Metal organic frameworks comprising a plurality of SBUS with different metal ions and/or a plurality of organic linking ligands with different functional groups
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
B01J-031/16
B01J-020/22
C07F-019/00
C07F-003/02
C07F-003/04
C07F-003/06
C07F-003/08
C07F-003/10
C07F-005/00
C07F-007/00
C07F-013/00
C07F-015/02
C07F-015/04
C07F-015/06
B01D-053/02
F17C-011/00
출원번호
US-0128225
(2015-03-27)
등록번호
US-10087205
(2018-10-02)
국제출원번호
PCT/US2015/023173
(2015-03-27)
국제공개번호
WO2015/195179
(2015-12-23)
발명자
/ 주소
Yaghi, Omar M.
Suzuki, Mitsuharu
Deng, Hexiang
Wang, Lisa
출원인 / 주소
The Regents of the University of California
대리인 / 주소
Gavrilovich, Dodd & Lindsey LLP
인용정보
피인용 횟수 :
0인용 특허 :
39
초록
The disclosure provides for metal organic frameworks (MOFs) which comprise a plurality of SBUs comprising different metals or metal ions and/or a plurality of organic linking moieties comprising different functional groups.
대표청구항▼
1. A Metal-Organic Framework (MOF) comprising a plurality of secondary building units (SBUs) that are linked together by a plurality of organic linking ligands, the MOF selected from the group consisting of: (a) a plurality of different SBUs, at least two SBUs of the plurality of SBUs comprising dif
1. A Metal-Organic Framework (MOF) comprising a plurality of secondary building units (SBUs) that are linked together by a plurality of organic linking ligands, the MOF selected from the group consisting of: (a) a plurality of different SBUs, at least two SBUs of the plurality of SBUs comprising different metals or metal ions and a plurality of homogenous organic linking ligands that have been alkyl or amine functionalized; and(b) a plurality of SBUs and a plurality of organic linking ligands wherein at least two of the organic linking ligands comprise a different number or a different type of functional group(s),wherein the plurality of organic linking ligands comprise a structure of Formula I and/or II: wherein, n is a number from 0 to 10;A1-A8 are independently a C or N;R1-R12 are independently selected from H, D, optionally substituted (C1-C12)alkyl, optionally substituted hetero-(C1-C12 alkyl, optionally substituted (C1-C12)alkenyl, optionally substituted hetero-(C1-C12)alkenyl, optionally substituted (C1-C12)alkynyl, optionally substituted hetero-(C1-C12)alkynyl, optionally substituted (C1-C12)cycloalkyl, optionally substituted (C1-C12)cycloalkenyl, optionally substituted aryl, optionally substituted heterocycle, optionally substituted mixed ring system, —C(R13)3, —CH(R13)2, —CH2R13, —C(R14)3, —CH(R14)2, —CH2R14, —OC(R13)3, OCH(R13)2, —OCH2R13, —OC(R14)3, —OCH(R14)2, OCH2R14, wherein R4-R11 when adjacent can be linked together to form one or more optionally substituted rings selected from the group consisting of cycloalkyl, cycloalkenyl, heterocycle, aryl, and mixed ring system;R13 is selected from optionally substituted (C1-C12)alkyl, optionally substituted hetero-(C1-C12)alkyl, optionally substituted (C1-C12)alkenyl, optionally substituted hetero-(C1-C12)alkenyl, optionally substituted (C1-C12)alkynyl, optionally substituted hetero-(C1-C12)alkynyl, hemiacetal, hemiketal, acetal, ketal, and orthoester; andR14 is selected from one or more substituted or unsubstituted rings selected from cycloalkyl, aryl and heterocycle. 2. The MOF of claim 1, wherein the plurality of organic linking ligands comprise a structure of Formula III: wherein, R6-R9 are independently selected from: wherein M is an alkaline metal species, an alkaline-earth metal species, or transition metal species that has a formal charge of +1 or +2 and that can be coordinated by one or more neutral or charged ligands. 