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NTIS 바로가기Canadian journal of chemistry, v.78 no.11, 2000년, pp.1421 - 1427
Hudrlik, Paul F , Arango, Jose O , Hijji, Yousef M , Okoro, Cosmas O , Hudrlik, Anne M
The alkoxides of o-silyl benzyl alcohols 4 undergo cleavage reactions under mild conditions allowing transfer of a benzyl or silyl group to an electrophile. Reactions 3a[GRAPHIC OMISSION]8, and 3c or 4c[GRAPHIC OMISSION]11 illustrate their potential as benzyl and silyl anion equivalents.Key words: s...
Les alcoolates d'alcools benzyliques o-silylés (4) subissent des réactions de clivage dans des conditions douces qui permettent d'effectuer le transfert d'un groupe benzyle ou silyle vers un électrophile. Les réactions 3a[GRAPHIC OMISSION]8 et 3c ou 4c[GRAPHIC OMISSION]11 illustrent leur potentiel comme équivalents des anions respectivement benzyle et silyle.Mots clés : migration d'un silyle, équivalent de l'anion benzyle, équivalent de l'anion silyle, -silylcétone, -hydroxysilane.
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