An ammonia gas generator for producing ammonia from a solution of an ammonia precursor substance, comprising a catalyst unit that comprises a catalyst for the decomposition and/or hydrolysis of ammonia precursor substances into ammonia and a mixing chamber provided upstream of the catalyst; an injec
An ammonia gas generator for producing ammonia from a solution of an ammonia precursor substance, comprising a catalyst unit that comprises a catalyst for the decomposition and/or hydrolysis of ammonia precursor substances into ammonia and a mixing chamber provided upstream of the catalyst; an injection device for injecting the solution of the ammonia precursor substance into the mixing chamber; at least one inlet for the carrier gas; and an outlet for the formed ammonia gas, said ammonia gas generator also comprising a perforated disc.
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1. An ammonia gas generator for generating ammonia from a solution of an ammonia precursor substance, comprising: a catalyst unit which comprises a catalyst for the decomposition and/or hydrolysis of ammonia precursor substances into ammonia and a mixing chamber provided upstream of the catalyst, th
1. An ammonia gas generator for generating ammonia from a solution of an ammonia precursor substance, comprising: a catalyst unit which comprises a catalyst for the decomposition and/or hydrolysis of ammonia precursor substances into ammonia and a mixing chamber provided upstream of the catalyst, the catalyst having a catalyst volume VCat and the mixing chamber having a mixing chamber volume VMix sufficient to wet a catalyst end face of the catalyst with the solution of the ammonia precursor substance;an injection device for introducing the solution of the ammonia precursor substance into the mixing chamber;at least one inlet for a carrier gas; and,an outlet for the ammonia gas that is formed,wherein the ammonia gas generator further comprises a perforated disc through which the carrier gas is introduced into the mixing chamber in the form of a plurality of parallel jets in a manner perpendicular to the catalyst end face; and wherein the mixing chamber is operable to deposit droplets of the solution of the ammonia precursor substance on the catalyst end face. 2. The ammonia gas generator of claim 1 wherein the ammonia gas generator comprises a perforated disc, in the centre of which at least one nozzle opening of a nozzle is arranged. 3. The ammonia gas generator of claim 1 wherein the injection device comprises a nozzle which generates drops having a Sauter diameter D32 of from 26 to 100 μm. 4. A method for generating ammonia from a solution of an ammonia precursor substance using an ammonia gas generator comprising: a catalyst unit which comprises a catalyst for the decomposition and/or hydrolysis of ammonia precursor substances into ammonia and a mixing chamber provided upstream of the catalyst, the catalyst having a catalyst volume VCat and the mixing chamber having a mixing chamber volume VMix sufficient to wet a catalyst end face of the catalyst with the solution of the ammonia precursor substance;an injection device for introducing the solution of the ammonia precursor substance into the mixing chamber;at least one inlet for a carrier gas; and,an outlet for the ammonia gas that is formed,wherein the carrier gas is introduced into the mixing chamber in the form of a plurality of parallel jets in a manner perpendicular to the catalyst end face, and the parallel jets are generated by a perforated disc; and wherein the mixing chamber is operable to deposit droplets of the solution of the ammonia precursor substance on the catalyst end face. 5. The method of claim 4 wherein the solution of the ammonia precursor substance is introduced into the mixing chamber in the form of drops having a Sauter diameter D32 of from 26 μm to 100 μm, from 26 μm to 49 μm, or from 26 μm to 40 μm. 6. The method of claim 4 wherein there is used in the method a carrier gas which has a temperature T(K) in the range of from 10° C. to 550° C. 7. The method of claim 4 wherein there is used in the method a carrier gas which is introduced into the mixing chamber at a temperature T(K) in the range of from 250° C. to 550° C. 8. The method according of claim 4 wherein there is used in the method a carrier gas which has a temperature T(K) in the range of from 10° C. to 200° C. 9. The method of claim 4 wherein the solution of the ammonia precursor substance is introduced in the form of an aerosol into the plurality of parallel jets of the carrier gas. 10. The method of claim 4 wherein the solution of the ammonia precursor substance is introduced into the mixing chamber separately from the carrier gas. 11. The method of claim 4 wherein the carrier gas is introduced into the mixing chamber in parallel with the solution of the ammonia precursor substance in the form of a bundle of parallel jets. 12. The method of claim 4 wherein there is used as the solution of an ammonia precursor substance an aqueous solution comprising urea, an ammonium salt, a guanidinium salt or mixtures thereof. 