[논문]Solid Electrolyte Interphase Revealing Interfacial Electrochemistry on Highly Oriented Pyrolytic Graphite in a Water-in-Salt Electrolyte

Kim, Yena; Hong, Misun; Oh, Hyunjeong; Kim, Yousoo; Suyama, Hiroshi; Nakanishi, Shinji; Byon, Hye Ryung

doi:10.1021/acs.jpcc.0c05433

[해외논문] Solid Electrolyte Interphase Revealing Interfacial Electrochemistry on Highly Oriented Pyrolytic Graphite in a Water-in-Salt Electrolyte

The journal of physical chemistry. C, Nanomaterials and Interfaces, v.124 no.37, 2020년, pp.20135 - 20142

Kim, Yena (Department of Chemistry , Korea Advanced Institute of Science and Technology (KAIST) , 291 Daehak-ro , Yuseong-gu, Daejeon 34141 , Republic of Korea) , Hong, Misun (Department of Chemistry , Korea Advanced Institute of Science and Technology (KAIST) , 291 Daehak-ro , Yuseong-gu, Daejeon 34141 , Republic of Korea) , Oh, Hyunjeong (Department of Chemistry , Korea Advanced Institute of Science and Technology (KAIST) , 291 Daehak-ro , Yuseong-gu, Daejeon 34141 , Republic of Korea) , Kim, Yousoo (Surface and Interface Science Laboratory, RIKEN , 2-1 Hirosawa , Wako , Saitama 351-0198 , Japan) , Suyama, Hiroshi (Advanced Material Engineering Division, Higashifuji Technical Center , Toyota Motor Corporation , 1200, Mishuku , Susono , Shizuoka 410-1193 , Japan) , Nakanishi, Shinji (Advanced Material Engineering Division, Higashifuji Technical Center , Toyota Motor Corporation , 1200, Mishuku , Susono , Shizuoka) , Byon, Hye Ryung

Abstract ▼ AI-Helper

We present a fundamental study of solid-electrolyte interphase (SEI) layers toward a better understanding of interfacial electrochemistry. In particular, water-in-salt electrolytes yield SEIs with a simple composition that describes the electrolyte-electrode interface explicitly. The 21 m lithium bis(trifluoromethanesulfonyl)imide formed a porous SEI film on a highly oriented pyrolytic graphite (HOPG) electrode at −2 V (vs Ag/AgCl). The significant hydrogen evolution reaction (HER) made holes in a thin SEI film and defect sites in the HOPG. In addition, the SEI comprised fragmented TFSI without including any Li compounds. We suggested that fragments of TFSI- were precipitated out by the addition of the hydrogen atoms, which were yielded through the Volmer step and detached from the HOPG surface before HER. Subsequently, a nonporous and LiOH-rich film was formed by −4 V. The OH- and Li+ ions were enriched during the continuous HER, and their chemical reaction produced a thick film and nanoneedles. However, there was no evidence of Li+ intercalation into graphitic layers of the HOPG, presumably caused by sluggish Li+-ion transport in the Li-deficient SEI layer. This study shows variable interfacial reactions over a wide range of applied potential and the HER impact on SEI films associated with the performance of aqueous Li-ion batteries.[FIG OMISSION]

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