[논문]Effect of Oxygen for Enhancing the Gas Storage Performance of Activated Green Carbon

Jang, Hyun-Seok; Lee, Chang Yeon; Jeon, Jun Woo; Jung, Won Taek; Hong, Won G.; Lee, Sang Moon; Kim, Haejin; Mun, Junyoung; Kim, Byung Hoon

doi:10.3390/en13153893

[해외논문] Effect of Oxygen for Enhancing the Gas Storage Performance of Activated Green Carbon 원문보기

Energies, v.13 no.15, 2020년, pp.3893 -

Jang, Hyun-Seok (Department of Physics, Incheon National University, Incheon 22012, Korea) , Lee, Chang Yeon (Department of Energy and Chemical Engineering, Incheon National University, Incheon 22012, Korea) , Jeon, Jun Woo (Department of Physics, Incheon National University, Incheon 22012, Korea) , Jung, Won Taek (Department of Physics, Incheon National University, Incheon 22012, Korea) , Hong, Won G. (Research Center for Materials Analysis, Korea Basic Science Institution, Daejeon 34144, Korea) , Lee, Sang Moon (Research Center for Materials Analysis, Korea Basic Science Institution, Daejeon 34144, Korea) , Kim, Haejin (Research Center for Materials Analysis, Korea Basic Science Institution, Daejeon 34144, Korea) , Mun, Junyoung (Department of Energy and Chemical Engineering, Incheon National University, Incheon 22012, Korea) , Kim, Byung Hoon (Department of Physics, Incheon National University, Incheon 22012, Korea)

Abstract ▼ AI-Helper

We investigated the gas storage capacity of thermally carbonized and chemically activated Phyllostachys bambusoides (PB), which is a nature-derived green carbon with an organic porous structure. Samples were thermally treated at 900 °C for 24 h, and then were chemically activated with different amounts of KOH. The pore distribution, surface area, and H2 storage capacity were measured by N2 and H2 gas sorption, up to 847 mmHg (1.13 bar) at 77 K. The CO2 storage capacity was measured up to 847 mmHg (1.13 bar) at 298 K. The maximum gas storage was shown in the sample activated with 6 times gravimetric ratio of chemical agent. It reached 1.86 wt% for H2 and 3.44 mmol/g for CO2. We used multilateral analysis methods (XRD, XPS, Raman spectroscopy, and scanning electron microscope) to identify the factors influencing gas sorption. We found that the amount of oxygen groups influence the enhancement of gas storage capacity. Moreover, the results showed that PB-based porous activated carbon has the potential to be used as a multirole gas storage material.

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