대표
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1. A magneto-cryogenic valve, comprising: a connector for connecting the magneto-cryogenic valve to a conduit through which a fluid flows;a valve chamber, comprising: end walls; andat least one fold;a heat transfer system comprising a cooling chamber suitable to contain a cryogen, wherein the cooling chamber is integrated into the magneto-cryogenic valve in proximity to the valve chamber;a first injector device for injecting magnetically susceptible particles into the fluid; anda magnetic field generating device, wherein: the valve chamber is connectable...
1. A magneto-cryogenic valve, comprising: a connector for connecting the magneto-cryogenic valve to a conduit through which a fluid flows;a valve chamber, comprising: end walls; andat least one fold;a heat transfer system comprising a cooling chamber suitable to contain a cryogen, wherein the cooling chamber is integrated into the magneto-cryogenic valve in proximity to the valve chamber;a first injector device for injecting magnetically susceptible particles into the fluid; anda magnetic field generating device, wherein: the valve chamber is connectable in fluid communication with the conduit so that the fluid of the conduit can flow through the valve chamber;the magnetic field generating device produces a magnetic field comprising field lines and is positioned so that at least a portion of the field lines penetrate through the fluid in the valve chamber and interact with the injected magnetically susceptible particles; andthe heat transfer system removes thermal energy from the valve chamber and the fluid therein. 2. The magneto-cryogenic valve of claim 1, further comprising a second injector device for injecting an adhesion promoter composition into the fluid. 3. The magneto-cryogenic valve of claim 1, wherein valve chamber comprises a portion of the conduit. 4. The magneto-cryogenic valve of claim 1, wherein the cooling chamber comprises: (a) particles, filings, turnings, shavings, pellets, threads or beads of a thermally conductive material; or(b) baffles or fins; or(c) a combination of (a) and (b). 5. The magneto-cryogenic valve of claim 1, wherein the cooling chamber comprises: an inlet port for admitting a cryogen into the cooling chamber; andan outlet port for discharging the spent cryogen out of the cooling chamber. 6. The magneto-cryogenic valve of claim 1, wherein the magnetic field generating device comprises an electromagnet, a permanent magnet, or a combination thereof. 7. The magneto-cryogenic valve of claim 6, wherein: (a) the permanent magnet comprises a ferrite material or a rare earth element; or(b) the permanent magnet is selected from among Nd—Fe—B type, Sm—Co type and Sm—N—Fe type rare earth permanent magnets. 8. The magneto-cryogenic valve of claim 1, wherein a magnet of the magnetic field generating device is mounted on a movable track. 9. The magneto-cryogenic valve of claim 1, wherein a pole of a magnetic field generating device penetrates into the valve chamber. 10. The magneto-cryogenic valve of claim 1, wherein no pole of a magnetic field generating device penetrates into the valve chamber. 11. The magneto-cryogenic valve of claim 1, wherein: (a) the magnetic field of at least one magnetic field generating device directs the injected magnetically susceptible particles to the center of the valve chamber; or(b) the magnetic field of at least one magnetic field generating device directs the injected magnetically susceptible particles to an end of the valve chamber; or(c) the magnetic field of at least one magnetic field generating device directs the injected magnetically susceptible particles to a wall of the valve chamber; or(d) a combination of any of (a), (b) and (c). 12. The magneto-cryogenic valve of claim 1, wherein the magnetic field generating device comprises an electromagnet or a permanent magnet having a magnetic flux density of about 0.1 Tesla to about 15 Tesla. 13. The magneto-cryogenic valve of claim 1, wherein the magnetic field generating device produces an oscillating magnetic field. 14. The magneto-cryogenic valve of claim 1, wherein the magnetic field generating devices are configured to provide a flux density of from about 0.5 Tesla to about 5 Tesla within the valve chamber. 