propylorthosilicate; vinyltris(methylethylketoxime)silane; methyltris(methylethylketoxime)silane; trisacetamidomethylsilane; bisacetamidodimethylsilane; tris(N-methyl-acetamido)methyl silane; bis(N-methylacetamido)dimethylsilane; (N-methyl-acetamido)methyldialkoxysilane; trisbenzamidomethylsilane; trispropenoxymethylsilane; alkyldialkoxyamidosilanes; alkylalkoxybisamidosilanes; CH3Si(OC2H5)1-2(NHCOR)2-1; (CH3Si(OC2H5)(NCH3COC6H5)2; CH3Si(OC2H5)—(NHCOC6H5)2; methyldimethoxy(ethylmethylketoximo)silane; methylmethoxybis-(ethylmethylketoximo)silane; methyldimethoxy(acetaldoximo)silane; methyldimethoxy(N-methylcarbamato)silane; ethyldimethoxy(N-methylcarbamato)silane; methyldimethoxyisopropenoxysilane; trimethoxyisopropenoxysilane; methyltri-iso-propenoxysilane; methyldimethoxy(but-2-ene-2-oxy)silane; methyldimethoxy(1-phenylethenoxy)silane; methyldimethoxy-2(1-carboethoxypropenoxy)silane; methylmethoxydi-N-methylaminosilane; vinyldimethoxymethylaminosilane; tetra-N,N-diethylaminosilane; methyldimethoxymethylaminosilane; methyltricyclohexylaminosilane; methyldimethoxyethylaminosilane; dimethyldi-N,N-dimethylaminosilane; methyldimethoxyisopropylaminosilane dimethyldi-N,N-diethylaminosilane; ethyldimethoxy(N-ethylpropionamido)silane; methyldimethoxy(N-methylacetamido)silane; methyltris(N-methyl acetamido)silane; ethyldimethoxy(N-methylacetamido)silane; methyltris(N-methylbenzamido)silane; methylmethoxybis(N-methylacetamido)silane; methyldimethoxy(caprolactamo)silane; trimethoxy(N-methylacetamido)silane; methyldimethoxyethylacetimidatosilane; methyldimethoxypropylacetimidatosilane; methyldimethoxy(N,N′,N′-trimethylureido)silane; methyldimethoxy(N-allyl-N′,N′-dimethylureido)silane; methyldimethoxy(N-phenyl-N′,N′-dimethylureido)silane; methyldimethoxyisocyanatosilane; dimethoxydiisocyanatosilane; methyldimethoxythioisocyanatosilane; methylmethoxydithioisocyanatosilane, or a combination of two or more thereof. 19. The composition of claim 1, comprising about 0.1 to about 10 pt. wt. of the crosslinker component (B) based on 100 pt. wt. of the polymer component (A). 20. The composition of claim 1, wherein the polymer component (A) is chosen from a polyorganosiloxane comprising divalent units of the formula [R2SiO] in the backbone, wherein R is chosen from a C1-C10-alkyl; a C1-C10 alkyl substituted with one or more of Cl, F, N, O or S; a phenyl; a C7-C16 alkylaryl; a C7-C16 arylalkyl; a C2-C4 polyalkylene ether; or a combination of two or more thereof. 21. The polymer composition of claim 1, wherein the polymer component (A) has the formula (3): R23-aR1aSi—Z—[R2SiO]x[R12SiO]y—Z—SiR1aR23-a (3) whereby x is 0 to 10000;y is 0 to 1000;a is 0 to 2;R is methyl;R1 is chosen from a C1-C10-alkyl; a C1-C10 alkyl substituted with one or more of Cl, F, N, O or S; a phenyl; a C7-C16 alkylaryl; a C7-C16 arylalkyl; a C2-C4 polyalkylene ether; or a combination of two or more thereof, and other siloxane units may be present in amounts less than 10 mol. %;R2 is chosen from OH, a C1-C8-alkoxy, a C2-C18-alkoxyalkyl, an oximoalkyl, an enoxyalkyl, an aminoalkyl, a carboxyalkyl, an amidoalkyl, an amidoaryl, a carbamatoalkyl, or a combination of two or more thereof; andZ is —O—, a bond, or —C2H4—. 22. The composition of claim 1, wherein the composition is provided as a one part composition. 23. The composition of claim 1, wherein the composition is provided as a two part composition comprising a first portion (P1) and a second portion (P2). 24. A method of providing a cured material comprising combining the first portion and the second portion of claim 23 and curing the mixture. 25. The composition of claim 1 comprising: 100 pt. wt. of component (A),0.1 to about 10 pt. wt. of at least one crosslinker (B),0.01 to about 7 pt. wt. of the catalyst composition (C),0 to about 5 pt. wt. of an amino-functional siloxane (E),0 to about 300 pt. wt. of component (F),0.01 to about 8 pt. wt. of component (G),whereby this composition can be stored in the absence of humidity and is curable in the presence of humidity upon exposure to ambient air. 26. The cured polymer material of claim 25 in the form of an elastomeric or duromeric seal, an adhesive, a coating, an encapsulant, a shaped article, a mold, and an impression material. 27. A method of providing a cured material comprising exposing the composition of claim 1 to ambient air. 28. A cured polymer material formed from the composition of claim 1.
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