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Systems and methods are provided for capturing CO2 from a combustion source using molten carbonate fuel cells (MCFCs). At least a portion of the anode exhaust can be recycled for use as part of anode input stream. This can allow for a reduction in the amount of fuel cell area required for separating

Systems and methods are provided for capturing CO2 from a combustion source using molten carbonate fuel cells (MCFCs). At least a portion of the anode exhaust can be recycled for use as part of anode input stream. This can allow for a reduction in the amount of fuel cell area required for separating CO2 from the combustion source exhaust and/or modifications in how the fuel cells can be operated.

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1. A method for capturing carbon dioxide from a combustion source, said method comprising: capturing an output stream from a combustion source, said captured output stream comprising oxygen and carbon dioxide;processing the captured output stream with a fuel cell array of one or more molten carbonat

1. A method for capturing carbon dioxide from a combustion source, said method comprising: capturing an output stream from a combustion source, said captured output stream comprising oxygen and carbon dioxide;processing the captured output stream with a fuel cell array of one or more molten carbonate fuel cells, the one or more fuel cells each having an anode and a cathode, the molten carbonate fuel cells being operatively connected to the carbon dioxide stream through one or more cathode inlets of molten carbonate fuel cells in the fuel cell array;reacting fuel with carbonate from the one or more fuel cell cathodes within the one or more fuel cell anodes to produce electricity and to produce an anode exhaust stream from at least one anode outlet of the fuel cell array comprising carbon dioxide and hydrogen, at least a portion of the fuel reacted with carbonate comprising hydrogen recycled from the anode exhaust stream;passing at least a portion of the anode exhaust stream through a water gas shift reaction stage;separating carbon dioxide from the water gas shifted anode exhaust stream in one or more separation stages; andrecycling at least a portion of the water gas shifted anode exhaust stream to the anode after separation of the carbon dioxide from the water gas shifted anode exhaust stream,wherein a cathode exhaust has a CO2 content at a cathode exit of about 2.0 vol % or less. 2. The method of claim 1, wherein the hydrogen content of the anode exhaust stream at the at least one anode outlet is at least about 10 vol %. 3. The method of claim 1, wherein the fuel utilization in the one or more fuel cell anodes is about 60% or less. 4. The method of claim 1, wherein the fuel comprises a carbon-containing component that is reformed in at least one reforming stage external to the fuel cell array. 5. The method of claim 1, wherein the fuel comprises a carbon-containing component that is reformed in at least one reforming stage internal to an assembly, the assembly comprising the reforming stage and one or more fuel cells in the fuel cell array. 6. The method of claim 1, wherein the hydrogen recycled from the anode exhaust stream comprises at least about 5 vol % of the fuel. 7. The method of claim 6, wherein the fuel comprises a carbon-containing component, the fuel being passed into the one or more fuel cell anodes without prior reforming. 8. The method of claim 7, wherein the carbon-containing component comprises methane. 9. The method of claim 1, wherein the fuel cell array comprises a plurality of fuel cells arranged in parallel, a plurality of fuel cells arranged in series, or a combination thereof. 10. The method of claim 1, wherein the fuel cell array comprises at least two stages of fuel cells, such as at least three stages of fuel cells, a fuel cell stage comprising one or more fuel cells in fluid communication in series with at least one fuel cell in a different fuel cell stage. 11. The method of claim 10, where the one or more fuel cells in fluid communication in series comprise one or more fuel cell cathodes in fluid communication in series. 12. The method of claim 1, wherein the at least a portion of the water gas shifted anode exhaust stream is recycled as fuel without recycling a portion of the anode exhaust stream, directly or indirectly, to a cathode of the fuel cell array. 13. The method of claim 1, wherein the captured exhaust stream comprises at least about 4 vol % CO2. 14. The method of claim 1, wherein the captured exhaust stream comprises about 8 vol % or less of CO2. 15. A method for capturing carbon dioxide from a combustion source, said method comprising: capturing an output stream from a combustion source, said captured output stream comprising oxygen and carbon dioxide;processing the captured output stream with a fuel cell array of one or more molten carbonate fuel cells, the one or more fuel cells each having an anode and a cathode, the molten carbonate fuel cells being operatively connected to the carbon dioxide stream through one or more cathode inlets of molten carbonate fuel cells in the fuel cell array;reacting fuel with carbonate from the one or more fuel cell cathodes at a fuel utilization of about 60% or less within the one or more fuel cell anodes to produce electricity and to produce an anode exhaust stream from at least one anode outlet of the fuel cell array comprising carbon dioxide and hydrogen, at least a portion of the fuel reacted with carbonate comprising hydrogen recycled from the anode exhaust stream;separating carbon dioxide from the anode exhaust stream in one or more separation stages; andrecycling at least a portion of the anode exhaust stream to the anode after separation of the carbon dioxide from the anode exhaust stream,wherein a cathode exhaust has a CO2 content at a cathode exit of about 2.0 vol % or less. 16. The method of claim 15, wherein the hydrogen content of the anode exhaust stream at the at least one anode outlet is at least about 20 vol %. 17. The method of claim 15, wherein the fuel utilization in the one or more fuel cell anodes is at least about 40%. 18. The method of claim 15, wherein the CO2 content of the cathode exhaust at the cathode exit is about 1.5 vol % or less. 19. The method of claim 15, wherein the fuel comprises a carbon-containing component that is reformed in at least one reforming stage that is external to the fuel cell array. 20. The method of claim 15, wherein the fuel comprises a carbon-containing component that is reformed in at least one reforming stage that is internal to an assembly, the assembly comprising the reforming stage and one or more fuel cells in the fuel cell array. 21. The method of claim 15, wherein the hydrogen recycled from the anode exhaust comprises at least about 5 vol % of the fuel. 22. The method of claim 21, wherein the fuel comprises a carbon-containing component, the fuel being passed into the one or more fuel cell anodes without prior reforming. 23. The method of claim 22, wherein the carbon-containing component comprises methane. 24. The method of claim 15, wherein the fuel cell array comprises a plurality of fuel cells arranged in parallel, a plurality of fuel cells arranged in series, or a combination thereof. 25. The method of claim 15, wherein the fuel cell array comprises at least two stages of fuel cells, such as at least three stages of fuel cells, a fuel cell stage comprising one or more fuel cells in fluid communication in series with at least one fuel cell in a different fuel cell stage. 26. The method of claim 25, where the one or more fuel cells in fluid communication in series comprise one or more fuel cell cathodes in fluid communication in series. 27. The method of claim 15, wherein the at least a portion of the anode exhaust stream is recycled as fuel without recycling a portion of the anode exhaust stream, directly or indirectly, to a cathode of the fuel cell array. 28. The method of claim 15, wherein the captured exhaust stream comprises at least about 4 vol % CO2. 29. The method of claim 15, wherein the captured exhaust stream comprises about 8 vol % or less of CO2. 30. The method of claim 15, wherein at least a second portion of the anode exhaust stream is passed through a water gas shift reaction stage prior to the separating of carbon dioxide from the anode exhaust stream.