15. The magneto-cryogenic valve of claim 1, wherein the valve chamber comprises: one fold to create a kidney-shaped chamber; ortwo folds to create a bi-lobed chamber; orthree folds to create a tri-lobed chamber; orfour folds to create a tetra-lobed chamber; orfive folds to create a penta-lobed chamber; orsix folds to create a hexa-lobed chamber; orseven folds to create a hepta-lobed chamber; oreight folds to create a octa-lobed chamber; ornine folds to create a nona-lobed chamber; orten folds to create a deca-lobed chamber. 16. The magneto-cryogenic valve of claim 1, wherein: (a) the valve chamber comprises two 90° end walls; or(b) the valve chamber comprises two sloped end walls; or(c) the valve chamber comprises one 90° end wall and one sloped end wall. 17. The magneto-cryogenic valve of claim 1, wherein the valve chamber has a width that is from about 1× to about 10× the inner diameter of the conduit to which the magneto-cryogenic valve is attached. 18. The magneto-cryogenic valve of claim 1, wherein the valve chamber has a length that is from about 1.5× to about 10× the inner diameter of the conduit to which the magneto-cryogenic valve is attached. 19. The magneto-cryogenic valve of claim 1, wherein the valve chamber comprises at least one wall that contains projections or indentations or a combination thereof. 20. The magneto-cryogenic valve of claim 2, wherein: (a) the first and second injectors comprise an isolation mechanism for controlling the flow of material through the injectors; or(b) the first and second injectors comprise an activatable flow modulating valve to adjust the flow of material through the injector; or(c) both (a) and (b). 21. The magneto-cryogenic valve of claim 2, wherein the first injector or second injector or both comprise one or more or a combination of a flow rate meter, an emergency shut-off valve, an over-pressure valve, a diverter valve, a heating unit or a thermal monitoring device. 22. A system for extracting thermal energy from a conduit containing a fluid, comprising: a magneto-cryogenic valve of claim 1; andan injector slurry supply module. 23. The system of claim 22, further comprising: (a) an adhesion promoter composition supply module; or(b) a pressure regulator system connected to the injector slurry supply module; or(c) a cryogen supply module; or(d) a pump in fluid communication with the adhesion promoter composition supply module; or(e) one or more or a combination of flow control valves, diverter valves, pressure relief valves, pressure monitoring devices, temperature monitoring devices, or flow rate measuring devices; or(f) a computer control module; or(g) a combination of any of (a), (b), (c), (d), (e), and (f). 24. The system of claim 22, wherein the injector slurry supply module is in fluid communication with the second injector of the magneto-cryogenic valve and provides an injector slurry composition comprising magnetically susceptible particles to the second injector. 25. The system of claim 24, wherein the injector slurry composition comprises: (a) magnetically susceptible particles that are paramagnetic or diamagnetic or ferromagnetic or any combination thereof; or(b) magnetically susceptible particles comprising cobalt, Co—Zr alloys, Co—Nb alloys, dysprosium, Fe—Si alloys, gadolinium, iron, mu metal (nickel iron alloy), nickel, permalloys (iron-nickel alloys), rare earth-transition metal alloys, spinel ferrites or supermalloy or any combination or alloy thereof; or(c) magnetically susceptible particles comprising a Gd—Co or Fe—Tb alloy; or(d) magnetically susceptible particles comprising cobalt, iron, nickel, magnetite (Fe3O4) or maghemite (Fe2O3) or combinations thereof; or(e) any combination of (a), (b), (c) and (d). 26. The system of claim 24, wherein the injector slurry composition comprises magnetically susceptible having a thermal conductivity greater than 0.2 W/(m·K), or greater than 0.5 W/(m·K), or greater than 0.75 W/(m·K), or greater than 1 W/(m·K), or greater than 5 W/(m·K), or greater than 10 W/(m·K), or greater than 20 W/(m·K), or greater than 30 W/(m·K), or greater than 40 W/(m·K), or greater than 50 W/(m·K) or greater than 100 W/(m·K). 27. The system of claim 24, wherein the injector slurry composition comprises magnetically susceptible particles of a shape selected from among cubes, flakes, granules, cylinders, rings, rods, needles, prisms, disks, fibers, pyramids, spheres, spheroids, prolate spheroids, oblate spheroids, ellipsoids, ovoids, hexahedrons, hexagonal prisms, tetrahexahedrons, octahedrons, truncated octahedrons, dodecahedrons, triangular prisms or random non-geometric shapes or any combinations of these shapes. 