[논문]가스 흡착 및 분리공정용 활성탄소와 탄소분자체의 제조 및 응용

정서경; 하성민; 이영석

doi:10.14478/ace.2022.1092

가스 흡착 및 분리공정용 활성탄소와 탄소분자체의 제조 및 응용
Manufacturing and Application of Activated Carbon and Carbon Molecular Sieves in Gas Adsorption and Separation Processes 원문보기

공업화학 = Applied chemistry for engineering, v.33 no.5, 2022년, pp.488 - 495

정서경 (충남대학교 응용화학공학과) , 하성민 (충남대학교 응용화학공학과) , 이영석 (충남대학교 응용화학공학과)

초록
AI-Helper

온실가스의 회수 및 분리를 위한 다공성 물질로 활성탄소와 탄소분자체가 주목을 받아왔다. 균일한 기공을 가지는 탄소분자체는 특정 가스를 선택적으로 흡착할 수 있기 때문에 가스의 포집 및 분리에 사용되고 있다. 탄소분자체의 성능은 세공의 크기 및 균일성에 따라 좌우되는데, 이러한 탄소분자체의 미세 기공 제어를 위하여 표면을 일정한 두께로 코팅할 수 있는 화학기상증착법이 널리 사용 되고 있다. 이 화학기상증착법은 탄소분자체 제조 시 기공의 크기를 제어하는데 사용될 수 있으나, 그 실험 변수가 다양하기 때문에 이에 대한 최적화가 필요하다. 따라서, 본 총설에서는 가스 흡착 및 분리공정용 활성탄소와 탄소분자체를 제조하기 위하여 여러 가지 활성화 공정, 화학기상증착법과 표면처리 등에 의한 기공 제어 기술들을 중심으로 다루고자 한다.

Abstract ▼ AI-Helper

Activated carbon (AC) and carbon molecular sieve (CMS) have attracted attention as porous materials for recovery and separation of greenhouse gases. The carbon molecular sieve having uniform pores is used for collecting and separating gases because it may selectively adsorb a specific gas. The size and uniformity of pores determine the performance of the CMS, and chemical vapor deposition (CVD) is widely used to coat the surface with a predetermined thickness in order to control the CMS's micropores. This CVD method can be used to control the size of pores in CMS manufacturing, but it must be optimized because of its various experimental variables. Therefore, in order to produce AC and CMS for gas adsorption and separation, this review focuses on various activation processes and pore control technologies by CVD and surface treatment.

주제어

표/그림 (9)

그림 Figure 1. Schematic diagram of pressure swing adsorption system[47].
그림 Figure 2. Schematic diagram of gas separation and adsorption of CMS.
그림 Figure 3. Schematic diagram of physical activation and chemical activation.
표 Table 1. Comparison of Adsorbents Used in PSA Process
그림 Figure 4. Schematic diagram of thermal CVD.
그림 Figure 5. Pore size control Schematic by CVD treatment.
표 Table 2. Comparison of Deposition Conditions and Surface Properties of CMS
표 Table 3. Surface Characteristics of CMS according to CVD Deposition Temperature and Amount of C₆H₆ Injection
표 Table 4. Gas Adsorption and Separation Capacity of Element-doped CMS

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표제어: PCR

동의어: Packet Collision Rate

용어 설명 출처 목록 (6)

용어 설명: PCR은 세균 특이성이 있는 primer를 이용하여 적은 수의 세균이 있을지라도 쉽게 검출할 수 있는 유용한 방법이며, 이를 이용하여 구강 내 치면세균막이나 타액에서 직접 세균을 검출할 수 있게 되었다[8].

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