13. The method of claim 4 wherein the carrier gas is introduced into the mixing chamber with a first pressure at the inlet for the carrier gas that is higher than a second pressure at the outlet for the ammonia gas. 14. The method of claim 4 wherein the carrier gas is introduced into the mixing chamber with a pressure which is necessary to overcome a pressure difference delta p(K) in the range of from 10 mbar to 100 mbar between the inlet for the carrier gas and the outlet for the ammonia gas. 15. The method of claim 4 wherein the carrier gas is drawn through the mixing chamber by a low pressure downstream of the ammonia gas generator. 16. The method of claim 4 wherein the catalyst is a heated hydrolysis catalyst for hydrolysis of the ammonia precursor substance. 17. A method for reducing nitrogen oxides in exhaust gases of internal combustion engines, comprising the method of claim 4 for generating ammonia wherein the resulting ammonia gas is introduced into the exhaust gas line of the internal combustion engine directly into a Venturi mixer. 18. A method for reducing nitrogen oxides in exhaust gases from internal combustion engines, from gas engines, from diesel engines or from petrol engines, comprising employing the method of claim 4. 19. The ammonia gas generator of claim 1, wherein the mixing chamber is delimited in a direction of flow on a first side by the catalyst end face and on a second side by the perforated disc. 20. The method of claim 4, wherein the mixing chamber is delimited in a direction of flow on a first side by the catalyst end face and on a second side by the perforated disc. 21. The method of claim 4, wherein the solution of the ammonia precursor substance is introduced into the mixing chamber together with the carrier gas. 22. An ammonia gas generator for generating ammonia from a solution of an ammonia precursor substance, comprising: a catalyst unit which comprises a catalyst for the decomposition and/or hydrolysis of ammonia precursor substances into ammonia and a mixing chamber provided upstream of the catalyst, the catalyst having a catalyst volume VCat and the mixing chamber having a mixing chamber volume Vmix sufficient to wet a catalyst end face of the catalyst with the solution of the ammonia precursor substance;an injection device for introducing the solution of the ammonia precursor substance into the mixing chamber;at least one inlet for a carrier gas; and,an outlet for the ammonia gas that is formed,wherein the ammonia gas generator further comprises a perforated disc through which the carrier gas is introduced into the mixing chamber in the form of a plurality of parallel jets in a manner perpendicular to a catalyst end face of the catalyst; andwherein the ammonia gas generator is not part of an exhaust gas line and is operable independent of whether the carrier gas is exhaust gas. 23. A method for generating ammonia from a solution of an ammonia precursor substance using an ammonia gas generator, comprising: a catalyst unit which comprises a catalyst for the decomposition and/or hydrolysis of ammonia precursor substances into ammonia and a mixing chamber provided upstream of the catalyst, the catalyst having a catalyst volume VCat and the mixing chamber having a mixing chamber volume Vmix sufficient to wet a catalyst end face of the catalyst with the solution of the ammonia precursor substance;an injection device for introducing the solution of the ammonia precursor substance into the mixing chamber;at least one inlet for a carrier gas; and,an outlet for the ammonia gas that is formed,wherein the carrier gas is introduced into the mixing chamber in the form of a plurality of parallel jets in a manner perpendicular to a catalyst end face of the catalyst, and the parallel jets are generated by a perforated disc; andwherein the ammonia gas generator is not part of an exhaust gas line and is operable independent of whether the carrier gas is exhaust gas. 24. An ammonia gas generator for generating ammonia from a solution of an ammonia precursor