[논문]암모니아의 특성에 따른 활용 현황과 부식 손상에 대한 고찰

이승준

doi:10.5695/jsse.2023.56.2.125

암모니아의 특성에 따른 활용 현황과 부식 손상에 대한 고찰
A Study on the Utilization Status and Corrosion Damage with Ammonia Characteristics 원문보기

한국표면공학회지 = Journal of the Korean institute of surface engineering, v.56 no.2, 2023년, pp.125 - 136

이승준 (군산대학교 ONSE대학 기관공학전공)

Abstract ▼ AI-Helper

Recently, ammonia has emerged as an alternative energy source that can reduce carbon emissions in various industries. Ammonia is used as a fuel in internal combustion engines because it contains no carbon in its components and does not emit any carbon when burned. It is also used in various fields such as fertilizer production, refrigeration, cleaning and disinfection, and drug manufacturing due to its unique characteristics, such as high volatility and easy solubility in water. However, it is highly corrosive to metals and is a toxic gas that can pose a risk to human health, so caution must be exercised when using it. In particular, stress corrosion cracking may occur in containers or manufacturing facilities made of carbon-manganese steel or nickel steel, so special care is needed. As ammonia has emerged as an alternative fuel for reducing carbon emissions, there is a need for a rapid response. Therefore, based on a deep understanding of the causes and mechanisms of ammonia corrosion, it is important to develop new corrosion inhibitors, improve corrosion monitoring and prediction systems, and study corrosion prevention design.

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표/그림 (7)

그림 Fig. 1. A schematic diagram showing methods and materials demanded for ammonia synthesis, separation, and utilization by using renewable energies [8]. Copyright 2021 Wiley Online Library.
그림 Fig. 2. Phasing out coal-fired power plants of IEA NZE 2050 Scenarios [16]. Copyright 2021 Korea Institute of Energy Research.
그림 Fig. 3. Flowchart the proposed methodology and use of tools for the safety, operability, and reliability analysis [35]. Copyright 2008 MPDI.
그림 Fig. 4. Flowsheet of selective recovery of valuable metals (Li, Ni, and Co) from spent LIBs [39]. Copyright 2021 Elsevier.
그림 Fig. 5. Polarization curves of NC Cu and CG Cu measured in 0.3 wt.% ammonia solution [61]. Copyright 2011 Elsevier.
그림 Fig. 6. N 1s XPS spectra after adsorption of NH₃ on the passive film formed on Cr(1 1 0), as a function of increasing exposure to NH3 (pNH₃=20 mbar, 25°C) [70]. Copyright 2002 Elsevier.
표 Table 1. Average amount of oxygen with transport temperature

참고문헌 (83)

P. Dimitriou, R. Javaid, A review of？ammonia as a compression ignition？engine fuel, Int. J. Hydrogen Energy, 45？(2020) 7098-7118.

상세보기
A. Pearson, Refrigeration with ammonia,？Int. J. Refrig., 31 (2008) 545-551.

