Systems chemistry approach to polyhexahydrotriazine polymeric structures
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
C08G-073/00
C08L-079/00
C08G-073/06
C07D-207/452
C08L-079/04
C08L-063/04
C08L-063/00
C08G-073/10
출원번호
US-0460785
(2017-03-16)
등록번호
US-10118993
(2018-11-06)
발명자
/ 주소
Boday, Dylan J.
Fevre, Mareva B.
Garcia, Jeannette M.
Hedrick, James L.
Wojtecki, Rudy J.
출원인 / 주소
International Business Machines Corporation
대리인 / 주소
Patterson + Sheridan, LLP
인용정보
피인용 횟수 :
0인용 특허 :
22
초록
In some embodiments, a product, such as a thermoset, has a polyhexahydrotriazine and a self-polymerized cross-linkable polymer. In some embodiments, a product is the reaction product of a diamine, an aldehyde, and a compound having an α,β-unsaturated electron withdrawing moiety.
대표청구항▼
1. A product that is the reaction product of: a diamine;an aldehyde; anda compound having an α,β-unsaturated electron withdrawing moiety. 2. The product of claim 1, wherein the aldehyde is paraformaldehyde. 3. The product of claim 1, wherein the compound having an α,β-unsaturated electron withdrawin
1. A product that is the reaction product of: a diamine;an aldehyde; anda compound having an α,β-unsaturated electron withdrawing moiety. 2. The product of claim 1, wherein the aldehyde is paraformaldehyde. 3. The product of claim 1, wherein the compound having an α,β-unsaturated electron withdrawing moiety is wherein R is selected from the group consisting of ether, aryl, and alkyl. 4. The product of claim 3, wherein the ether is the aryl is and the alkyl is 5. The product of claim 1, wherein the diamine is of the structure: NH2—X—NH2, wherein X is selected from the group consisting of a phosphine derivative, an ether, and a lactone. 6. The product of claim 5, wherein the phosphine derivative is the ether is and the lactone is 7. The product of claim 1, wherein the product comprises a polyhexahydrotriazine including the structure: wherein each instance of X is independently a phosphine derivative, ether, or lactone. 8. The product of claim 7, wherein the product further comprises: the structure wherein R is selected from the group consisting of an ether, an aryl group, and an alkyl group, wherein X is selected from the group consisting of a phosphine, an ether, and a lactone, and wherein n is a positive integer. 9. The composition of claim 8, wherein R is selected from the group consisting of ether of structure aryl of structure and alkyl of structure: 10. The composition of claim 9, wherein n is a positive integer from between about 2 to about 500. 11. The composition of claim 8, wherein R is ether. 12. The composition of claim 8, wherein R is aryl. 13. The composition of claim 8, wherein R is alkyl. 14. The product of claim 7, wherein the product further comprises: the structure wherein R is selected from the group consisting of ether, aryl, and alkyl, and wherein n is a positive integer. 15. The composition of claim 14, wherein R is selected from the group consisting of ether of structure aryl of structure and alkyl of structure: 16. The composition of claim 15, wherein n is a positive integer from between about 2 to about 500. 17. The composition of claim 14, wherein R is ether. 18. The composition of claim 14, wherein R is aryl. 19. The composition of claim 14, wherein R is alkyl. 20. The product of claim 1, wherein the product comprises: the structure wherein R is selected from the group consisting of an ether, an aryl group, and an alkyl group, wherein X is selected from the group consisting of a phosphine, an ether, and a lactone, and wherein n is a positive integer.
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