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Tetrahedron, v.56 no.51, 2000년, pp.10057 - 10066
Coles, Simon J (Department of Chemistry, University of Southampton, Southampton SO17 1BJ, UK) , Mellor, John M (Department of Chemistry, University of Southampton, Southampton SO17 1BJ, UK) , El-Sagheer, Afaf H (Department of Chemistry, University of Southampton, Southampton SO17 1BJ, UK) , Salem, Ezz El-Din M (Department of Chemistry, Faculty of Science, Suez Canal University, Ismailia, Egypt) , Metwally, Reda N (Department of Science and Maths, Faculty of Petroleum and Mining Engineering, Suez Canal University, Suez, Egypt)
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AbstractBenzyl Grignard reagents react with cyclic β-alkoxy-α,β-unsaturated trifluoromethyl ketones by 1,2-addition to afford unsaturated allylic alcohols in high yield. The factors determining the balance between 1,2- and 1,4-addition to unsaturated ketones are discussed. The s...
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