[논문]Reactions of silamorpholinones and acylsilamorpholines with electrophilic reagents. X-ray structure of products including a pentacoordinated silicon compound

Shipov, Aleksandr G.; Kramarova, Evgeniya P.; Mamaeva, Elizaveta A.; Zamyshlyaeva, Oksana A.; Negrebetsky, Vadim V.; Ovchinnikov, Yuri E.; Pogozhikh, Sergey A.; Bassindale*, Alan R.; Taylor*, Peter G.; Baukov*, Yuri I.

doi:10.1016/S0022-328X(00)00821-4

[해외논문] Reactions of silamorpholinones and acylsilamorpholines with electrophilic reagents. X-ray structure of products including a pentacoordinated silicon compound

Journal of organometallic chemistry, v.620 no.1/2, 2001년, pp.139 - 149

Shipov, Aleksandr G. (Russian State Medical University, Ostrovityanov Street 1, Moscow 117813, Russia) , Kramarova, Evgeniya P. (Russian State Medical University, Ostrovityanov Street 1, Moscow 117813, Russia) , Mamaeva, Elizaveta A. (Russian State Medical University, Ostrovityanov Street 1, Moscow 117813, Russia) , Zamyshlyaeva, Oksana A. (Russian State Medical University, Ostrovityanov Street 1, Moscow 117813, Russia) , Negrebetsky, Vadim V. (Russian State Medical University, Ostrovityanov Street 1, Moscow 117813, Russia) , Ovchinnikov, Yuri E. (Nesmeyanov's Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova Street 28, Moscow 117813, Russia) , Pogozhikh, Sergey A. (Nesmeyanov's Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova Street 28, Moscow 117813, Russia) , Bassindale*, Alan R. (Chemistry Department, Open University, Walton Hall, Milton Keynes MK7 6AA, UK) , Taylor*, Peter G. (Chemistry Department, Open University, Walton Hall, Milton Keynes MK7 6AA, UK) , Baukov*, Yuri I. (Russian State Medical University, Ostrovityanov Street 1, Moscow 117813, Russia)

Abstract ▼ AI-Helper

AbstractReactions of 2-sila-5-morpholinones, 4-acyl-2-silamorpholines and 4-acyl-2,6-disilamorpholines with electrophilic reagents generally lead to the opening of the sila- or disilacycle by cleavage of the Si–O bond with subsequent rearrangement to form five-membered chelate derivatives where the amide oxygen atoms coordinate with the silicon to form pentacoordinate silicon species. Multinuclear NMR spectroscopy and X-ray diffraction studies were used for structural investigation of the products. 4-Acyl-2,6-disilamorpholines initially form adducts with strong acids where the amide oxygen is protonated by the acid as demonstrated by X-ray crystallography.

주제어

참고문헌 (21)

Kost 2 1339 1998
Chem. Rev. Chuit 93 1371 1993 10.1021/cr00020a003

상세보기
Chem. Rev. Holmes 96 927 1996 10.1021/cr950243n

상세보기
10.1007/3-540-15811-1_3 (a) S.N. Tandura, M.G. Voronkov, N.A. Alekseev, Topics in Current Chemistry, vol. 131, Springer-Verlag, Berlin, 1986, pp. 99-189.
(b) A.G. Shipov, E.P. Kramarova, O.B. Artamkina, Yu.I. Baukov, Metalloorg. Khim. 4 (1991) 1101.
(c) A.G. Shipov, E.P. Kramarova, O.B. Artamkina, G.I. Oleneva, N.A. Nepomniashaja, Yu.I. Baukov, Zh. Obshch. Khim. 65 (1995) 272.
Zh. Organ. Khim. Baukov 32 1259 1996
Zh. Organ. Khim. Artamkina 63 2289 1993
V.V. Negrebetsky, Yu.I. Baukov, Izv. Akad. Nauk, Ser. Khim. (1997) 1912.
Zh. Obshch. Khim. Artamkina 65 2005 1995
Zh. Obshch. Khim. Kramarova 64 1222 1994
Zh. Obshch. Khim. Baukov 59 127 1989
10.1039/C39780000209 K.D. Onan, A.T. McPhail, C.H. Yoder, R.W. Hillard, J. Chem. Soc. Chem. Commun. (1978) 209.

상세보기
J. Chem. Soc. Perkin Trans. Allen II 1 1987 10.1039/p298700000s1

상세보기
Epshtein 255 1981 Hydrogen Bonds
10.1039/c39930000352 A.R. Bassindale, M. Borbaruah, J. Chem. Soc. Chem. Commun. (1993) 352.

상세보기
10.1070/MC1994v004n05ABEH000403 Yu.E. Ovchinnikov, Yu.T. Struchkov, A.G. Shipov, L.S. Smirnova, Yu.I. Baukov, S.Yu. Bylikin, Mendeleev Commun. (1994) 178.

상세보기
J. Organomet. Chem. Baukov 536-537 399 1997 10.1016/S0022-328X(96)06786-1

상세보기
Kristallografia Strel'zov 34 1369 1989
Robinson 366 1988 Crystallographic Computing Techniques and New Technologies
J. Organomet. Chem. Hillard 153 369 1978 10.1016/S0022-328X(00)92060-6

상세보기

내보내기 구분	파일저장 인쇄 메일전송
구성항목	기본정보 상세정보 관리번호, 논문명, 저널/프로시딩명, 저자 , 발행년, 권, 호, 시작페이지, 끝페이지, 발행기관 관리번호, 논문명, 대등논문명, 저자 , 저널/프로시딩명, 발행기관, 발행년, 발행언어, 권, 호, 시작페이지, 끝페이지, ISBN, ISSN, 주제분야, 키워드, 초록(한글), 초록(영문), 저자(소속기관)
저장형식	Text(ASCII format) Excel format RefWorks Direct Export RIS format (for Reference Manager, ProCite, EndNote), Scholar's Aids, Mendeley
메일정보	받는사람 (필수) @ 보내는사람 (선택) @ 제목 내용 KISTI 검색결과 이메일 서비스
안내	총 건의 자료가 검색되었습니다. 다운받으실 자료의 인덱스를 입력하세요. (1-10,000) 검색결과의 순서대로 최대 10,000건 까지 다운로드가 가능합니다. 데이타가 많을 경우 속도가 느려질 수 있습니다.(최대 2~3분 소요) 다운로드 파일은 UTF-8 형태로 저장됩니다. 파일의 내용이 제대로 보이지 않을실 때는 웹브라우저 상단의 보기 -> 인코딩 -> 자동선택 여부를 확인하십시오. ~ Text(ASCII format) Excel format

연합인증

[해외논문] Reactions of silamorpholinones and acylsilamorpholines with electrophilic reagents. X-ray structure of products including a pentacoordinated silicon compound

Abstract ▼ AI-Helper

주제어

참고문헌 (21)

이 논문을 인용한 문헌

관련 콘텐츠

원문 URL 링크

AI-Helper ※ AI-Helper는 오픈소스 모델을 사용합니다.

선택된 텍스트