$\require{mediawiki-texvc}$

연합인증

연합인증 가입 기관의 연구자들은 소속기관의 인증정보(ID와 암호)를 이용해 다른 대학, 연구기관, 서비스 공급자의 다양한 온라인 자원과 연구 데이터를 이용할 수 있습니다.

이는 여행자가 자국에서 발행 받은 여권으로 세계 각국을 자유롭게 여행할 수 있는 것과 같습니다.

연합인증으로 이용이 가능한 서비스는 NTIS, DataON, Edison, Kafe, Webinar 등이 있습니다.

한번의 인증절차만으로 연합인증 가입 서비스에 추가 로그인 없이 이용이 가능합니다.

다만, 연합인증을 위해서는 최초 1회만 인증 절차가 필요합니다. (회원이 아닐 경우 회원 가입이 필요합니다.)

연합인증 절차는 다음과 같습니다.

최초이용시에는
ScienceON에 로그인 → 연합인증 서비스 접속 → 로그인 (본인 확인 또는 회원가입) → 서비스 이용

그 이후에는
ScienceON 로그인 → 연합인증 서비스 접속 → 서비스 이용

연합인증을 활용하시면 KISTI가 제공하는 다양한 서비스를 편리하게 이용하실 수 있습니다.

2차(次) 자원(資源)으로부터 습식방법(濕式方法)에 의한 인듐의 회수(回收)
Recovery of Indium from Secondary Resources by Hydrometallurgical Method 원문보기

資源리싸이클링 = Journal of the Korean Institute of Resources Recycling, v.22 no.2, 2013년, pp.3 - 10  

왕능운 (목포대학교 공과대학 신소재공학과) ,  이만승 (목포대학교 공과대학 신소재공학과)

초록
AI-Helper 아이콘AI-Helper

인듐희유금속으로 주로 ITO제조에 사용된다. 본 총설에서는 인듐을 함유한 2차자원을 침출한 용액으로부터 인듐을 분리하기 위한 용매추출, 이온교환 및 석출법에 대한 공정 조건 및 장단점을 조사했다. 보통 정도의 산성용액에서 인듐의 추출제로 D2EHPA가 가장 많이 사용되고 있으며, 매우 강한 염산용액에서는 아민계 추출제가 사용된다. 일반적으로 이온교환수지의 인듐 흡착량이 낮으므로, 인듐의 농도가 낮은 경우에 한해 이온교환은 용매추출보다 장점이 있다.

Abstract AI-Helper 아이콘AI-Helper

Indium is one of the rare metals, and it has been used mainly for preparation of indium tin oxide (ITO). This review investigated the process parameters and the merits and demerits of several methods to recover indium from the leaching solution of secondary resources, such as solvent extraction, ion...

주제어

참고문헌 (52)

  1. Alfantazi, A.M., Moskalyk, R.R., 2003: Processing of indium: a review, Minerals Engineering, 16, pp. 687-694. 

  2. Ullmann, et al., 2001: Ullmann's Encyclopaedia of Industrial Chemistry 6th ed, Volume 19 Indium and Indium Compounds, pp. 65-74, Wiley-VCH, Weinheim, Germany. 

  3. Wikipedia, General internet address, General internet address: http://en.wikipedia.org/wiki/Indium (accessed on September 2012). 

  4. Fact sheet: Indium, Polinares working paper n.39, March 2012, pp.1-6. General internet address: http://www.polinares.eu/docs/d2-1/polinares_wp2_annex2_factsheet5_v1_10.pdf (accessed on September 2012). 

  5. Tolcin, A.C., 2012: Mineral Commodity Summaries, U.S.Geological Survey, January 2012, pp. 74-75. 

  6. Micheal, W. G., 2005: Mineral Commodity Summaries, U.S.Geological Survey, January 2005, pp. 80-81. 

  7. Schampera, U.S., Herzig, P.M., Indium: Geology, Mineralogy, and Economics, Springer, Berlin, 2002, p2. 

  8. Li, C.X., Chang, W., Xu, H.S., Deng, Z.G., Liao, J.Q., Li, X.B., Li, M.T., 2010: Kinetics of indium dissolution from sphalerite concentrate in pressure acid leaching, Hydrometallurgy, 105(2010), pp. 172-175. 

  9. Li, S.Q., Tang, M.T., He, J., Yang, S.H., Tang, C.B., Chen, Y.M., 2006: Extraction of indium from indium-zinc concentrates, Trans. Nonferrous Met. SOC. China, 16(2006), pp. 1448-1454. 

  10. Li, C.X., Wei, C., Xu, H.S., Li, M.T., Li, X.B., Deng, Z.G., Fan, G., 2012: Oxidative pressure leaching of sphalerite concentrate with high indium and iron content in sulfuric acid medium, Hydrometallurgy, 102(2010), pp. 91-94. 

  11. Sinclair, W.D., Kooiman, G.J.A., Martin, D.A., Kjarsgaard, I.M., 2006: Geology, geochemistry and mineralogy of indium resources at Mount Pleasant, New Brunswick, Canada. Ore Geology Reviews 28, pp. 123-145. 

