The present invention relates to a dental polymer composition, in particular to a polymerizable resin composition combining comonomers capable of intermolecular hydrogen bonding with one or more hydrophobic comonomers. Polymers employing the present resin system exhibit high mechanical strength prop
The present invention relates to a dental polymer composition, in particular to a polymerizable resin composition combining comonomers capable of intermolecular hydrogen bonding with one or more hydrophobic comonomers. Polymers employing the present resin system exhibit high mechanical strength properties that are retained in the presence of water.
대표청구항▼
1. A polymerizable resin composition comprising a urethane monomer, wherein the urethane monomer is urethane dimethacrylate (UDMA), an acidic monomer, wherein the acidic monomer is methacrylic acid (MAA), and one or more hydrophobic monomers, and wherein the molar ratio of urethane monomer UDMA to a
1. A polymerizable resin composition comprising a urethane monomer, wherein the urethane monomer is urethane dimethacrylate (UDMA), an acidic monomer, wherein the acidic monomer is methacrylic acid (MAA), and one or more hydrophobic monomers, and wherein the molar ratio of urethane monomer UDMA to acidic monomer MAA is about 1:2+/−20%. 2. The resin composition of claim 1, wherein the weight ratio of urethane monomers plus acidic monomers compared to hydrophobic monomers is selected from about 99:1 to 50:50. 3. The resin composition of claim 1 further comprising a surfactant. 4. The resin composition of claim 1 further comprising an initiator. 5. The resin composition of claim 1 further comprising a prepolymer. 6. The resin composition of claim 1, wherein the one or more hydrophobic monomers are selected from the group consisting of isostearyl methacrylate (ISMA), branched ISMA, ethoxylated bisphenol A dimethacrylate (EBDMA), stearyl methacrylate, lauryl methacrylate, isodecyl methacrylate, 2-ethylhexyl methacrylate and cyclohexyl methacrylate. 7. The resin composition of claim 3, wherein the surfactant is selected from sodium dodecyl sulfate (SDS), ammonium lauryl sulfate, Cetyl trimethylammonium bromide (CTAB), Cetylpyridinium chloride (CPC), Polyethoxylated tallow amine (POEA); Dodecyl betaine, Dodecyl dimethylamine oxide, sodium lauryl sulfate and polyether modified polydimethyl-siloxane. 8. The resin composition of claim 4, wherein the initiator is selected from a thermal initiator or a photoinitiator. 9. The resin of claim 8, wherein the thermal initiator is selected from the group consisting of 2,2′azobis(isobutyronitrile) (AIBN), azobis(2-methylbutyronitrile), azobis(2,4-dimethylvaleronitrile), 4,4-azobis(4-cyanovaleric acid), 1,1′-azobis(cyclohexanecarbonitrile); and a peroxide. 10. The resin composition of claim 5, wherein the prepolymer is formed from a resin composition comprising methyl methacrylate (MMA) or isobornyl methacrylate (IBMA). 11. A polymerizable dental restorative material comprising: particles of filler and the resin composition of claim 1. 12. The dental restorative material of claim 11, wherein the filler is present at 40 wt % to 90 wt % of the total material weight. 13. The dental restorative material of claim 11, wherein the filler is present at 70 wt % to 85 wt % of the total material weight. 14. The dental restorative material of claim 11, wherein the filler is present at 75 wt % to 80 wt % of the total material weight. 15. The resin of claim 9, wherein the peroxide is selected from the group consisting dilauroyl peroxide, tert-butyl peroxyneodecanoate, dibenzoyl peroxide, 2,2-bis(tert-butylperoxy)butane, 1,1-bis(tert-butylperoxy)cyclohexane, 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane, 2,5-bis(tert-Butylperoxy)-2,5-dimethyl-3-hexyne, bis(1-(tert-butylperoxy)-1-methylethyl)benzene, 1,1-bis(tert-butylperoxy)-3,3,5-trimethylcyclohexane, tert-butyl hydroperoxide, tert-butyl peracetate, tert-butyl peroxide, tert-butylperoxy isopropyl carbonate, cyclohexanone peroxide, dicumyl peroxide, lauroyl peroxide, 2,4-pentanedione peroxide, peracetic acid, cumyl peroxide, tert-butyl peroxy-2-ethyl hexanoate, tert-butyl peroxy diethyl acetate, tert-amyl peroxybenzoate, tert-butyl peroxy benzoate and benzoyl peroxide (BPO). 