28. The system of claim 24, wherein the injector slurry composition comprises: (a) magnetically susceptible particles that are solid; or(b) magnetically susceptible particles that are hollow; or(c) a combination of (a) and (b). 29. The system of claim 24, wherein the injector slurry composition comprises magnetically susceptible particles that comprise: (a) a partial or complete coating comprising a thermally conductive material or an oxide or a combination thereof; or(b) a partial or complete coating comprising a corrosion-resistant material; or(c) a partial or complete ferromagnetic coating; or(d) any combination of (a), (b) and (c). 30. The system of claim 24, wherein the injector slurry composition comprises magnetically susceptible particles of a particle size from about 1 nm to about 20 cm. 31. The system of claim 30, wherein the injector slurry composition comprises magnetically susceptible particles of a particle size: (a) from about 1 nm to about 100 μm; or(b) greater than 100 μm and less than 5 cm; or(c) from about 1000 μm and about 1 cm; or(d) any combination of (a), (b) and (c). 32. The system of claim 24, wherein the injector slurry composition comprises magnetically susceptible particles having a bimodal particle size distribution, wherein one mode of the distribution has an average particle size between about 1000 μm and about 10 cm and the other mode of the distribution has an average particle size between about 1 nm and 100 μm. 33. The system of claim 24, wherein the amount of magnetically susceptible particles in the injection slurry composition is: (a) from 0.01% to 95% based on the weight of the injection slurry composition; or(b) greater than 95% based on the weight of the injection slurry composition. 34. The system of claim 24, wherein the injector slurry composition comprises a carrier comprising a cryogen or a solvent or a combination thereof. 35. The system of claim 34 wherein the cryogen comprises liquid nitrogen, liquid oxygen, liquid helium, liquid neon, liquid methane, liquid natural gas, liquid argon, liquid nitrous oxide, or liquid carbon dioxide or combinations thereof. 36. The system of claim 34, wherein: (a) the amount of cryogen the injector slurry composition is from 1% to 99% based on the weight of the injector slurry composition; or(b) the amount of solvent in the injector slurry composition is from about 0.05% to 75% based on the weight of the injector slurry composition. 37. The system of claim 23, wherein the adhesion promoter supply module is in fluid communication with the first injector of the magneto-cryogenic valve and provides an adhesion promoter composition to the second injector. 38. The system of claim 37, wherein the adhesion promoter composition comprises: (a) a surface tension reducer in an amount of from about 0.01% to about 50% based on the weight of the adhesion promoter composition; or(b) a solvent in an amount of from about 0.05% to about 85% based on the weight of the adhesion promoter composition; or(c) a combination of (a) and (b). 39. The system of claim 23, wherein the cryogen supply module is in fluid communication with the heat transfer system of the magneto-cryogenic valve and provides a cryogen to the heat transfer system. 40. The system of claim 39, wherein the cryogen comprises liquid carbon dioxide, liquid ammonia, liquified chlorofluorohydrocarbons, liquid nitrogen, liquid oxygen, liquid neon, liquid argon, liquid nitrous oxide, hydrofluoroethane, pentafluoropropane, trichloro-monofluoromethane or dichlorodifluoromethane, or a mixture or any combination thereof. 41. The system of claim 23, wherein the cryogen supply module comprises one or more of a flow rate meter, a flow-control metering valve, an isolation valve, an emergency shut-off valve, an over-pressure valve, a diverter valve, a heating unit, or a thermal monitoring device or any combination thereof. 42. A method for temporarily preventing the flow of fluid in a conduit, comprising: activating a magneto-cryogenic valve of claim 2 attached to the conduit, wherein the heat transfer system of the magneto-cryogenic valve removes sufficient thermal energy from the fluid to cause at least a portion of the fluid in the valve chamber of the magneto-cryogenic valve to freeze to form a reversible plug that prevents the fluid from flowing through the conduit. 