상세보기
A.A. Lima, G.D. Leite, A.A. Ochoa, C.A.？Santos, J.A. Costa, P.S. Michima, A.M.？Caldas, Absorption refrigeration systems？based on ammonia as refrigerant？using different absorbents: review and？applications, Energies, 14 (2020) 48.
R. K. Dreepaul, A study of alternative？refrigerants for the refrigeration and air？conditioning sector in mauritius, Earth？Environ. Sci., 93 (2017) 012054.
S. J. Benson, C. J. Lennard, P. Maynard,？D. M. Hill, A. S. Andrew, C. Roux,？Forensic analysis of explosives using？isotope ratio mass spectrometry (IRMS)？- discrimination of ammonium nitrate？sources, Sci. Justice., 49 (2009) 73-80.
G. Chehade, I. Dincer, Progress？in green ammonia production as in green ammonia production as？potential carbon-free fuel, Fuel, 299？(2021) 120845.
J. Guo, P. Chen, Catalyst: NH 3 as an？Energy Carrier, Chem., 3 (2017) 709-712.
F. Chang, W. Gao, J. Guo, P. Chen,？Emerging materials and methods？toward ammonia-based energy storage？and conversion, Adv. Mater., 33 (2021)？2005721.
W. S. Chai, Y. Bao, P. Jin, G. Tang, L. Zhou,？A review on ammonia, ammonia-hydrogen and ammonia-methane fuels,？Renewable Sustainable Energy Rev., 147？(2021) 111254.
C. Zou, B. Xiong, X. Huaqing, D. Zheng,？The role of new energy in carbon？neutral, Pet. Explor. Dev., 48 (2021)？411-420.
M. Sonachalam, P. Paulpandian, V.？Manieniyan, Emission reduction in？diesel engine with acetylene gas and？biodiesel using inlet manifold injection,？Clean Technol. Environ. Policy, 22？(2020) 2177-2191.
M. Sonachalam, V. Manieniyan, Impact？of secondary fuel injector in various？distance on direct injection diesel？engine using acetylene-bio diesel？in reactivity controlled compression？ignition mode, Energy Sources Part A？Recovery Util. Environ. Eff., 22 (2020)？1810177.
X. Xu, E. Liu, N. Zhu, F. Liu, F. Qian,？Review of the current status of？ammonia-blended hydrogen fuel engine？development, Energies, 15 (2022) 1023.
M.C. Chiong, H.S. Kang, N.M.R.？Shaharuddin, S. Mat, L.K. Quen, K.H. Ten, M.？C. Ong, Challenges and opportunities？of marine propulsion with alternative？fuels, Renew Sustain. Energy Rev., 149？(2021) 111397.
F.Y.A. Aboosi, M.M.E. Halwagi, M.？Margaux, R.B. Nielsen, Renewable？ammonia as an alternative fuel for the？shipping industry, Curr. Opin. Chem.？Eng., 31 (2021) 100670.
Carbon Free Fuel: Ammonia Policy？and Industry Trends, Korea Institute of？Energy Research Climate Technology？Brief No.42 (2021)
A. Klerke, C.H. Christensen, J.K. Norskov, T.？Vegge, Ammonia for hydrogen storage:？challenges and opportunities, J. Mater.？Chem., 18 (2008) 2304.

상세보기
G. Chehade, I. Dincer, Progress in green？ammonia production as potential？carbon-free fuel, Fuel, 299 (2021)？120845.

상세보기
H. Zhang, L. Wang, J.V. Herle, F. Marechal, U.？Desideri, Techno-economic comparison？of green ammonia production processes,？Appl. Energy, 259 (2020) 114135.

상세보기
A. Sanchez, M. Martin, Optimal renewable？production of ammonia from water and？air, J. Clean. Prod., 178 (2018) 325-342.
A.V. Medina, H. Xiao, M.O. Jones, W. David,？P. Bowen, Ammonia for power, Prog.？Energy Combust. Sci., 69 (2018) 63-102.
O. Siddiqui, I. Dincer, Development？and performance evaluation of a direct？ammonia fuel cell stack, Chem. Eng.？Sci., 200 (2019) 285-293.

상세보기
J. Sun, D. Alam, R. Daiyan, H. Masood,？T. Zhang, R. Zhou, P. J. Cullen, E.？C. Lovell, A. Jalili, R. Amal, A hybrid？plasma electrocatalytic process for？sustainable ammonia production,？Energy Environ. Sci., 14 (2021) 865-872.

상세보기
S. Giddey, S. P. S. Badwal, A. Kulkarni,？Review of electrochemical ammonia？production technologies and materials,？Int. J. Hydrogen Energy, 38 (2013)？14576-14594.

상세보기
H. Shen, C. Choi,J. Masa, X. Li,J. Qiu, Y.Jung, Z. Sun, Electrochemical ammonia synthesis:？mechanistic understanding and catalyst？design, Inside Chem., 7 (2021) 1708-1754.
M. Negovanovic, L. Kricak, S. Milanovic,？D. Nikola, S. Nikola, Ammonium nitrate？explosion hazards, Undergr. Min.？Eng., 27 (2015) 49-63.
X. Vecino, M. Reig, B. Bhushan, O. Gibert,？C. Valderrama, J. Cortina, Liquid fertilizer？production by ammonia recovery from？treated ammonia-rich regenerated？streams using liquid-liquid membrane？contactors, J. Chem. Eng., 360 (2019)？890-899.
M. Montazer, A. Shamei, F. Alimohammadi,？Synthesis of nanosilver on polyamide fabric？using silver/ammonia complex, Mater. Sci.？Eng. C, 38 (2014) 170-176
J. Yang, W. Wang, W. Xiao, Electrochemical？synthesis of ammonia in molten salts,？J. Energy Chem., 43 (2020) 195-207.
A. E. Yuzbasioglu, C. Avsar, A. O.？Gezerman, The current situation in the？use of ammonia as a sustainable energy？source and its industrial potential,？Curr. Opin. Green Sustain. Chem., 5？(2022) 100307.
A. V. Medina, F. A. Hatem, A. K. Azad, I. C.？Dedoussi, M. Joannon, R. X. Fernandes, P.？Glarborg, H. Hashemi, X. He, S. Mashruk,？J. M. Gowan, C. M. Rouselle, A. O. Prado,？A. O. Alera, I. Rossetti, B. Shu, M. Yehia,？H. Xiao, M. Costa, Review on ammonia？as a potential fuel: from synthesis to？economics, Energy Fuels, 35 (2021) 6964-7029.