16. The resin composition of claim 2, wherein the weight ratio of urethane monomers plus acidic monomers compared to hydrophobic monomers is from about 90:10 to about 60:40. 17. The resin composition of claim 16, wherein the weight ratio of urethane monomers plus acidic monomers compared to hydrophobic monomers is from about 85:15 to about 75:25. 18. The resin composition of claim 16, wherein the weight ratio of urethane monomers plus acidic monomers compared to hydrophobic monomers is about 70:30. 19. The resin composition of claim 1, wherein the molar ratio of urethane monomer UDMA to acidic monomer MAA is about 1:2. 20. The resin composition of claim 6, wherein the hydrophobic monomer is selected from the group consisting of ethoxylated bisphenol A dimethacrylate (EBDMA) and branched isostearyl methacrylate (ISMA). 21. The resin composition of claim 20, wherein the hydrophobic monomer comprises ethoxylated bisphenol A dimethacrylate (EBDMA) and branched isostearyl methacrylate (ISMA) in about a 75:25 weight ratio. 22. A polymerizable resin composite composition comprising a resin phase and a filler phase, wherein the resin phase comprises: about 51.2 wt % Urethane dimethacrylate;about 18.8 wt % Methacrylic acid;about 22.5 wt % Ethoxylated bisphenol A dimethacrylate;about 7.5 wt % branched Isostearyl methacrylate, compared to total weight of combined urethane monomers, acidic monomers and one or more hydrophobic monomers in the resin phase of the polymerizable resin composition. 23. The polymerizable resin composite composition of claim 22, wherein the resin phase further comprises Benzoyl peroxide (BPO). 24. The polymerizable resin composite composition of claim 22, wherein the filler phase comprises a filler selected from the group consisting of barium glass, fumed silica, and ytterbium fluoride. 25. The polymerizable resin composite composition of claim 24, wherein the filler phase comprises from about 40 and 85 wt % with respect to the weight of the overall composite composition. 26. The polymerizable resin composite composition of claim 25, wherein the filler phase comprises a barium glass with methacrylate silane surface treatment (Ba glass) and/or a fumed silica with methacrylate silane surface treatment (OX50). 27. The polymerizable resin composite composition of claim 22, further comprising one or more additional adjuvants selected from the group consisting of colorants, flavorants, anti-microbials, fragrance, stabilizers, viscosity modifiers and fluoride releasing materials. 28. The polymerizable resin composition of claim 22, wherein after polymerization, the cured composite composition exhibits: i. surface hardness of at least 40 kgf/mm2 as determined by Vickers indentation;ii. conversion of at least 92% when tested by near-infrared spectroscopy;iii. flexural modulus of at least 4 GPa when tested according to ISO/DIS 4049;iv. flexural strength of at least 88 MPa when tested according to ISO/DIS 4049. 29. The polymerizable resin composition of claim 28, wherein after polymerization, the cured composite composition exhibits flexural strength of at least 134 MPa when tested according to ISO/DIS 4049.
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이 특허에 인용된 특허 (4)
Neffgen, Stephan; Neander, Swen; Lubbers, Dierk, Conditioning agent for the etching of enamel lesions.
Aasen Steven M. (Lakeland MN) Ubel ; III F. Andrew (St. Paul MN) Oxman Joel D. (St. Louis Park MN) Mitra Sumita B. (West St. Paul MN) Fundingsland Jon W. (Maplewood MN), Method for adhering to hard tissue.
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