43. The method of claim 42, wherein the frozen plug transfers the upstream pressure load from the fluid to the walls of the valve chamber. 44. The method of claim 42, wherein activating the magneto-cryogenic valve comprises charging the heat transfer system so that it is able to extract thermal energy from at least a portion of the conduit to which the heat transfer system is attached or from a fluid contained therein. 45. The method of claim 44, wherein charging the heat transfer system comprises activating the cryogen supply module to provide cryogen to the heat transfer system. 46. The method of claim 42, wherein activating the magneto-cryogenic valve further comprises: (a) activating the pump attached to the adhesion promoter composition supply module to cause adhesion promoter to be injected into the fluid within the conduit via the first injector of the magneto-cryogenic valve; or(b) activating the pressure regulator system attached to the injector slurry supply module to cause an injector slurry composition comprising magnetically susceptible particles to be injected into the fluid within the conduit via the second injector of the magneto-cryogenic valve; or(c) activating the magnetic field generating device to produce magnetic fields, at least a portion of which enter the valve chamber; or(d) any combination of (a), (b) and (c). 47. The method of claim 46, wherein the magnetic fields of the magnetic field generating device interact with the magnetically susceptible particles of the injection slurry composition. 48. The method of claim 42, wherein the first injector of the magneto-cryogenic valve is positioned so that the injection of the adhesion promoter composition into the fluid within the conduit occurs before the second injector introduces the injection slurry composition into the fluid within the conduit. 49. The method of claim 42, wherein the heat transfer system or the second injector injecting the injection slurry composition or both is/are activated for a sufficient amount of time to form a frozen plug of fluid that prevents flow of the fluid through the conduit. 50. The method of claim 42, further comprising as a step increasing the temperature in the vicinity of the attachment of the heat transfer system to donate thermal energy to the conduit, thereby at least partially melting the frozen plug and restoring flow of the fluid through the conduit. 51. The method of claim 50, wherein the temperature is increased by: (a) oscillating a magnetic field of a magnetic field generating device; or(b) activating a heating device; or(c) both (a) and (b). 52. The method of claim 42, wherein the fluid within the conduit comprises a hydrocarbon gas or hydrocarbon fluid or combination thereof. 53. The method of claim 46, wherein the injector slurry composition comprises magnetically susceptible particles of a particle size: (a) from about 1 nm to about 20 cm; or(b) from about 1 nm to about 100 μm; or(c) greater than 100 μm and less than 5 cm; or(d) from about 1000 μm to about 1 cm; or(e) having a bimodal particle size distribution, wherein one mode of the distribution has an average particle size from about 1000 μm to about 17 cm and the other mode of the distribution has an average particle size between about 1 nm and 100 μm. 54. The method of claim 46, wherein the step of injecting an injector slurry comprises injecting a plurality of different injector slurries each containing magnetically susceptible particles having a different average particle size. 55. The method of claim 46, wherein the magnetically susceptible particles have a shape selected from among cubes, flakes, granules, cylinders, rings, rods, needles, prisms, disks, fibers, pyramids, spheres, spheroids, prolate spheroids, oblate spheroids, ellipsoids, ovoids, hexahedrons, hexagonal prisms, tetrahexahedrons, octahedrons, truncated octahedrons, dodecahedrons, triangular prisms or random non-geometric shapes or any combinations of these shapes. 56. The method of claim 46, wherein prior to injection, the magnetically susceptible particles are cooled to a temperature below the freezing temperature of the fluid within the conduit. 57. The magneto-cryogenic valve of claim 1 having a cooling chamber between each fold of the valve chamber. 58. The magneto-cryogenic valve of claim 1, wherein the end walls are the entry and exit walls of the valve chamber.