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멤브레인 = Membrane Journal, v.34 no.1, 2024년, pp.10 - 19
김도형 (경상국립대학교 그린에너지융합연구소) , 남상용 (경상국립대학교 그린에너지융합연구소)
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The bipolar membrane is an ion exchange membrane consisting of a cation exchange layer, an anion exchange layer, and an interface layer, and is a membrane that generates protons and hydroxide ions based on water dissociation characteristics. Using these properties, research is being conducted in var...
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M. B. McDonald and M. S. Freund, "Graphene oxide as a water dissociation catalyst in the bipolar membrane interfacial layer", ACS Appl. Mater. Interfaces, 6, 13790 (2014).？
Y. Liu, J. Chen, R. Chen, T. Zhou, C. Ke, and X. Chen, "Effects of multi-walled carbon nanotubes on bipolar membrane properties", Mater. Chem. Phys., 203, 259 (2018).？
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M. S. Kang, Y. J. Choi, H. J. Lee, and S. H. Moon, "Effects of inorganic substances on water splitting in ion-exchange membranes: I. Electrochemical characteristics of ion-exchange membranes coated with iron hydroxide/oxide and silica sol", J. Colloid. Interface Sci., 273, 523 (2004).？
E. Lucas, J. C. Bui, M. Hwang, K. Wang, A. T. Bell, A. Z. Weber, S. Ardo, H. A. Atwater, and C. Xiang, "Asymmetric bipolar membrane for high current density electrodialysis operation with exceptional stability", ChemRxiv, DOI:10.26434/che mrxiv-2023-n4c6x.？
S. Z. Oener, M. J. Foster, and S. W. Boettcher, "Accelerating water dissociation in bipolar membranes and for electrocatalysis", Science, 359, 1099 (2020).？
Y. Cho, K. Kim, J. Ahn, and J. Lee, "A study on lithium hydroxide recovery using bipolar membrane electrodialysis", J. Korean Inst. Met. Mater., 59, 223 (2021).？
S. Bunani, K. Yoshizuka, S. Nishihama, M. Arda, and N. Kabay, "Application of bipolar membrane electrodialysis (BMED) for simultaneous separation and recovery of boron and lithium from aqueous solutions", Desalination, 424, 37 (2017).？
J. Kroupa, J. Kincl, and J. Cakl, "Recovery of H2SO4 and NaOH from Na2SO4 by electrodialysis with heterogeneous bipolar membrane", Desalination Water Treat., 56, 3238 (2015).？
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O. S. L. Bruinsma, D. J. Branken, T. N. Lemmer, L. van der Westhuizen, and S. Rossouw, "Sodium sulfate splitting as zero brine process in a base metal refinery: Screening and optimization in batch mode", Desalination, 511, 115096 (2021).？
D. A. Vermaas and W. A. Smith, "Synergistic electrochemical CO2 reduction and water oxidation with a bipolar membrane", ACS Energy Lett., 1, 1143 (2016).？
Y. Jeon, V. D. C. Tinh, V. D. Thuc, and D. Kim, "Ether-free polymer based bipolar electrolyte membranes without an interlayer catalyst for water electrolysis with durability at a high current density", Chem. Eng. J., 459, 141467 (2023).？
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I. Belhaj, M. Faria, B. Sljukic, V. Geraldes, and D. M. F. Santos, "Bipolar membranes for direct borohydride fuel cells-A review", Membranes, 13, 730 (2023).？
D. Seeberger, A. Hartert, B. Mayerhofer, and S. Thiele, "Bipolar-interface hydrogen fuel cells: A review and perspective on future high-performance, low platinum-group metal content designs", ChemElectroChem., 8, 1430 (2021).？
Z. Yan, R. J. Wycisk, A. S. Metlay, L. Xiao, Y. Yoon, P. N. Pintauro, and T. E. Mallouk, "High-voltage aqueous redox flow batteries enabled by catalyzed water dissociation and acid-base neutralization in bipolar membranes", ACS Cent. Sci., 7, 1028 (2021).
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