  12. Seifert, T., Sandmann, D., 2006: Mineralogy and geochemistry of indium-bearing polymetallic vein-type deposits: implications for host minerals from the Freiberg district, Eastern Erzgebirge, Germany. Ore Geology Reviews 28, pp. 1-31. 

  13. Murao, S., Deb, M., Furuno, M., 2008: Mineralogical evolution of indium in high grade tinpolymetallic hydrothermal veins - a comparative study from Tosham, Haryana state, India and Goka, Naegi district, Japan. Ore Geology Reviews 33, pp. 490-504. 

  14. Cook, N.J., Ciobanu, C.L., Pring, A., Skinner, W., Shimizu, M., Danyushevsky, L., Saini-Eidukat, B., Melcher, F., 2009: Trace and minor elements in sphalerite: a LA-ICPMS study, Geochimica et Cosmochimi ca Acta 73, pp. 4761-4791. 

  15. Goonan, T.G., 2012: Materials flow of indium in the United States in 2008 and 2009: U.S. Geological Survey Circular 1377, 12 p. http://pubs.usgs.gov/circ/1377/ (accessed on September 2012). 

  16. Tolcin, A.C., 2008: Mineral Commodity Summaries, U.S. Geological Survey, January 2008, pp. 80-81. 

  17. Hammarberg, E., Prodi-Schwab, A., Feldmann, C., 2008: Microwave-assisted synthesis of indium tin oxide nano-crystals in polyol media and transparent, conductive layers thereof, Thin Solid Films, 516(21), pp. 7437-7442. 

  18. Jeon, M.K., Kang, M., 2008: Synthesis and characterization of indium-tin-oxide particles prepared using sol?gel and solvothermal methods and their conductivities after fixation on polyethyleneterephthalate films, Materials Letters, 62(4-5), pp. 676-682. 

  19. Li, Y.H., Liu, Z.H., Li, Q.H., Liu, Z.Y., Zeng, L., 2011: Recovery of indium from used indium - tin oxide (ITO) targets, Hydrometallurgy, 105, pp. 207-212. 

  20. Kang, H. N., Lee, J.Y., Kim, J.Y., 2011: Recovery of indium from etching waste by solvent extraction and electrolytic refining, Hydrometallurgy, 110(2011), pp. 120-127. 

  21. Barakat, M.A., 1998: Recovery of lead, tin and indium from alloy wire scrap, Hydrometallurgy, 49(1998), pp. 63-73. 

  22. Sami, V., Don, I., Erkki, P., 2011: Recovery of indium from indium tin oxide by solvent extraction, Hydrometallurgy, 107, pp. 56-61. 

  23. Fortes, M.C.B., Benedetto, J. S., 1998: Technical note separation of indium and iron by solvent extraction, Mincruls Engineering. Vol. II, No. 5, pp. 447-451. 

  24. Paiva, A.P. 2001: Recovery of indium from aqueous solutions by solvent extraction, Separation science and technology, 36(7), pp. 1395-1419. 

  25. Tomii, K., Tsuchida, H., 1981: Solvent extraction recovery process for indium, U.S. Patent 4292284. 

  26. Ke, J., Qiu, R., Chen, C., 1984: Recover y of metal values from copper smelter flue dust, Hydrometallurgy, 12, pp. 217-224. 

  27. Fossi, P., Sambarino, E., 1983: Process for the Recovery of Indium, U.S. Patent 4372922. 

  28. Sato, T., Sato, K., 1992: Liquid-liquidextraction of indium (III) from aqueousacid solutions by acid organophosphorus compounds, Hydrometallurgy, 30(1992), pp. 367-383. 

  29. Sato, T., 1975: The extraction of indium(III), lanthanum(III) and bismuth(III) from sulphuric acid solutions by di-(2-ethylhexyl)-phosphoric acid, J. Inorg. Nucl. Chem., 37, pp. 1485-1488. 

  30. Nikov, B., Stojanov, P., Stojadinovic, T., 1994: Production of indium from imperial smelting process residues. Proceedings of Hydrometallurgy '94. Chapman and Hall, Cambridge, pp. 1153-1164. 

  31. Bina, G., Niti, M., Indu, S., 2007: Separations and recovery of indium and gallium using bis(2,4,4-trimethylpentyl) phosphinic acid (Cyanex272), Separation and Purification Technology, 57(2007), pp. 294-303. 

  32. Alguacil, F.J., 1999: Solvent extraction of indium(III) by LIX 973N, Hydrometallurgy, 51, pp. 97-102. 

  33. Navratil, O., Meindl, J., Kos, J., 1981: Extraction of indium(III) and antimony(III) from hydrochloric acid solutions by means of some neutral organophosphorus reagents, Coll. Czech. Chem. Commun., 46, pp. 1906-1912. 

  34. Seo, J.S., Ahn, J.W., Lee, M.S., 2010: Solvent extraction of Sn(IV) from Hydrochloric Acid Solution by Tri-Butyl Phosphate(TBP), J. of Korean Inst. of Resources Recycling, 19, pp. 45-51. 