상세보기
S. Ghavam, M. Vahdati, I. A. G. Wilson,？P. Styring, Sustainable ammonia？production processes, Front. Energy？Res., 9 (2021) 580808
M. Ozturk, I. Dincer, An integrated？system for ammonia production from？renewable hydrogen: a case study, Int. J.？Energy, 46 (2021) 5918-5925.
N. L. Trivyza, M. Cheliotis, E. Boulougouris,？G. Theotokatos, Safety and reliability？analysis of an ammonia-powered fuel-cell system, Safety, 7 (2021) 80.
D. Chang, T. Rhee, K. Nam, K. Chang,？D. Lee, S. Jeong, A study on availability？and safety of new propulsion systems？for LNG carriers, Reliab. Eng. Syst.？Saf., 93 (2008) 1877-1885.

상세보기
V. Radmehr, S. M. J. Koleini, M. R.？Khalesi, M. R. T. Mohammadi, Ammonia？leaching: a new approach of copper？industry in hydrometallurgical？Processes, J. Inst. Eng. (India): D., 94？(2013) 95-104.
A. C. Grosse, G. W. Dicinoski, M. J.？Shaw, P. R. Haddad, Leaching and？recovery of gold using ammoniacal？thiosulfate leach liquors (a review),？Hydrometallurgy, 69 (2003) 1-21.

상세보기
Y. Ma, J. Tang, R. Wanaldi, X. Zhou, H.？Wang, C. Zhou, J. Yang, A promising？selective recovery process of valuable？metals from spent lithium ion batteries？via reduction roasting and ammonia？leaching, J. Hazard. Mater., 402 (2021)？123491.
S. M. Shin, N. H. Kim, J. S. Sohn, D.？H. Yang, Y. H. Kim, Development of？a metal recovery process from Li-ion？battery wastes, Hydrometallurgy, 79？(2005) 172-181.

상세보기
B. Ogilvie, A. S. Leal, J. Lopez, B. Poole,？R. Robison, B. Berges, Alcohol-free？hand sanitizer and other quaternary？ammonium disinfectants quickly and？effectively inactivate SARS-CoV-2, J.？Hosp. Infect., 108 (2021) 142-145.

상세보기
C. P. Gerba, Quaternary ammonium？biocides: efficacy in application, Appl.？Environ. Microbiol., 81 (2015) 02633-14

상세보기
D. Wu, F. Lu, H. Gao, L. Shao, P.？He, Mesophilic bio-liquefaction of？lincomycin manufacturing biowaste:？The influence of total solid content and inoculum to substrate ratio, Bioresour.？Technol., 102 (2011) 5855-5862.

상세보기
M. Montazer, A. Shamei, F. Alimohammadi,？Synthesizing and stabilizing silver？nanoparticles on polyamide fabric？using silver-ammonia/PVP/UVC, Prog.？Org. Coat., 75 (2012) 379-385.

상세보기
C. Loftus, M. Yost, P. Sampson,？E.Torres, G. Arias, V. B. Vasquez, K. Hartin,？J. Armstrong, M. T. French, S. Vedal,？P. Bhatti, C. Karr, Ambient ammonia？exposures in an agricultural community？and pediatric asthma morbidity,？Epidemiol., 26 (2015) 794-801.
T. Li, J. Panther, Y. Qiu, C. Liu, J. Huang,？Y. Wu, P.K. Wong, T. An, S. Zhang, H.Zhao,？Gas-permeable membrane-based？conductivity probe capable of in situ？real-time monitoring of ammonia in？aquatic environments, Environ. Sci.？Technol., 51 (2017) 13265-13273.

상세보기
E. Stokstad, Ammonia pollution from？farming may exact hefty health costs,？Science, 343 (2014) 238.

