[논문]Heating rate dependency of petroleum-forming reactions: implications for compositional kinetic predictions

Dieckmann, V.; Horsfield, B.; Schenk, H.J.

doi:10.1016/s0146-6380(00)00105-4

[해외논문] Heating rate dependency of petroleum-forming reactions: implications for compositional kinetic predictions

Organic geochemistry, v.31 no.12, 2000년, pp.1333 - 1348

Dieckmann, V. , Horsfield, B. , Schenk, H.J.

Abstract ▼ AI-Helper

The generation of bulk petroleum, liquid and gaseous hydrocarbons from the Duvernay Formation was simulated by heating immature kerogens in a closed system (MSSV pyrolysis) at four different heating rates (0.013, 0.1, 0.7 and 5.0 K/min). Using the established parallel reaction kinetic model, temperature and compositional predictions were tested to be suitable for geological conditions by comparing the laboratory results with natural changes in source bitumens and reservoir oil maturity sequences from the Duvernay Formation. In the case of bulk liquid and gaseous hydrocarbons, the above kinetic calculations can be considered valid because their maximum yields are independent of laboratory heating rates. In contrast, the contents of paraffins, aromatics and sulfur compounds show a pronounced heating rate dependence. Extrapolated to geological heating rates, the compositional predictions are consistent with the bulk composition of natural products in the Duvernay-petroleum system showing an increase of paraffinicity and hydrogen content. In contrast to that, the ''hump'' decreases with decreasing heating rate, a trend which is confirmed by the low amounts of unresolved compounds in natural high maturity products. Because of these heating-rate dependent compositional changes, geological predictions of natural molecular composition by the commonly used kinetic models are not suitable.

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참고문헌 (58)

Energy and Fuels Behar 10 4 932 1996 10.1021/ef9600366 Experimental determination of the rate constants of the n-C25 thermal cracking at 120, 400 and 800 bar: implications for high-pressure/high-temperature prospects

상세보기
Organic Geochemistry Behar 19 173 1992 10.1016/0146-6380(92)90035-V Experimental simulation in a confined system and kinetic modelling of kerogen and oil cracking

상세보기
Chemical Geology Behar 126 247 1995 10.1016/0009-2541(95)00121-2 Experimental simulation of gas generation from coals and marine kerogen

상세보기
Organic Geochemistry Behar 26 321 1997 10.1016/S0146-6380(97)00014-4 Thermal cracking of kerogen in open and closed systems: determination of kinetic parameters and stoichiometric coefficients for oil and gas generation

상세보기
Energy and Fuels Braun 1 153 1990 10.1021/ef00002a003 Mathematic model of oil generation, degradation and expulsion

상세보기
Energy and Fuels Braun 5 192 1991 10.1021/ef00025a033 Pyrolysis kinetics for lacustrine and marine sources by programmed micropyrolysis

상세보기
Fuel Burnham 63 1353 1984 10.1016/0016-2361(84)90336-3 On the mechanics of kerogen pyrolysis

상세보기
10.1021/bk-1983-0230.ch017 Burnham, A.K., Singleton, M.F., 1983. High pressure pyrolysis of Green River oil shale. In: Miknis, F.P., McKay, J.F. (Eds.), Geochemistry and Chemistry of Oil Shales. Am. Chem. Soc. Symposium Series 2, pp. 335-351.
Energy and Fuels Burnham 1 452 1987 10.1021/ef00006a001 Comparison of methods for measuring kerogen pyrolysis rates and fitting kinetic parameters

상세보기
Organic Geochemistry Burnham 23 931 1995 10.1016/0146-6380(95)00069-0 A test of the parallel reaction model using kinetic measurements on hydrous pyrolysis residue

상세보기
In Situ Campbell 2 1 1978 Oil shale retorting: effects of particle size and heating rate on oil evolution and intraparticle oil degradation

상세보기
Carr 313 1990 The relationship between aromaticity, vitrinite reflectance and maceral composition in coals: Implications for the use of vitrinite reflectance as a maturation parameter
Bull. Ca. Petr. Geol. Chow 43 433 1995 Productivity versus preservation controls on two organic-rich carbonate facies in the Devonian of Alberta: sedimentological and organic petrological evidence
Cooles 235 1986 Advances in Organic Geochemistry Calculation of petroleum masses generated and expelled from source rocks
10.1144/GSL.SP.1990.050.01.9 Creaney, S., Allan, J., 1990. Hydrocarbon generation and migration in the Western Canada sedimentary Basin. In Brooks, J. (Ed.), Classical Petroleum Provinces. Geological Society Special Publication 50, pp. 189-202