substance, comprising: a catalyst unit which comprises a catalyst for the decomposition and/or hydrolysis of ammonia precursor substances into ammonia and a mixing chamber provided upstream of the catalyst, the catalyst having a catalyst volume VCat and the mixing chamber having a mixing chamber volume Vmix sufficient to wet a catalyst end face of the catalyst with the solution of the ammonia precursor substance;an injection device for introducing the solution of the ammonia precursor substance into the mixing chamber;at least one inlet for a carrier gas; and,an outlet for the ammonia gas that is formed,wherein the ammonia gas generator further comprises a perforated disc through which the carrier gas is introduced into the mixing chamber in the form of a plurality of parallel jets in a manner perpendicular to a catalyst end face of the catalyst; andwherein complete conversion of the ammonia precursor substance to ammonia occurs before the ammonia formed at the outlet is introduced into an exhaust gas stream. 25. A method for generating ammonia from a solution of an ammonia precursor substance using an ammonia gas generator, comprising: a catalyst unit which comprises a catalyst for the decomposition and/or hydrolysis of ammonia precursor substances into ammonia and a mixing chamber provided upstream of the catalyst, the catalyst having a catalyst volume VCat and the mixing chamber having a mixing chamber volume Vmix sufficient to wet a catalyst end face of the catalyst with the solution of the ammonia precursor substance;an injection device for introducing the solution of the ammonia precursor substance into the mixing chamber;at least one inlet for a carrier gas; and,an outlet for the ammonia gas that is formed,wherein the carrier gas is introduced into the mixing chamber in the form of a plurality of parallel jets in a manner perpendicular to a catalyst end face of the catalyst, and the parallel jets are generated by a perforated disc; andwherein complete conversion of the ammonia precursor substance to ammonia occurs before the ammonia formed at the outlet is introduced into an exhaust gas stream. 26. An ammonia gas generator for generating ammonia from a solution of an ammonia precursor substance, comprising: a catalyst unit which comprises a catalyst for the decomposition and/or hydrolysis of ammonia precursor substances into ammonia and a mixing chamber provided upstream of the catalyst, the catalyst having a catalyst volume VCat and the mixing chamber having a mixing chamber volume VMix;an injection device for introducing the solution of the ammonia precursor substance into the mixing chamber;at least one inlet for a carrier gas; and,an outlet for the ammonia gas that is formed,wherein the ammonia gas generator further comprises a perforated disc through which the carrier gas is introduced into the mixing chamber in the form of a plurality of parallel jets in a manner perpendicular to the catalyst end face;wherein the mixing chamber is operable to deposit droplets of the solution of the ammonia precursor substance on the catalyst end face; andwherein the mixing chamber is arranged to cause droplets of the solution of the ammonia precursor substance to wet the catalyst end face. 27. A method for generating ammonia from a solution of an ammonia precursor substance using an ammonia gas generator comprising: a catalyst unit which comprises a catalyst for the decomposition and/or hydrolysis of ammonia precursor substances into ammonia and a mixing chamber provided upstream of the catalyst, the catalyst having a catalyst volume VCat and the mixing chamber having a mixing chamber volume VMix;an injection device for introducing the solution of the ammonia precursor substance into the mixing chamber;at least one inlet for a carrier gas; and,an outlet for the ammonia gas that is formed,wherein the carrier gas is introduced into the mixing chamber in the form of a plurality of parallel jets in a manner perpendicular to the catalyst end face, and the parallel jets are generated by a perforated disc;wherein the mixing chamber is operable to deposit droplets of the solution of the ammonia precursor substance on the catalyst end face; andwherein the mixing chamber is arranged to cause droplets of the solution of the ammonia precursor substance to wet the catalyst end face.
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Schmelz Helmut (Prien DEX), Method and apparatus for controlled introduction of a reducing agent into a nitrogen oxide-containing exhaust gas.
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