상세보기
S. J. Zeng, D. W. Shang, M. Yu, H. Chen,？H. Dong, X. Zhang, Applications and？perspectives of NH 3 separation and？recovery with ionic liquids, Chin. J.？Chem. Eng., 70 (2019) 10.
X. Xu, Q. Xu, G. Huang, L. Wang,？L. Huang, Removal of ammonia？by absorption combined with？electrochemical oxidation on RuO 2 /Ti？anode, Chin. J. Chem. Eng., 67 (2016) 7.
S. Dasarathy, R. P. Mookerjee, V.？Rackayova, V. R. Thrane, B. Vairappan, P.？Ott, C. F. Rose, Ammonia toxicity: from？head to toe?, Metab. Brain Dis., 32 (2017)？529-538.

상세보기
K. R. Prasun, B. Arti, K. Bimal, K.？Sarvjeet, R. Chitra, Consequence and risk？assessment: case study of an ammonia？storage facility, Arch. Environ. Sci,？5 (2011) 25-36.
C. Hassan, C. Rosmani, B. Puvaneswaran, A.？Raman, A. A. Mahmood, N. Zalina,？F. C. Hung, N. M. Sulaiman, A.？Puvaneswaran, L. Balasubramaniam,？A case study of consequences analysis？of ammonia transportation by rail from？Gurun to Port Klang in Malaysia using？safety computer Model, J. Saf. Health？Environ. Res., 6 (2009) 1-19.
S. Giddey, S. Badwal, A. Kulkarni,？Review of electrochemical ammonia？production technologies and materials,？Int. J. Hydrog. Energy, 38 (2013) 14576-14594.

상세보기
P. Jha, N. S. Ramgir, P. K. Sharma, N.？Datta, S. Kailasaganapathi, M. Kaur,？S. P. Koiry, V. Saxena, A. K. Chauhan,？A. K. Debnath, Charge transport and？ammonia sensing properties of flexible？polypyrrole nanosheets grown at air-liquid interface, Mater. Chem. Phys., 40？(2013) 300-306.
X. Feng, Methanol-ammonia and the？new energy economy, Chem. Ind. Press,？(2010) 60-62.
D. A. Jones, B. E. Wilde, Corrosion？performance of some metals and alloys？in liquid ammonia, Corrosion, 33 (1977)？46-50.

상세보기
N. Anjana, A. Amarnath, M. Harindranathan？Nair, Toxic hazards of ammonia release？and population vulnerability assessment？using geographical information system,？J. Environ. Manage., 210 (2018) 201-209.

상세보기
D. Strmcnik, M. Gaberscek, B.？Pihlar, D. Kocar, J. Jamnik, Copper？Dissolution in Ammonia Solutions:？Identification of the Mechanism at Low？Overpotentials, J. Electrochem. Soc.,？156 (2009) 3123289.

상세보기
G. Jennings, P. E. Laibinis, Self-assembled monolayers of alkanethiols？on copper provide corrosion resistance？in aqueous environments, Colloids？and Surfaces A: Physicochemical and on copper provide corrosion resistance？in aqueous environments, Colloids Surf.？A Physicochem. Eng. Asp., 116 (1996)？105-114.
Guidelines for Ships Using Ammonia as？Fuels, Korean Register, 2021.
P. Shi, Q. Wang, Y. Xu, W. Luo, Corrosion？behavior of bulk nanocrystalline copper？in ammonia solution, Mater. Lett., 65？(2011) 857-859.

상세보기
E. Pugh, W. Montague, A. Westwood,？Stress-corrosion cracking of copper,？Corros. Sci., 6 (1966) 345-346.

상세보기
H. H. Uhlig, D. J. Duqette, Alleged stress-corrosion cracking of pure Cu, Corros.？Sci., 9 (1969) 557-558.

상세보기
E. Escalante, J. Kruger, Stress corrosion？cracking of pure copper, J. Electrochem.？Soc., 118 (1971) 2408247.

상세보기
F. I. Danilov, V. S. Protsenko, V. O.？Gordiienko, S. C. Kwon, J. Y. Lee, M.？Kim, Nanocrystalline hard chromium？electrodeposition from trivalent？chromium bath containing carbamide？and formic acid: Structure, composition,？electrochemical corrosion behavior,？hardness and wear characteristics of？deposits, Appl. Surf. Sci., 257 (2011)？8048.
H. H. Sheu, M. H. Lin, S. Y. Jian, T. Y.？Hong, K. H. Hou, M. D. Ger, Improve？the mechanical properties and wear？resistance of Cr-C thin films by adding？Al 2 O 3 particles, Surf. Coat. Technol.,？350 (2018) 1036.
A. Liang, Q. Liu, B. Zhang, L. Ni,？J. Zhang, Preparation of crystalline？chromium coating on cu substrate？directly by DC electrodepositing from？wholly environmentally acceptable？Cr(III) electrolyte, Mater. Lett., 119？(2014) 131.

