[논문]SCAPS-1D 시뮬레이션을 이용한 n-i-p 구조 페로브스카이트 태양전지의 열적 열화 원인 분석

김성탁; 배수현; 정영훈; 한동운; 김동환; 모찬빈

doi:10.21218/cpr.2022.10.1.016

SCAPS-1D 시뮬레이션을 이용한 n-i-p 구조 페로브스카이트 태양전지의 열적 열화 원인 분석
Numerical Analysis on Thermal-Induced Degradation of n-i-p Structure Perovskite Solar Cells Using SCAPS-1D 원문보기

Current photovoltaic research = 한국태양광발전학회논문지, v.10 no.1, 2022년, pp.16 - 22

김성탁 (강원본부 기능성소재부품연구그룹, 한국생산기술연구원) , 배수현 (태양광연구단, 한국에너지기술연구원) , 정영훈 (강원본부 기능성소재부품연구그룹, 한국생산기술연구원) , 한동운 (강원본부 기능성소재부품연구그룹, 한국생산기술연구원) , 김동환 (신소재공학과, 고려대학교) , 모찬빈 (강원본부 기능성소재부품연구그룹, 한국생산기술연구원)

Abstract ▼ AI-Helper

The long-term stability of PSCs against visual and UV light, moisture, electrical bias and high temperature is an important issue for commercialization. In particular, since the operation temperature of solar cell can rise above 85℃, a study on thermal stability is required. In this study, the cause of thermal-induced degradation of PSCs was investigated using the SCAPS-1D simulation tool. First, PSCs of TiO2/CH3NH3PbI3/Spiro-OMeTAD/Au structure were exposed to a constant temperature of 85℃ to observe changes in conversion efficiency and quantum efficiency. Because the EQE reduction above 500 nm was remarkable, we simulated PSCs performance as a function of lifetime, doping density of perovskite and spiro-OMeTAD. Consequently, the main cause of thermal-induced degradation is considered to be the change in the perovskite doping concentration and lifetime due to ion migration of perovskite.

주제어

표/그림 (9)

그림 Fig. 1. (a) Structure of the MAPbI₃ PSC, (b) PSC architecture for SCAPS-1D
그림 Fig. 2. (a) Normalized Voc and Jsc, (b) Normalized FF and PCE, (c) EQE curve of as-prepapared and after thermal stress PSCs
표 Table 1. Parameters used for simulation of PSCs
표 Table 2. Comparision between experimental and simulated results of PSCs
그림 Fig. 3. I-V and EQE results with acceptor density of PVSK, (a) I-V curve, (b) EQE curve, (c) V_oc, (d) J_sc, (e) FF, (f) PCE
그림 Fig. 4. I-V and EQE results with donor density of PVSK, (a) I-V curve, (b) EQE curve, (c) V_oc, (d) J_sc, (e) FF, (f) PCE
그림 Fig. 5. Energy band, generation/recombination rate with acceptor density (a,b) and donor density (c,d) of PVSK
그림 Fig. 6. I-V parameters with PVSK lifetime (a) V_oc, (b) J_sc, (c) FF, (d) PCE, (e) EQE curve
그림 Fig. 7. I-V parameters with doping density of Spiro-OMeTAD (a) Voc, (b) Jsc, (c) FF, (d) PCE

참고문헌 (21)

Kojima, A., Techima, K., Shirai, Y., Miyasaka, T., "Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells," Journal of the American Chenical Society, 131(17), 6050-6051 (2009).

상세보기
"NREL Best Research-Cell Efficiencies", https://www.nrel.gov/pv/assets/pdfs/best-research-cell-efficiencies-rev211117. pdf (accessed:November, 2021).
Wang, Y., Zhang, Y., Zhang, P., Zhang, W., "High intrinsic carrier mobility and photon absorption in the perovskite CH 3 NH 3 PbI 3 ," Physical Chemistry Chemical Physics, 17(17), 11516-11520 (2015).

상세보기
Levine, I., Gupta, S., Brenner, T. M., Azulay, D., Millo, O., Hodes, G., Cahen, D., Balberg, I., "Mobility-Lifetime Products in MAPbI3 Films," The Journal of Physical Chemistry Letters, 7(24), 5219-5226 (2016).

상세보기
Jeon, N. J., Noh, J. H., Yang, W. S., Kim, Y. C., Ryu, S., Seo, J., Seok, S. I., "Compositional engineering of perovskite materials for high-performance solar cells," Nature, 517, 476-480 (2015).

