[논문]스테인레스 강의 수전해 전극 응용기술 동향

김문수; 하재윤; 김용태; 최진섭

doi:10.5229/jkes.2021.24.2.13

스테인레스 강의 수전해 전극 응용기술 동향
Technology Trends in Stainless Steel for Water Splitting Application 원문보기

전기화학회지 = Journal of the Korean Electrochemical Society, v.24 no.2, 2021년, pp.13 - 27

김문수 (인하대학교 화학.화학공학 융합학과) , 하재윤 (인하대학교 화학.화학공학 융합학과) , 김용태 (인하대학교 화학.화학공학 융합학과) , 최진섭 (인하대학교 화학.화학공학 융합학과)

초록
AI-Helper

스테인레스 강은 지구상에서 가장 널리 사용되고 있는 철의 합금으로 니켈과 크롬을 포함하여 높은 내부식성을 가지고 있어 구조용 강재로 사용하기 매우 적합하다. 또한, 최근에는 스테인레스 강에 포함된 철과 니켈의 고유 특성을 이용하여 다양한 고기능성 촉매나 지지체, 또는 전극의 집전체 등으로의 응용 연구가 다양하게 이루어지고 있다. 특히, 높은 촉매 특성으로 인해 수전해 전극으로의 응용을 위한 스테인레스 강의 표면에서의 활성화 표면 처리 연구가 많이 이루어지고 있다. 이에 본 총설은 수전해 전극 응용을 위한 스테인레스 강의 수전해 전극 응용 표면처리 기술 자료를 정리 및 요약하였으며, 스테인레스 강의 표면처리 방법에 대한 특징 및 이를 통해 스테인레스 강이 저비용 고효율의 수전해 전극 활용을 위한 촉매 물질로써 응용될 수 있는 여러 방법을 제시하였다.

Abstract ▼ AI-Helper

Stainless steel, which includes Ni and Cr with Fe balance, is most often applied for a wide range of applications such as structure and equipment material. It is not only suitable for use in these applications due to its good corrosion resistance, but also can be applied to catalyst, supporting material, and current collector due to intrinsic properties of Ni and Fe contained in stainless steel. Therefore, in recent years, a lots of surface treatment methods have been studied to activate stainless steel, developing application of water splitting system. In this review paper, the research on the surface treatment technology of stainless steel for water splitting is summarized. It is expected to be able to propose the diverse surface treatment approaches of stainless steel for application to low-cost and highly efficient water splitting electrode.

주제어

표/그림 (14)

표 Table 1. Overview of chemical composition of stainless steel types.
그림 Fig. 1. Ohmic resistance-uncorrected cyclic voltammetry of SS scrubber for (a) HER and (b) OER polarization in 1 M KOH. (c) Ohmic resistance-corrected linear sweep voltammetry of SS scrubber and Pt/C/CFP for HER polarization and (d) those of SS scrubber, Ni(OH)₂/CFP, and RuO₂/CFP for OER polarization in 1 M KOH at scan rate of 5 mV s⁻¹. Reprinted with permission from ref. 32. Copyright 2018 American Chemical Society.
그림 Fig. 2. HER activity of SS-304, and SS-304-Ox-ECA by linear sweep voltammetry with ohmic compensation. Reprinted with permission from ref. 33. Copyright 2018 American Chemical Society.
표 Table 2. Comparison of relative cost of the materials.³²⁾
그림 Fig. 3. (a) Top-view SEM image of NASS316L (a cross sectional view is shown as inlet), (b) energy dispersive spectroscopy (EDS) spectra for sample a (SS316L) and b (NASS316L), and (c) XRD pattern of NASS316L. Reprinted with permission from ref. 34. Copyright 2018 American Chemical Society.
그림 Fig. 4. (a) The dependence of the electrocatalytic oxygen evolution properties of the Ni : Fe relation using Fe and the other FeNi alloys. Blue arrows indicate the overpotential value for each sample. (b) A comparison of cyclic voltammetry of Elox300 and SS304. (c) Tafel plot of Elox300 in 5 M KOH. (d) Illustration of the enrichment of nickel on the surface of electro-oxidized SS304 steel under harsh conditions. Published by The Royal Society of Chemistry.³⁶⁾
표 Table 3. Comparing composition of SS, HA-60, and HA-300.³⁷⁾
그림 Fig. 5. Top-view SEM images of (a) Bare-SS, (b) HA-60, (c) HA-300. (d) XRD patterns, (e) linear sweep voltammetry curves, (f) corresponding Tafel slopes, and (g) EIS shown as Nyquist plots for the samples. All the electrochemical measurements were carried out with 1 M KOH. Reprinted with permission from ref 37. Copyright 2020 Elsevier.
그림 Fig. 6. (a) Time-current density curve of general anodizing process. (b) – (e) Schematic illustration of anodizing process with fluoride ion, generally represented by Ti anodization. Reproduced by permission of The Royal Society of Chemistry.³⁸⁾
그림 Fig. 7. TEM images and EDS-mapping of (a) and (b) EASS-air; (c) and (d) EASS-Ar/H₂. Reprinted with permission from ref 38. Copyright 2020 Elsevier.
그림 Fig. 8. (a) polarization curves of ESS, EASS-air, and EASS-Ar/H₂, (b) polarization curves of EASS-Ar/H₂ before and after linear sweep voltammetry for 10,000 cycles. (c) Long-term stability test as measured by chronopotentiometry for 24 h at 10 mA cm⁻². All the electrochemical measurement were carried out with 1 M KOH. Reprinted with permission from ref 38. Copyright 2020 Elsevier.
그림 Fig. 9. XPS spectrums of EASS-Ar/H₂ by different number of operating cycle. (a) Ni2p, (b) O1s, (c) Fe2p, and (d) Cr2p. Reprinted with permission from ref 38. Copyright 2020 Elsevier.
그림 Fig. 10. The results of TEM-EDS mapping for IRNTs. Ti, Ru, and Ir are marked as blue (b), red (c), and green (d) spots, respectively. (e) and (f) The results for OER activity, where f is a high magnification of e near overpotential region. Reprinted with permission from ref 53. Copyright 2017 Elsevier.
그림 Fig. 11. (a) Linear relation between anodizing voltage and atomic % concentration of tungsten. EDS mapping images of tungsten incorporated anodic film on the stainless steel anodized at 60 V, (b) W–M, (c) Fe–K, (d) O–K, respectively. Reprinted with permission from ref 44. Copyright 2020 The Korean Institute of Surface Engineering.

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저자의 다른 논문 :

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