3. The MOF of claim 1, wherein the plurality of organic linking ligands comprise at least one organic linking ligand having the structure of: 4. The MOF of claim 1, wherein any hydroxyl group is protected with a hydroxyl protecting group, any amine group is protected with an amine protecting group, and/or any carbonyl is protected with a carbonyl protecting group. 5. The MOF of claim 4, wherein the amine protecting group is a tert-butyl carbamate (Boc) group. 6. The MOF of claim 1, wherein the plurality of SBUs comprise at least three SBUs that differ by being comprised of different metals or metal ions. 7. The MOF of claim 1, wherein the plurality of SBUs comprise at least four SBUs that differ by being comprised of different metals or metal ions. 8. The MOF of claim 1, wherein the plurality of SBUs comprise one or more metals or metal ions selected from: Li+, Na+, K+, Rb+, Cs+, Be2+, Mg2+, Ca2+, Sr2+, Ba2+, Sc3+, Sc2+, Sc+, Y3+, Y2+, Y+, Ti4+, Ti3+, Ti2+, Zr4+, Zr3+, Zr2+, Hf4+, Hf3+, V5+, V4+, V3+, V2+, Nb5+, Nb4+, Nb3+, Nb2+, Ta5+, Ta4+, Ta3+, Ta2+, Cr6+, Cr5+, Cr4+, Cr3+, Cr2+, Cr+, Cr, Mo6+, Mo5+, Mo4+, Mo3+, Mo2+, Mo+, Mo, W6+, W5+, W4+, W3+, W2+, W+, W, Mn7+, Mn6+, Mn5+, Mn4+, Mn3+, Mn2+, Mn+, Re7+, Re6+, Re5+, Re4+, Re3+, Re2+, Re+, Re, Fe6+, Fe4+, Fe3+, Fe2+, Fe+, Fe, Ru8+, Ru7+, Ru6+, Ru4+, Ru3+, Ru2+, Os8+, Os7+, Os6+, Os5+, Os4+, Os3+, Os2+, Os+, Os, Co5+, Co4+, Co3+, Co2+, Co+, Rh6+, Rh5+, Rh4+, Rh3+, Rh2+, Rh+, Ir6+, Ir5+, Ir4+, Ir3+, Ir2+, Ir+, Ir, Ni3+, Ni2+, Ni+, Ni, Pd6+, Pd4+, Pd2+, Pd+, Pd, Pt6+, Pt5+, Pt4+, Pt3+, Pt2+, Pt+, Cu4+, Cu3+, Cu2+, Cu+, Ag3+, Ag2+, Ag+, Au5+, Au4+, Au3+, Au2+, Au+, Zn2+, Zn+, Zn, Cd2+, Cd+, Hg4+, Hg2+, Hg+, B3+, B2+, B+, Al3+, Al2+, Al+, Ga3+, Ga2+, Ga+, In3+, In2+, In1+, Tl3+, Tl+, Si4+, Si3+, Si2+, Si+, Ge4+, Ge3+, Ge2+, Ge+, Ge, Sn4+, Sn2+, Pb4+, Pb2+, As5+, As3+, As2+, As+, Sb5+, Sb3+, Bi5+, Bi3+, Te6+, Te5+, Te4+, Te2+, La3+, La2+, Ce4+, Ce3+, Ce2+, Pr4+, Pr3+, Pr2+, Nd3+, Nd2+, Sm3+, Sm2+, Eu3+, Eu2+, Gd3+, Gd2+, Gd+, Tb4+, Tb3+, Tb2+, Tb+, Db3+, Db2+, Ho3+, Er3+, Tm4+, Tm3+, Tm2+, Yb3+, Yb2+, Lu3+, La3+, La2+, La+, and combinations thereof, including any complexes which contain the metals or metal ions, as well as any corresponding metal salt counter-anions. 9. The MOF of claim 1, wherein the plurality of SBUs comprise one or more divalent metal ions selected from: Be2+, Mg2+, Ca2+, Sr2+, Ba2+, Sc2+, Y2+, Ti2+, Zr2+, V2+, Nb2+, Ta2+, Cr2+, Mo2+, W2+, Mn2+, Re2+, Fe2+, Ru2+, Os2+, Co2+, Rh2+, Ir2+, Ni2+, Pd2+, Pt2+, Cu2+, Ag2+, Au2+, Zn2+, Cd2+, Hg2+, B2+, Al2+, Ga2+, In2+, Si2+, Ge2+, Sn2+, Pb2+, As2+, Te2+, La2+, Ce2+, Pr2+, Nd2+, Sm2+, Eu2+, Gd2+, Tb2+, Db2+, Tm2+, Yb2+, and La2+, including any complexes which contain the metal ions, as well as any corresponding metal salt counter-anions. 10. The MOF of claim 1, wherein the plurality of SBUs comprise one or more divalent metal ions selected from: Mg2+, Ca2+, Sr2+, Mn2+, Fe2+, Co2+, Ni2+, and Zn2+, including any complexes which contain the metal ions, as well as any corresponding metal salt counter-anions. 11. The MOF of claim 1, wherein the plurality of SBUs all have the same topology. 12. The MOF of claim 1, wherein the MOF comprises an M2M-MOF-74, and M4M-MOF-74, and M6M-MOF-74, and M8M-MOF-74 or an M10M-MOF-74. 13. A device comprising a MOF of claim 1. 14. A method of separating one or more gases from a gas mixture comprising contacting the gas mixture with a MOF of claim 1. 15. A method of catalyzing the formation of one or more products from one or more reactants by using a one-pot co-catalyst system that comprises contacting the one or more reactants with a MOF of claim 1.
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