Process for the regeneration of a copper, zinc and zirconium oxide-comprising adsorption composition
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
B01J-020/06
B01J-020/34
C07C-007/12
B01J-020/30
C10G-025/00
C10G-025/12
출원번호
US-0134660
(2013-12-19)
등록번호
US-9931613
(2018-04-03)
발명자
/ 주소
Henze, Guido
Karrer, Lothar
Urtel, Heiko
Hatscher, Stephan
출원인 / 주소
BASF SE
대리인 / 주소
Drinker Biddle & Reath LLP
인용정보
피인용 횟수 :
0인용 특허 :
4
초록▼
The invention relates to a process for the regeneration of a copper-, zinc- and zirconium oxide-comprising adsorption composition after use thereof for the adsorptive removal of carbon monoxide from substance streams comprising carbon monoxide and at least one olefin, in which the adsorption composi
The invention relates to a process for the regeneration of a copper-, zinc- and zirconium oxide-comprising adsorption composition after use thereof for the adsorptive removal of carbon monoxide from substance streams comprising carbon monoxide and at least one olefin, in which the adsorption composition is heated to a temperature in the range from 160 to 400° C. and a regeneration gas is passed through the adsorption composition, wherein the regeneration gas comprises 1000 to 3000 ppm of oxygen in an inert carrier gas.
대표청구항▼
1. A process for the regeneration of a copper-, zinc- and zirconium oxide-comprising adsorption composition for the adsorptive removal of carbon monoxide from a substance stream comprising carbon monoxide and at least one olefin, the process comprising; heating the adsorption composition to a temper
1. A process for the regeneration of a copper-, zinc- and zirconium oxide-comprising adsorption composition for the adsorptive removal of carbon monoxide from a substance stream comprising carbon monoxide and at least one olefin, the process comprising; heating the adsorption composition to a temperature in the range from 190° to 250° C.,passing a regeneration gas through the adsorption composition at a gas hourly velocity of from 100 to 5000 hr−1, wherein the regeneration gas comprises 1000 to 1900 ppm of oxygen in an inert carrier gas, wherein the copper-comprising fraction of the adsorption composition after the regeneration has a reduction level of at least 65% and at most 80%. 2. The process according to claim 1, wherein the adsorption composition comprises copper in a quantity which corresponds to 30 to 99.8 wt. % CuO, zinc in a quantity which corresponds to 0.1 to 69.9 wt. % ZnO and zirconium in a quantity which corresponds to 0.1 to 69.9 wt. % ZrO2, each based on the total quantity of the adsorption composition. 3. The process according to claim 1, wherein the adsorption composition comprises copper in a quantity which corresponds to 65 to 75 wt. % CuO, zinc in a quantity which corresponds to 1.5 to 25 wt. % ZnO and zirconium in a quantity which corresponds to 5 to 15 wt. % ZrO2, each based on the total quantity of the adsorption composition. 4. The process according to claim 1, wherein the copper-comprising fraction of the adsorption composition after the regeneration is at most 75%. 5. The process according to claim 1, wherein the regeneration gas comprises 1000 to 1500 ppm of oxygen. 6. The process according to claim 2, wherein the absorption composition further comprises aluminium oxide, and the aluminium oxide replaces at least 10% and at most 80% of the zirconium oxide fraction in the adsorption composition. 7. The process according to claim 1, wherein the reduction level of the adsorption composition is increased by 1.5 to 2% per regeneration step. 8. A process for the regeneration of a copper-, zinc- and zirconium oxide-comprising an adsorption composition for the adsorptive removal of carbon monoxide from a substance stream that also includes at least one olefin, the process comprising; heating the adsorption composition to a temperature in the range from 190° to 250° C.,passing a regeneration gas through the adsorption composition, wherein the regeneration gas comprises 1000 to 3000 ppm of oxygen in an inert carrier gas, wherein the copper-comprising fraction of the adsorption composition after the regeneration has a reduction level of at least 65%, and the reduction level of the adsorption composition is increased by 1.5 to 2% per regeneration step. 9. The process according to claim 8, wherein the adsorption composition comprises copper in a quantity which corresponds to 50 to 80 wt. % CuO, zinc in a quantity which corresponds to 5 to 30 wt. % ZnO and zirconium in a quantity which corresponds to 5 to 30 wt. % ZrO2, each based on the total quantity of the adsorption composition. 10. The process according to claim 8, wherein the copper-comprising fraction of the adsorption composition exhibits a reduction level of the copper-comprising fraction of 60 to 80% before the adsorption of carbon monoxide from the substance stream and after regeneration. 11. The process according to claim 8, wherein the adsorption composition comprises copper in a quantity which corresponds to 30 to 99.8 wt. % CuO, zinc in a quantity which corresponds to 0.1 to 69.9 wt. % ZnO, zirconium in a quantity which corresponds to 0.1 to 69.9 wt. % ZrO2, each based on the total quantity of the adsorption composition, and aluminium oxide, the aluminium oxide replacing at least 10% and at most 80% of the zirconium oxide fraction in the adsorption composition. 12. The process according to claim 9, wherein the passing the regeneration gas is conducted at a flow of from 100 to 1,000 hr−1.
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이 특허에 인용된 특허 (4)
Yokoe Jintaro (Amagasaki JPX) Takeuchi Masami (Amagasaki JPX) Tsuji Toshiaki (Amagasaki JPX), Adsorbent for separation-recovery of CO, preparing method thereof and process for separation-recovery of high purity CO,.
Xie Youchang (Beijing CNX) Bu Naiyu (Beijing CNX) Liu Jun (Beijing CNX) Yang Ge (Beijing CNX) Qiu Jianguo (Beijing CNX) Yang Naifang (Beijing CNX) Tang Youchi (Beijing CNX), Adsorbents for use in the separation of carbon monoxide and/or unsaturated hydrocarbons from mixed gases.
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