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Journal of organometallic chemistry, v.620 no.1/2, 2001년, pp.139 - 149
Shipov, Aleksandr G. (Russian State Medical University, Ostrovityanov Street 1, Moscow 117813, Russia) , Kramarova, Evgeniya P. (Russian State Medical University, Ostrovityanov Street 1, Moscow 117813, Russia) , Mamaeva, Elizaveta A. (Russian State Medical University, Ostrovityanov Street 1, Moscow 117813, Russia) , Zamyshlyaeva, Oksana A. (Russian State Medical University, Ostrovityanov Street 1, Moscow 117813, Russia) , Negrebetsky, Vadim V. (Russian State Medical University, Ostrovityanov Street 1, Moscow 117813, Russia) , Ovchinnikov, Yuri E. (Nesmeyanov's Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova Street 28, Moscow 117813, Russia) , Pogozhikh, Sergey A. (Nesmeyanov's Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova Street 28, Moscow 117813, Russia) , Bassindale*, Alan R. (Chemistry Department, Open University, Walton Hall, Milton Keynes MK7 6AA, UK) , Taylor*, Peter G. (Chemistry Department, Open University, Walton Hall, Milton Keynes MK7 6AA, UK) , Baukov*, Yuri I. (Russian State Medical University, Ostrovityanov Street 1, Moscow 117813, Russia)
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AbstractReactions of 2-sila-5-morpholinones, 4-acyl-2-silamorpholines and 4-acyl-2,6-disilamorpholines with electrophilic reagents generally lead to the opening of the sila- or disilacycle by cleavage of the Si–O bond with subsequent rearrangement to form five-membered chelate derivatives whe...
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