상세보기
Peleg, R., "HZB sets new 29.8% effciency record for perovskitesilicon tandem solar cells," https://www.perovskite-info.com/hzb-sets-new-298-efficiency-record-perovskite-silicon-tandem-solar-cells (November, 2021).
VDMA, "International Technology Roadmap for Photovoltaic (ITRPV)," 12th edition (2021).
Lang, F., Shargaieva, O., Brus, V. V., Neitzert, H. C., Rappich, J., Nickel, N. H., "Influence of radiation on the properties and the stability of hybrid perovskites," Advanced Materials, 30, 1702905 (2017).

상세보기
Lee, S.-W., Kim, S., Bae, S., Cho, K., Chung, T., Mundt, L. E., Lee, S., Park, S., Park, H., Schubert, M. C., Glunz, S. W., Ko, Y., Jun, Y., Kang, Y., Lee, H.-S., Kim, D., "UV degradation and recovery of perovskite solar cells," Scientific Reports, 6, 38150 (2016).

상세보기
Kim, N.-K., Min, Y. H., Noh, S., Cho, E., Jeong, G., Joo, M., Ahn, S.-W., Lee, J. S., Kim, S., Ihm, K., Ahn, H., Kang, Y., Lee, H.-S., Kim, D., "Investigation of thermally induced degradation in CH3NH3PbI3 perovskite solar cells using in-situ synchrotron radiation analysis," Scientific Reports, 7, 4645 (2017).

상세보기
Yang, J., Siempelkamp, B. D., Liu, D., Kelly, T. L., "Investigation of CH 3 NH 3 PbI 3 degradation rates and mechanisms in controlled humidity environments using in situ techniques," ACS Nano, 9, 1955-1963 (2015).

상세보기
Bae, S., Kim, S., Lee, S.-W., Cho, K., Park, S., Lee, S., Kang, Y., Lee, H.-S., Kim, D., "Electric-field-induced degradation of methylammonium lead iodide perovskite solar cells," Journal of Physics and chemistry letters, 7, 3091-3096 (2016).

상세보기
Abdelaziz, S., Zekry, A., Shaker, A., Abouelatta, M., "Investigating the performance of formamidinium tin-based perovskite solar cell by SCAPS device simulation," Optical Materials, 101, 109738 (2020).

상세보기
Abnavi, H., Maram, D. K., Abnavi, A., "Performance analysis of several electron/hole transport layers in thin film MAPbI 3 -based perovskite solar cells: A simulation study," Optical Materials, 118, 111258 (2021).

상세보기
Ouslimane, T., Et-taya, L., Elmaimouni, L., Benami, A., "Impact of absorber layer thickness, defect density, and operating temperature on the performance of MAPbI3 solar cells based on ZnO electron transporting material," Heliyon, 7, e06379 (2021).

상세보기
Kim, S., Bae, S., Lee, S.-W., Cho, K., Lee, K. D., Kim, H., Park, S., Kwon, G., Ahn, S.-W., Lee, H.-M., Kang, Y., Lee, H.-S., Kim, D., "Relationship between ion migration and interfacial degradation of CH 3 NH 3 PbI 3 perovskite solar cells under thermal conditions," Scientific Reports, 7, 1200 (2017).

상세보기
Burgelman, M., Nollet, P., Degrave, S., "Modelling polycrystalline semiconductor solar cells," Thin Solid Films, 361-362, 527-532 (2000).

상세보기
Pierret, R., "Semiconductor device fundamentals," 209, AddisonWesley (1996).
Marinova, N., Tress, W., Humphry-Baker, R., Dar, M. I., Bojinov, V., Zakeeruddin, S. M., Nazeeruddin, M. K., Gratzel, M., "Light harvesting and charge recombination in CH 3 NH 3 PbI 3 perovskite solar cells studied by hole transport layer thickness variation," ACS Nano, 9, 4200-9 (2015).

상세보기
Tammireddy, S., Reichert, S., An, Q., Taylor, A. D., Paulus, F., Vaynzof, Y., Deibel, C., "Temperature-dependent ionic conductivity and properties of iodine-related defects in metal halide peorvskites," ACS Energy Letters, 7, 310-319 (2022).

상세보기
Yin, W.-J., Shi, T., Yan, Y., "Unusual defect physics in CH3NH3PbI3 perovskite solar cell absorber," Applied Physics Letters, 104, 063903 (2014).

상세보기

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