[논문]Interwoven Metal-Organic Framework on a Periodic Minimal Surface with Extra-Large Pores

Chen, Banglin; Eddaoudi, M.; Hyde, S. T.; O'Keeffe, M.; Yaghi, O. M.

doi:10.1126/science.1056598

Interwoven Metal-Organic Framework on a Periodic Minimal Surface with Extra-Large Pores

Science, v.291 no.5506 = no.5506, 2001년, pp.1021 - 1023

Chen, Banglin (Department of Chemistry, University of Michigan, Ann Arbor, MI 48109, USA.) , Eddaoudi, M. (Department of Chemistry, University of Michigan, Ann Arbor, MI 48109, USA.) , Hyde, S. T. (Department of Applied Mathematics, Australian National University, Canberra, Australia.) , O'Keeffe, M. (Department of Chemistry, Arizona State University, Tempe, AZ 85287, USA.) , Yaghi, O. M. (Department of Chemistry, University of Michigan, Ann Arbor, MI 48109, USA.)

Abstract ▼ AI-Helper

Interpenetration (catenation) has long been considered a major impediment in the achievement of stable and porous crystalline structures. A strategy for the design of highly porous and structurally stable networks makes use of metal-organic building blocks that can be assembled on a triply periodic P -minimal geometric surface to produce structures that are interpenetrating-more accurately considered as interwoven. We used 4,4′,4"-benzene-1,3,5-triyl-tribenzoic acid (H 3 BTB), copper(II) nitrate, and N , N ′-dimethylformamide (DMF) to prepare Cu 3 (BTB) 2 (H 2 O) 3 ·(DMF) 9 (H 2 O) 2 (MOF-14), whose structure reveals a pair of interwoven metal-organic frameworks that are mutually reinforced. The structure contains remarkably large pores, 16.4 angstroms in diameter, in which voluminous amounts of gases and organic solvents can be reversibly sorbed.

참고문헌 (22)

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For the design of intergrown nets with optimal porosity see T. M. Reineke M. Eddaoudi D. Moler M. O'Keeffe
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M. O'Keeffe
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Details of the elemental analysis and crystal structures for as-synthesized and evacuated MOF-14 [ Im 3 a = 26.946(2) and 26.919(1) Å respectively] and the elemental analysis of solvent-exchanged MOF-14 are available at Science Online (www.sciencemag.org/cgi/content/full/291/5506/1021/DC1). X-ray coordinates have been deposited with the Cambridge Data Bank.
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Supported by NSF grants DMR-9804817 (M.O'K.) and CHE-9980469 (O.M.Y.) and by the U.S. Department of Energy (O.M.Y.). We thank S. Ramsden for production of Fig. 2.

표제어: PCR

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Interwoven Metal-Organic Framework on a Periodic Minimal Surface with Extra-Large Pores

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