[논문]하이볼륨 플라이애시 시멘트의 수화도 및 역학적 특성

차수원; 최영철

doi:10.11112/jksmi.2022.26.5.95

하이볼륨 플라이애시 시멘트의 수화도 및 역학적 특성
The Degree of Hydration and Mechanical Properties of High Volume Fly Ash Cement 원문보기

한국구조물진단유지관리공학회 논문집 = Journal of the Korea Institute for Structural Maintenance and Inspection, v.26 no.5, 2022년, pp.95 - 102

차수원 (울산대학교 토목공학과) , 최영철 (가천대학교 토목환경공학과)

초록
AI-Helper

최근, 전세계적으로 온실 가스의 저감에 관심이 높아지면서 건설 산업에서도 FA를 대량 치환하는 HVFAC의 사용을 위한 연구가 수행되고 있다. 시멘트의 수화도와 FA 반응도의 정량적인 측정은 HVFAC의 강도발현 메커니즘을 명확히 이해할 수 있게 한다. FA가 포함된 시멘트 페이스트의 수화 및 포졸란 반응은 매우 복잡하고 수화 생성물의 조성을 정확하게 결정할 수 없으므로 간단한 방법으로 반응도를 설명하는 것은 매우 어렵다. 따라서, 이 연구는 재령에 따른 하이볼륨 FA 시멘트의 수화 특성을 조사하였다. 시멘트의 수화도와 FA의 반응도는 재령에 따른 선택용해법과 페이스트의 비증발 수량을 통해 평가하였다. 또한 HVFA 모르타르 시편을 이용하여 연령에 따른 압축강도를 측정하였다. 실험결과 FA의 치환율이 증가할수록 시멘트의 수화도는 증가하나 FA의 반응성은 감소하는 것으로 나타났다.

Abstract ▼ AI-Helper

Recently, there has been a growing interest in reducing greenhouse gases in all industrial fields. In the construction industry, studies have been conducted for the use of high-volume fly ash concrete to replace cement with fly ash. Quantitative measurements of cement hydration and fly ash reactivity enable a clear understanding of the strength development mechanism of high-volume fly ash concrete. It is very difficult to describe the reactivity in a simple way because the hydration and pozzolanic reactions of cement paste containing fly ash are very complex and the composition of the hydration product cannot be accurately determined. This study investigated the hydration and mechanical properties of high volume fly ash (HVFA) cement according to the substitution rate of fly ash (FA). The hydration degree of cement and the reactivity of FA were evaluated through the selective dissolution method and the non-evaporable water content of the paste according to age. In addition, compressive strength was measured using HVFA mortar specimens according to age. As a result of the experiment, as the substitution rate of fly ash increased, the hydration degree of cement increased, but the reactivity of FA decreased.

주제어

표/그림 (13)

그림 Fig. 1 XRD patterns of OPC and FA
표 Table 1 Chemical compositions and physical properties
그림 Fig. 2 Particle size distributions of OPC and FA
표 Table 2 Mix proportions of specimens
그림 Fig. 3 Penetration results of Vicat needle
그림 Fig. 4 Non-evaporable water contents of specimens
그림 Fig. 5 Residue of paste after acid dissolution
그림 Fig. 6 Reaction degree of FA
그림 Fig. 7 BSE image of reacted FA
그림 Fig. 8 Hydration degree of OPC
그림 Fig. 9 Compressive strength of specimens
그림 Fig. 10 Strength increase of specimens after 7 days
그림 Fig. 11 Compressive strength vs. hydraion degree of binder

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