  35. Sato, T., Yasumura, H., Mizuno, Y., T. Nishimura, T, 1996: Solvent extraction of trivalent gallium, indium and thallium from hydrochloric acid solutions by TOPO and TB, Proceedings of the International Solvent Extraction Conference, ISEC '96, Shallcross, D. C., Paimin, R., Prvcic, L. M. (Eds.), Univ. Melbourne, Vol. 1, pp. 559-564. 

  36. Golinski, M., 1971: Extraction of tin and indium with tributylphosphate from hydrochloric acid solutions. Proceedings of the International Solvent Extraction Conference, ISEC'71, London, pp. 603-615. 

  37. De, A. K., Sen, A. K., 1967: Solvent extraction and separation of gallium(III), indium(III) and thallium(III) with tributylphosphate, Talanta, 14, pp. 629-635. 

  38. Bao, C.; Li, D.; Chou, J. 1987: Extraction of indium with trioctylphosphine oxide (TOPO). Wuji Huaxue, 1987, 3(1), pp. 16-21. 

  39. Hasegawa, Y.; Shimada, T., 1980: Niitsu, M. Solvent extraction of 3B group metal ions from hydrochloric acid with trioctylphosphine oxide. J. Inorg. Nucl. Chem., 42, pp. 1487-1489. 

  40. Aguilar, M., 1975: Extraction with long-chain amines. XX. Extraction of indium(III) chloride by tri-n-octylammonium chloride dissolved in benzene, Chem. Scripta, 1975 8(1), pp. 37-42. 

  41. Fischer, C., Wagner, H., Bagreev, V. V., Stojanov, E. S, 1977: On the extraction of In(III) with tri-n-octylamine from HCl solutions, J. Inorg. Nucl. Chem., 1977, 39, pp. 513-517. 

  42. Nelson, A.D., Fasching, J.L., Mcdonald, R.L., 1965: Extraction of Fe(III) and In(III) from aqueous HCl by trin-octylamine in nitrobenzene, J. Inorg. Nucl. Chem., 1965, 27, pp. 439-447. 

  43. Karve, Ms. M. A.; Khopkar, S. M., 1992: Solvent extraction separation of indium with quaternary ammonium anion exchanger Aliquat 336S from an ascorbate solution, Analytical Science, v. 8, pp. 77-80. 

  44. Kuchekar, S. R., Chavan, M. B., 1988: Separation of gallium, indium and thallium by extraction with n-octylaniline in chloroform, Talanta, v. 35, 5, pp. 357-360. 

  45. Mahamuni, S.V., Kolekar, S.S., Wadgaonkar, P.P., Anuse M.A., 2009: Solvent Extraction of Trivalent Indium from Succinate Solution by 2-Octylaminopyridine in Chloroform, J. Iran. Chem. Soc., Vol. 6, No. 1, pp. 200-212. 

  46. Shilmkar, T.N., Kolekar, S.S., Wadgaonkar, P.P., 2008: Rapid extraction and separation of indium(III) with a high molecular weight amine, Indian Journal of Chemical Technology Vol. 15, May 2008, pp. 291-297. 

  47. Marinho, R.S., Silva, C.N., Afonso, J.C., Cunha, J.W., 2011: Recovery of platinum, tin and indium from spent catalysts in chloride medium using strong basic anion exchange resins, Journal of Hazardous Materials, 192 (2011), pp. 1155-1160. 

  48. Fortes, M.C.B., Martins, A.H., Benedetto, J.S., 2003: Indium adsorption onto ion exchange polymeric resins, Minerals Engineering, 16(2003), pp. 659-663. 

  49. Chung, Y.H., Lee, C.W., 2012: Electrochemical behaviors of Indium, Journal of Electrochemical Science and Technology, Vol. 3, pp. 1-13. 

  50. Han, K.N., Siddartha, K., Park, K.W., Kang, H.M., 2002: Recovery of Indium from Indium/Tin Oxides Scrap by Chemical Precipitation, Geosystem Eng., 5(4), pp. 93-98. 

  51. Koleini, S.M., Mehrpouya, H., Saberyan, K., Abdolahi, M., 2010: Extraction of indium from zinc plant residues, Minerals Engineering, 23(2010), pp. 51-53. 

  52. Jiang, J.B., Liang, D.Q., Zhong, Q.D., 2011: Precipitation of indium using sodium tripolyphosphat, Hydrometallurgy, 106(2011), pp. 165-169. 

저자의 다른 논문 :

LOADING...

관련 콘텐츠

오픈액세스(OA) 유형

저작권 관리 안내
섹션별 컨텐츠 바로가기

AI-Helper ※ AI-Helper는 오픈소스 모델을 사용합니다.

AI-Helper 아이콘
AI-Helper
안녕하세요, AI-Helper입니다. 좌측 "선택된 텍스트"에서 텍스트를 선택하여 요약, 번역, 용어설명을 실행하세요.
※ AI-Helper는 부적절한 답변을 할 수 있습니다.

선택된 텍스트

맨위로