상세보기
Dieckmann, V., 1998. The prediction of oil and gas composition by the integration of laboratory experiments and case studies. PhD-RWTH-Aachen. Berichte des Forschungszentrum Juelich 3648.
Fuel Dieckmann 77 23 1998 10.1016/S0016-2361(97)00165-8 Kinetics of petroleum generation and cracking by programmed-temperature closed-system pyrolysis of Toarcian shales

상세보기
Dieckmann, V., Schenk, H.J., Horsfield, B., in press. Asssessing the overlap of primary and secondary reactions by closed- versus open-system pyrolysis. Journal of Analytical and Applied Pyrolysis.
Durand 1980 Kerogen-Insoluble Organic Matter from Sedimentary Rocks
Espitalie 893 1988 Advances in Organic Geochemistry Primary cracking of kerogen. Experimenting and modeling C1, C2-5, C6-15 and C15+ classes of hydrocarbons formed
Fausett 1981 Simplified kinetics of oil shale pyrolysis
Horsfield 337 1997 Petroleum and Basin Evolution, Insights from Petroleum Geochemistry, Geology and Basin Modeling The bulk composition of first-formed petroleum in source rocks
Horsfield 189 1994 The Petroleum System from Source to Trap Diagenesis, catagenesis and metagenesis of organic matter
Geol. Rund Horsfield 78 361 1989 10.1007/BF01988370 The microscale simulation of maturation: outline of a new technique and its potential application

상세보기
Organic Geochemistry Horsfield 19 191 1992 10.1016/0146-6380(92)90036-W An investigation of the in-reservoir conversion of oil to gas: compositional and kinetic findings from closed-system programmed temperatur pyrolysis

상세보기
Larter 1984 Application of Analytical Pyrolysis Techniques to Kerogen Characterisation and Fossil Fuel Exploration/Exploitation. Analytical Pyrolysis, Methods and Application
10.1306/M60585C11 Lewan, M.D., 1994. Assessing natural oil expulsion from source rocks by laboratory pyrolysis. In: Magoon, L.B., Dow, W.G. (Eds), The Petroleum System - from Source to Trap. AAPG Memoir 60, pp. 201-210
Lewan M.D., Comer, J.B., Hamilton-Smith, T., Hasenmueller, N.R., Guthrie, J.M., Hatch, J.R. et al., 1995. Feasibility study of material-balance assessment of petroleum from the New Albany Shale in the Illinois Basin. US Geol. Surv. Bull. 2137.
Li 163 1998 Advances in Organic Geochemistry Geochemical constraints on petroleum secondary migration models: revisit the Rimbey-Meadowbrook Reef Trend in WCSB
Louis, M.C., Tissot, B., 1967. Influence de la temperature et de la pression sur la formation des hydrocarbures dans les argiles a kerogene. In: Proc. 7th World Petrol. Cong., Vol. 2, Mexico City, pp. 47-60.
Fuel Maciel 57 505 1979 10.1016/0016-2361(78)90163-1 Correlation between oil yields of oil shales and 13C nuclear magnetic resonance

상세보기
Geochimica et Cosmochimica Acta Michels 59 1589 1995 10.1016/0016-7037(95)00065-8 Effects of effluents and water pressure on oil generation during confined pyrolysis and high-pressure hydrous pyrolysis

상세보기
Energy and Fuels Muscio 10 10 1996 10.1021/ef950189d Enhanced formation of inert carbon during the natural maturation of a marine source rock, Bakken Shale, Williston Basin

상세보기
Rev. Inst. Fr. Pet. Pelet 40 551 1985 10.2516/ogst:1985034 Evaluation quantitative des produits formes lors de l'evolution geochemique de la matiere organique
Marine and Petroleum Geology Pepper 12 291 1995 10.1016/0264-8172(95)98381-E Simple kinetic models of petroleum formation. Part 1: oil and gas generation from kerogen

상세보기
Marine and Petroleum Geology Pepper 12 321 1995 10.1016/0264-8172(95)98382-F Simple kinetic models of petroleum formation. Part II: oil-gas cracking