상세보기
K. S. Nam, K. H. Lee, S. C. Kwon, D.？Y. Lee, Y. S. Song, Improved wear and？corrosion resistance of chromium(III)？plating by oxynitrocarburising and？steam oxidation, Mater. Lett., 58 (2004)？3540.

상세보기
O. de Sanctis, L. Gomez, N. Pellegri,？A. Duran, Behaviour in hot ammonia？atmosphere of SiO 2 -coated stainless？steels produced by a sol-gel procedure,？Surf. Coat. Technol., 70 (1995) 251-255.

상세보기
H. Ma, Y. Berthier, P. Marcus, NH 3 ？probing of the surface acidity of？passive films on chromium, Corros. Sci.,？44 (2002) 171-178.

상세보기
G. Bouyssoux, M. Romand, H.？D. Polaschegg, J. T. Calow, XPS and AES？studies of anodic passive films grown？on chromium electrodes in sulphuric？acid baths, J. Electron. Spectrosc. Relat.？Phenom., 11 (1977) 185-196.

상세보기
M. Seo, R. Saito, N. Sato, Ellipsometry？and Auger Analysis of Chromium？Surfaces Passivated in Acidic and Neutral？Aqueous Solutions, J. Electrochem.？Soc., 127 (1980) 1909.

상세보기
S. Haupt, H. H. Strehblow, The analysis？of dissolved Cr3+with the rotating ring-disc technique and its application to？the corrosion of Cr in the passive state,？J. Electroanal. Chem., 216 (1987) 229-240.
S. Haupt, H. H. Strehblow, The？formation of the passive layer on Cr in？0.5 M H 2 SO 4 A combined electrochemical？and surface analytical study, J.？Electroanal. Chem., 228 (1987) 365-392.
T. P. Moffat, R. M. Latanision, An？electrochemical and X-ray photoelectron？spectroscopy study of the passive？state of chromium, J. Electrochem.？Soc., 139 (1992) 1869.

상세보기
T. P. Moffat, H. Yang, F. R. F. Fan, A.？J. Bard, Electron-transfer reactions？on passive chromium, J. Electrochem.？Soc., 139 (1992) 3158.

상세보기
C. A. Melendres, M. Pankush, Y.？S. Li, R. L. Knight, Surface enhanced raman spectroelectrochemical studies of？the corrosion films on iron and chromium？in aqueous solution environments,？Electrochim. Acta, 37 (1992) 2747-2754.

상세보기
V. Maurice, W. Yang, P. Marcus,？XPS and STM investigation of the？passive film formed on Cr(110) single-crystal surfaces, J. Electrochem.？Soc., 141 (1994) 3016.

상세보기
L. Oblonsky, T. Devine, A surface？enhanced raman spectroscopic study？of the passive films formed in borate？buffer on iron, nickel, chromium and？stainless steel, Corros. Sci., 37 (1995)？17-41.

상세보기
D. Zuili, V. Maurice, P. Marcus, In situ？scanning tunneling microscopy study？of the structure of the hydroxylated？anodic oxide film formed on Cr(110)？single-crystal surfaces, J. Phys. Chem. B,？103 (1999) 7896-7905.
M. M. Hukovic, M. C. Ceric, P-type and？n-type behavior of chromium oxide as？a function of the applied potential, J.？Electrochem. Soc., 134 (1987) 2193.

상세보기
C. Sunseri, S. Piazza, F. D. Quarto,？Photocurrent spectroscopic investigations？of passive films on chromium, J.？Electrochem. Soc., 137 (1990) 2411.

상세보기
P. C. Searson, R. M. Latanision, A？photoelectrochemical study of the？passive film on chromium, Electrochim.？Acta, 35 (1990) 445-450.

상세보기
M. Bojinov, G. Fabricius, T. Laitinen,？T. Saario, G. Sundholm, Conduction？mechanism of the anodic film on？chromium in acidic sulphate solutions,？Electrochim. Acta, 44 (1998) 247-261.

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