[논문]Ethylene-Vinyl Acetate Semi-Batch Emulsion Copolymerization: Use of Factorial Experiments for Improved Process Understanding

Scott, P. J.; Penlidis, A.; Rempel, G. L.

doi:10.1002/pola.1993.080310904

Ethylene-Vinyl Acetate Semi-Batch Emulsion Copolymerization: Use of Factorial Experiments for Improved Process Understanding

Journal of polymer science. Part A, Polymer chemistry, v.31 no.9, 1993년, pp.2205 -

Scott, P. J. , Penlidis, A. , Rempel, G. L.

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AbstractA good working knowledge of the mechanism and an appreciation of the effects the process variables have on the properties of interest are required for optimization and control of polymerization processes. Despite the importance of ethylene‐vinyl acetate emulsion copolymers, limited kinetic information is available. Results from a series of factorial experiments are presented here which examine the emulsion polymerization of ethylene with vinyl acetate. Copolymers of up to 32 wt % ethylene have been produced at an ethylene pressure of 500 psig and a temperature of 20°C. The effects of the process variables on the rate of polymerization, copolymer composition, particle size and number, molecular weight averages, and gel content are discussed. The kinetic results obtained suggest process improvements for the production of homogeneous copolymer. Mechanistically, the locus of polymerization has been verified as the polymer particles and little water phase polymerization was observed. © 1993 John Wiley & Sons, Inc.

참고문헌 (18)

Scott, P. J., Penlidis, A., Rempel, G. L.. Ethylene-vinyl acetate semi‐batch emulsion copolymerization: Experimental design and preliminary screening experiments. Journal of polymer science. Part A, Polymer chemistry, vol.31, no.2, 403-426.

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P. J.Scott M. E.Kuindersma andA.Penlidis GPC/HPLC Operating Manual Internal Report available from A. Penlidis January 1992.
Adv. Chem. GarciaRubio L. H. 312 203 17 1983
Developments in Polymer Characterization Hamielec A. E. 1986
Statistics for Experimenters Box G. E. P. 1978
Wessling, Ritchie A.. Kinetics of continuous addition emulsion polymerization. Journal of applied polymer science, vol.12, no.2, 309-319.

상세보기
Gerrens, Heinz. On semicontinuous emulsion polymerization. Journal of polymer science. Part C, Polymer symposia, vol.27, no.1, 77-93.

상세보기
Arzamendi, Gurutze, Asua, Jose M.. Monomer addition policies for copolymer composition control in semicontinuous emulsion copolymerization. Journal of applied polymer science, vol.38, no.11, 2019-2036.

상세보기
Arzamendi, Gurutze, Leiza, José R., Asua, José M.. Semicontinuous emulsion copolymerization of methyl methacrylate and ethyl acrylate. Journal of polymer science. Part A, Polymer chemistry, vol.29, no.11, 1549-1559.

상세보기
Hamielec, A. E., MacGregor, J. F., Penlidis, A.. Multicomponent free‐radical polymerization in batch, semi‐ batch and continuous reactors. Die Makromolekulare Chemie. Macromolecular symposia, vol.10, no.1, 521-570.

상세보기
Okubo, M., Fujimura, M., Mori, T.. The acceleration of decomposition of potassium persulfate in the presence of sodium dodecyl sulfate and polymer particles as a model of emulsion polymerization system. Colloid and polymer science, vol.269, no.2, 121-123.

상세보기
Molecular Thermodynamics of Fluid‐Phase Equilibria Prausnitz J. M. 1969
J. Appl. Chem. USSR Shirinyan V. T. 202 51 1971
J. Coatings Tech. Craig D. H. 49 61 779 1989
Graessley, William W., Hartung, Ralph D., Uy, William C.. Studies of branching in polyvinyl acetate. Journal of polymer science. Part A-2, Polymer physics, vol.7, no.11, 1919-1935.

상세보기
Friis, N., Goosney, D., Wright, J. D., Hamielec, A. E.. Molecular weight and branching development in vinyl acetate emulsion polymerization. Journal of applied polymer science, vol.18, no.4, 1247-1259.

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Friis, N., Hamielec, A. E.. Kinetics of vinyl chloride and vinyl acetate emulsion polymerization. Journal of applied polymer science, vol.19, no.1, 97-113.

상세보기
P. F.Stehle C. K.Wu S.Loshaek andJ.Dickstein U.S. Pat. 3 644 262 1972.

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Ethylene-Vinyl Acetate Semi-Batch Emulsion Copolymerization: Use of Factorial Experiments for Improved Process Understanding

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