상세보기
Price 141 1992 Advances in Organic Geochemistry The control of pressure on petroleum generation, maturation and thermal destruction as delineated by hydrous pyrolysis
Geochimica et Cosmochimica Acta Philippi 29 1021 1965 10.1016/0016-7037(65)90101-8 On the depth, time and mechanism of petroleum generation

상세보기
Anal. Chem. Radke 50 663 1978 10.1021/ac50026a035 Removal of soluble organic matter from rock samples with a flow-through extraction cell

상세보기
Anal. Chem. Radke 52 406 1980 10.1021/ac50053a009 Preparative hydrocarbon group type determination by automated medium pressure liquid chromatography

상세보기
Rubel, A.M., Margolis, M.J., Haley, J.K., Davis, B.H., 1983. Bench scale fluid retorting of Kentucky oil shale. In: Eastern Oil Shale Symposium, 13-16 November, pp. 399-405.
Organic Geochemistry Sandvik 19 1-3 77 1992 10.1016/0146-6380(92)90028-V Expulsion from hydrocarbon sources: the role of organic absorbtion

상세보기
Schaefer 115 1990 Advances in Organic Geochemistry Determination of gross kinetic parameters for petroleum formation from Jurassic source rocks of different maturity levels by means of laboratory experiments
Geochimica Cosmochimica Acta Schenk 57 623 1993 10.1016/0016-7037(93)90373-5 Kinetics of petroleum generation by programmed-temperature closed- versus open-system pyrolysis

상세보기
Schenk 137 1998 Advances in Organic Geochemistry Assessing the reliability of kinetic timing predictions
Schenk 943 1989 Advances in Organic Geochemistry Structural modifications of vitrinite and alginite concentrates during pyrolytic maturation at different heating rates. A combined infrared, 13C NMR and microscopical study
Organic Geochemistry Schenk 26 467 1997 10.1016/S0146-6380(97)00024-7 The conversion of oil into gas in petroleum reservoirs. Part 1: comparative kinetic investigation of gas generation from crude oils of lacustrine, marine and fluviodeltaic origin by programmed-temperature closed-system pyrolysis

상세보기
10.2110/cor.85.07.0343 Stoaks, F.A., Creaney, S., 1984. Sedimentology of a carbonate source rock: the Duvernay Formation of Alberta, Canada. In: Longman, M.W., Shanley, K.W. (Eds), Rocky Mountain Carbonate Reservoirs - A Core Workshop. Society of Economy Paleontologists and Mineralogists, Core Workshop No. 7, Golden, CO, pp. 343-375.
Stoaks, F.A., Creaney, S., 1985. Controls on the accumulation and subsequent maturation and migration-history of a Carbonate source rock. In: SEPM Core Workshop Proceedings, Golden, CO, p. 56.
Colo. Scho. Mines. Quart. Stout 71 153 1976 Pyrolysis of oil shale: effects of thermal history on oil yield
Am. Ass. Pet. Geol. Bull. Sweeney 74 10 1559 1990 Evaluation of a simple model of vitrinite reflectance based on chemical kinetics
Energy Fuels Tang 9 507 1995 10.1021/ef00051a016 Rate constants of n-alkane generation from type II-kerogen in open and closed pyrolysis systems

상세보기
Organic Geochemistry Tang 23 451 1995 10.1016/0146-6380(95)00020-F Formation of pristene, pristane and phytane: kinetic study by laboratory pyrolysis of Monterey source rock

상세보기
Rev. Inst. Fr. Pet. Tissot 24 470 1969 Premiere donnees sur les mechanismes et la cinetique de la formation du petrole dans les sediments. Simulation d'un schema reactionnel sur ordinateur
Bull. Am. Ass. Pet. Geol. Tissot 55 12 2177 1971 Origin and evolution of hydrocarbons in early Toarcian Shales, Paris Basin, France
Ungerer 1 1990 Advances in Organic Geochemistry State of art of research in kinetic modelling of oil formation and expulsion
Nature Ungerer 327 52 1987 10.1038/327052a0 Extrapolation of the kinetics of oil and gas generation from laboratory experiments to sedimentary basins

상세보기
VDI Forschungsheft, Van Heek 612 48 1982 Druckpyrolyse von Steinkohlen

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